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Tea leaf-polyolefin composite material and preparation method thereof

A composite material and polyolefin technology, applied in the field of chemistry, can solve the problems of high cost of biodegradable materials, unfavorable long-term production and use, difficult to promote and use on a large scale, and achieve strong functional advantages, strong cost advantages, and low prices. Effect

Active Publication Date: 2014-12-17
YINGKOU DONGSHENG IND +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, most of the raw materials used in the production and production of plastic packaging are polyethylene. The packaging materials produced by polyethylene polymers are widely used in the field, which brings great convenience to daily life, but also produces many negative effects such as environmental pollution. , Because polyethylene cannot be degraded, the cost is high! Filling with other materials will increase the weight of the product, so it is not conducive to long-term production and use. Most of the biodegradable materials currently researched have high costs and are difficult to promote and use on a large scale.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1),( Embodiment 2)

[0033] The chemical name of the antioxidant 1010 used in the embodiment of the present invention is tetrakis[methyl-β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate] pentaerythritol ester, which is produced by Shijiazhuang Yima Chemical Industry Co., Ltd. Co., Ltd. (Example 1), Zibo Xiangdong Chemical Co., Ltd. (Example 2), Shijiazhuang Baina Chemical Auxiliary Co., Ltd. (Example 3), Hangzhou Shangyou Chemical Co., Ltd. (Example 4) ), produced by Zhengzhou Haichuan Chemical Co., Ltd. (Example 5).

[0034] The model of the co-rotating parallel twin-screw extruder used in the embodiment of the present invention is TSE-65B, a product of Nanjing Hisilicon Extrusion Equipment Co., Ltd., and the working parameters are: main engine power 75kw, vacuum negative pressure -0.08~-0.05Mpa.

[0035] The screw diameter of the co-rotating parallel twin-screw extruder used in the embodiment of the present invention is 71 mm, and the aspect ratio is 44.

[0036] The high-speed mixer model that...

Embodiment 1

[0040] A tea polyolefin composite material of the present invention is made of the following raw materials in mass percentage: 30% of tea fine powder treated with silane coupling agent, 58% of polyethylene, 10% of maleic anhydride grafted polyethylene, 0.5% of stearic acid %, PE wax 1%, antioxidant 0.5%.

[0041] A preparation method of tea polyolefin composite material, comprising the following steps:

[0042] Step 1: Process the tea leaves into 150-mesh fine powder with a mechanical mill; immerse the fine powder in a diluted solution of KH550 silane coupling agent with a weight concentration of 3.0%, and soak for 4 hours under stirring; filter and separate the soaked fine powder Solid, dried at 82°C for 40 hours to obtain agglomerate powder; then use a mechanical mill to break up the agglomerate powder, and then dry at 82°C to constant weight to obtain tea fine powder treated with silane coupling agent ;

[0043] Step 2, prepare tea fine powder, polyethylene, maleic anhydr...

Embodiment 2

[0050] A tea polyolefin composite material of the present invention is made of the following raw materials in mass percentage: 31% of tea fine powder treated with silane coupling agent, 57% of polyethylene, 9% of maleic anhydride grafted polyethylene, and 0.6% of stearic acid %, PE wax 1.8% and antioxidant 0.6%.

[0051] A preparation method of tea polyolefin composite material, comprising the following steps:

[0052] Step 1: Process the tea leaves into 150-mesh fine powder with a mechanical mill; immerse the fine powder into a diluted solution of KH550 silane coupling agent with a weight concentration of 2.8%, and soak for 3.5 hours under stirring; filter and separate the soaked fine powder Solid, dried at 81°C for 32 hours to obtain agglomerate powder; then use a mechanical mill to break up the agglomerate powder, and then dry at 81°C to constant weight to obtain tea fine powder treated with silane coupling agent ;

[0053] Step 2, prepare tea fine powder, polyethylene, m...

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Abstract

The invention relates to a tea leaf-polyolefin composite material which is prepared from the following raw materials in percentage by weight: 30-35% of tea leaf fine powder treated by a silane coupling agent, 52-58% of polyethylene, 6-10% of maleic anhydride grafted polyethylene, 0.5-0.8% of stearic acid, 1-2% of PE (Poly Ethylene) wax and 0.5-0.8% of antioxidant. The preparation method comprises the following steps: S1, obtaining the tea leaf fine powder treated by the silane coupling agent; S2, preparing treated tea leaf fine powder, polyethylene, maleic anhydride grafted polyethylene, stearic acid, PE wax and antioxidant; S3, adding the treated tea leaf fine powder into a high-speed mixer; S4, adding the maleic anhydride grafted polyethylene; S5, adding polyethylene into the high-speed mixer; S6, adding the stearic acid, PE wax and antioxidant; and S7, obtaining the tea leaf-polyolefin composite material. The material provided by the invention has the beneficial effects that the performance requirements of functional biomass high polymer materials are satisfied; the composite material is a low-cost and green high polymer material which not only has the characteristic of conventional polyethylene, but also is degradable and can be used for improving the mechanical properties of plastic products.

Description

[0001] technical field [0002] The invention belongs to the technical field of chemistry, and in particular relates to a tea polyolefin composite material and a preparation method thereof. Background technique [0003] At present, most of the raw materials used in the production and production of plastic packaging are polyethylene. The packaging materials produced by polyethylene polymers are widely used in the field, which brings great convenience to daily life, but also produces many negative effects such as environmental pollution. , Because polyethylene cannot be degraded, the cost is high! Filling with other materials will increase the weight of the product, so it is not conducive to long-term production and use. Most of the biodegradable materials currently researched have high costs and are difficult to promote and use on a large scale. Contents of the invention [0004] Aiming at the deficiencies of the prior art, the present invention provides a tea polyolefin c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L51/06C08L97/02
CPCC08L23/06C08L2201/06C08L2205/025C08L2205/035C08L2205/08C08L97/02C08L51/06
Inventor 李智武文起东文博郝天禹李姝谊
Owner YINGKOU DONGSHENG IND
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