Preparation method of eva thermally conductive composite adhesive film for photovoltaic encapsulation
A heat-conducting composite and encapsulation adhesive film technology, which is applied in photovoltaic power generation, adhesives, semiconductor devices, etc., can solve problems such as PID failure, and achieve the effects of easy-to-obtain raw materials, simple preparation process, and excellent pid performance
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Embodiment 1
[0022] Prepare EVA thermal conductive composite film A, which is composed of the following parts by mass of raw materials:
[0023] 100 parts of ethylene vinyl acetate copolymer,
[0024] 0.8 parts of tert-butylperoxy 2-ethylhexyl carbonate,
[0025] 0.4 parts of tris(2,4-di-tert-butylphenyl) phosphite,
[0026] 1 part of 2-hydroxy-4-n-octyloxy diphenylmethyl,
[0027] 4 parts of fumed silica.
[0028] The above-mentioned raw materials are mixed uniformly in proportion, and then the mixture is poured into an extruder for blending and extruding. The extrudate is cast, cooled, oven shaped, drawn, and rolled to obtain the EVA packaging film A.
Embodiment 2
[0030] Prepare EVA thermally conductive composite film B, which consists of the following parts by mass of raw materials:
[0031] 100 parts of ethylene vinyl acetate copolymer,
[0032] 0.6 parts of 2,5-dimethyl-2,5-bis(tert-butylperoxy)hexane,
[0033] 0.3 parts of tris(2,4-di-tert-butylphenyl) phosphite,
[0034] 1 part of 2-hydroxy-4-n-octyloxy diphenylmethyl,
[0035] 3 parts of fumed silica.
[0036] The above-mentioned raw materials are mixed uniformly in proportion, and then the mixture is poured into an extruder for blending and extrusion. The extrudate is cast, cooled, oven shaped, hauled, and rolled to obtain the EVA encapsulating film B.
Embodiment 3
[0038] The adhesive performance and impact resistance of the EVA thermally conductive composite film prepared in Examples 1 and 2 were performed, and the results are shown in Table 1. Bonding performance is tested in accordance with the national standard GB / T2790 "Adhesive 180℃ peel strength test method, bypassing material to rigid material"; impact resistance is tested in accordance with "Toughened Glass" GB / T9963-1998 and the national standard "Building Curtain Wall" GB / T21086- The impact resistance test operation method specified in 2007 was tested.
[0039] The pid test was performed on the same components encapsulated by the packaging adhesive film of Example and 2 and the results are shown in Table 1.
[0040] Optional test method: under 80% humidity and 75°C, cover the surface of the module with copper foil and connect the positive electrode of 200V, connect the battery to the negative electrode, and test the battery efficiency after 72 hours.
[0041] Table 1
[0042]
[0043...
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