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A kind of high transparency solid glue stick and preparation method thereof

A solid glue stick, transparency technology, applied in adhesives, non-polymer adhesive additives, N-vinylpyrrolidone copolymer adhesives, etc. Potential safety hazards of personnel and workshop environment, difficulty in large-scale production, etc., to achieve the effect of easy access to raw materials, low production costs, and easy control of reactions

Inactive Publication Date: 2016-05-25
NINGBO INST OF TECH ZHEJIANG UNIV ZHEJIANG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The patent for invention discloses a preparation method of a transparent solid glue stick, but it has the following disadvantages: First, although this preparation method can obtain a solid glue stick with a certain degree of transparency, the transparency is not large, and it is impossible to obtain a solid glue stick with a certain transparency. High transparency solid glue stick
Second, although the free formaldehyde content of the transparent solid glue sticks prepared by this method is low enough to meet the standard requirements, the use of formaldehyde cannot be avoided in the production process, which poses a greater safety hazard to operators and the workshop environment
The 3rd, the production process of this solid glue stick is complicated, and the production cycle is longer
[0005] Another patent number is 201110188372.8, and the invention patent titled "A transparent alkali-soluble acrylic resin solid glue and its preparation method" discloses a kind of invention that uses alkali-soluble acrylic resin as an adhesive and dibenzylidene sorbitol as an excipient. transparent solid glue, but because dibenzylidene sorbitol raw material is difficult to obtain on the market, and the price is higher; therefore the production cost is high, it is difficult to carry out large-scale production

Method used

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Examples

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Effect test

preparation example Construction

[0028] A preparation method for a high-transparency solid glue stick: it is characterized in that it comprises the following steps:

[0029] Step 1, prepare raw materials;

[0030] Step 2: Add the solvent into the reaction kettle, slowly add polyvinylpyrrolidone after stirring, dissolve at room temperature for 10 minutes to 60 minutes, then raise the temperature to 56°C to 88°C and then keep the temperature;

[0031] Step 3: Add excipients into the reaction kettle, and stir at constant temperature for 10 to 40 minutes until the excipients are completely melted and transparent and evenly dispersed in the solvent;

[0032] Step 4. Slowly add a pH regulator aqueous solution to the reaction kettle to adjust the pH value of the system to 10 to 12, and stir at a constant temperature for 10 to 50 minutes until the solution is transparent; after it becomes transparent, there is no white turbidity;

[0033] Step 5. Add a transparent agent into the reaction kettle, stir at a constant t...

Embodiment 1

[0036] Step 1, prepare raw materials according to the following weight percentages:

[0037] Polyvinylpyrrolidone 5%

[0038] Solvent: Glycerol 50%

[0039] Propylene Glycol 10%

[0040] Excipients: stearic acid 10%

[0041] pH adjuster: sodium hydroxide 1.5%

[0042] Potassium hydroxide 0.8%

[0043] Transparent agent: 10% ethanol

[0044] Sucrose 3%

[0045] The rest is water.

[0046] Step 2. Add the solvent (a mixture of 50% glycerol and 10% propylene glycol) into the reaction kettle, slowly add 5% polyvinylpyrrolidone after stirring, dissolve at room temperature for 10 minutes to 60 minutes, and then heat up to 56°C to 88°C Constant temperature after ℃;

[0047] Step 3: Add excipients (10% stearic acid) into the reaction kettle, stir at constant temperature for 10 to 40 minutes until the excipients are completely melted and transparent and evenly dispersed in the solvent;

[0048] Step 4. Slowly add a pH adjuster (a mixture of 1.5% sodium hydroxide and 0.8% potas...

Embodiment 2

[0052] Step 1, prepare raw materials according to the following weight percentages:

[0053] Polyvinylpyrrolidone 10%

[0054] Solvent: Glycerol 30%

[0055] Ethylene glycol 15%

[0056] Excipients: stearic acid 8%

[0057] Lauric acid 3%

[0058] pH adjuster: sodium hydroxide 2%

[0059] Potassium hydroxide 1%

[0060] Transparent agent: 15% ethanol

[0061] Sorbitol 5%

[0062] The rest is water.

[0063] Step 2. Add the solvent (a mixture of 30% glycerol and 15% ethylene glycol) into the reaction kettle, slowly add 10% polyvinylpyrrolidone after stirring, dissolve at room temperature for 10 minutes to 60 minutes, and then heat up to 56°C Constant temperature after reaching 88°C;

[0064] Step 3. Add excipient (a mixture of 8% stearic acid and 3% lauric acid) into the reaction kettle, stir at constant temperature for 10 minutes to 40 minutes until the excipient is completely melted and transparent and evenly dispersed in the solvent;

[0065] Step 4. Slowly add an ...

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PUM

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Abstract

The invention relates to a high-transparency solid glue stick. The high-transparency solid glue stick comprises the following raw materials by weight percentage: 5-50% of polyvinylpyrrolidone, 3-20% of excipient, 15-80% of solvent, 5-30% of clarifier, 0.5-10% of pH modifier, and the balance of water; the sum of the raw materials is 100%; the excipient is fatty acid salt. The preparation method comprises the following steps: (1) preparing raw materials; (2) adding the solvent in a reaction still; slowly adding the polyvinylpyrrolidone after stirring; conducting dissolution at a room temperature; increasing the temperature to 56-88 DEG C to be at a constant temperature; (3) adding the excipient; conducting stirring at the constant temperature until the excipient is completely fused, and transparent; (4) slowly adding the pH modifier aqueous solution; regulating the PH value to 10-12; conducting stirring at the constant temperature until the solution is transparent; (5) adding the clarifier; leaving the solution to stand at the constant temperature after stirring at the constant temperature; (6) filling the product; conducting cooling at the room temperature to obtain the product. The preparation method has the advantages that the production cost is low, the technology is simple, and the production period is short.

Description

technical field [0001] The invention relates to a stationery product, in particular to a high-transparency solid glue stick and a preparation method thereof. Background technique [0002] Stationery adhesives are mainly PVA liquid glue and solid glue sticks. Most of the colloids of solid glue sticks on the market are white or light yellow opaque solids, and transparent solid glue sticks are very popular among consumers because their colloids have certain crystal-like transparency. [0003] The existing patent number is 200910153831.1 titled "A transparent and environmentally friendly solid glue and its preparation method" [0004] The patent for invention discloses a preparation method of a transparent solid glue stick, but it has the following disadvantages: First, although this preparation method can obtain a solid glue stick with a certain degree of transparency, the transparency is not large, and it is impossible to obtain a solid glue stick with a certain transparency....

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J139/06C09J11/06C09J9/00
Inventor 徐金宝钟国伦
Owner NINGBO INST OF TECH ZHEJIANG UNIV ZHEJIANG
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