Surface modification processing device for poly(p-phenylene benzobisoxazole) fiber and use method of surface modification processing device

Active Publication Date: 2015-02-04
SHANGHAI COMPOSITES SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Some of these methods have excessively lost the mechanical properties of the fiber itself (chemical oxidation method) while improving the surface properties of PBO fibers, and some have serious degradation effects, that is, the modification effect decreases with time (plasma treatment method) , radiation treatment method), some treatment effects are not obvious and the treatment speed is slow and the efficiency is low (biological treatment method). At the same time, most of these methods are in the experimental stage and cannot continuously process PBO fiber filaments, which reduces production efficiency , can not achieve the purpose of industrial production

Method used

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  • Surface modification processing device for poly(p-phenylene benzobisoxazole) fiber and use method of surface modification processing device
  • Surface modification processing device for poly(p-phenylene benzobisoxazole) fiber and use method of surface modification processing device
  • Surface modification processing device for poly(p-phenylene benzobisoxazole) fiber and use method of surface modification processing device

Examples

Experimental program
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Effect test

Embodiment 1

[0035] Place the PBO fiber bundle on the yarn roll 10 on the device 1, place the prepared coupling agent modification solution (1-9% KH560 aqueous solution) in the surface modification tank 3, and manually draw the fiber bundle through the yarn guide The device 2, the surface modification treatment tank 3, and the drying device 4 are placed on the winding device 5 and fixed. Then turn on the drying device 4 and set the temperature at 100-110°C. After the temperature is reached, turn on the winding device 5 and set the roller speed at 1-5 r / min to wind the modified PBO fiber. The surface of PBO fiber modified by this device is obviously covered with a layer of uniform coating by scanning electron microscope observation, the surface roughness is increased, and the contact angle of single fiber to epoxy resin is reduced from 38.88° to 30.94°. The interfacial shear strength of the oxygen resin increased from 7.9MPa to 12.3MPa, an increase of 55.6%, and the wettability of the fiber...

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Abstract

The invention relates to a surface modification processing device for poly(p-phenylene benzobisoxazole) fiber and a use method of the surface modification processing device. The surface modification processing device partially comprises a tension providing device, a yarn guide device, a surface modification processing groove, a drying device and a coiling device. Through the device provided by the invention, the poly(p-phenylene benzobisoxazole) fiber is subjected to surface modification, the poly(p-phenylene benzobisoxazole) fiber can be continuously subjected to surface processing in real time, the surface performance is improved, meanwhile, the original mechanical property of the PBO fiber is not damaged, and in addition, the processing effect is good. The device provided by the invention has the advantages that the structure is simple, the operation is simple and convenient, and the continuous and industrial production can be realized.

Description

technical field [0001] The invention relates to the surface modification of poly-p-phenylene benzobisoxazole fibers, in particular to a surface modification treatment device for continuously treating poly-p-phenylene benzobisoxazole fibers. Background technique [0002] Due to its light weight and high strength properties, composite materials have a growing demand in high-tech fields such as aviation, aerospace and national defense. Composite materials are multiphase systems composed of matrix materials and reinforcement materials. Composite materials that use polymer as a matrix as structural members mostly use fibrous materials, especially continuous long fibers, as reinforcing materials. As a new type of reinforcing material, poly-p-phenylenebenzobisoxazole (PBO) fiber has attracted much attention not only for its excellent mechanical properties, but also for its good heat resistance and high oxygen resistance index. "Superfibers of the 21st Century". However, despite ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06B3/04D06B23/04
Inventor 谢钟清王晓蕾田杰
Owner SHANGHAI COMPOSITES SCI & TECH CO LTD
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