Microarray substrate, microarray, microfluidic system and methods for preparing the same
A microfluidic system and microarray technology, applied in the direction of microbial library, chemical library, combinatorial chemistry, etc., can solve problems such as high cost
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[0064] Fabrication of multilayer microfluidic loading devices
[0065] A multilayer microfluidic loading device was prepared to form polydopamine microspots on a fluoropolymer membrane. Microfluidic systems can also be used to deliver chemical or biochemical agents to the fluoropolymer substrates disclosed herein. The terms "microfluidic loading device" and "microfluidic system" are used interchangeably herein.
[0066] Microfluidic systems can be fabricated using a variety of materials such as polydimethylsiloxane (PDMS), polystyrene, polycarbonate, glass, and silicon wafers. For example, microfluidic systems are made of polydimethylsiloxane (PDMS). PDMS is a commonly used material for microfluidic chips 29 , PDMS is known to be gas and water permeable 32 . As an example, methods of fabricating microfluidic systems include the use of soft lithography 30 .
[0067] In one embodiment, the microfluidic system comprises or consists of two layers with different patterns. T...
Embodiment 1
[0092] Example 1: Preparation of PDMS microfluidic loading device
[0093]The PDMS microfluidic device consists of two PDMS layers with different patterns, by soft lithography using Siloxane 184 Silicone Elastomer kit (Dow Corning) to produce. The kit contains PDMS precursor and curing agent.
[0094] By casting PDMS precursors, liquid siloxane monomers ( 184, Dow Corning) and a mixture of curing agent (5:1) to make the upper PDMS layer. The silicon master is patterned using photolithography. The silicon master serves as a mold and contains a relief structure ( figure 1 ).
[0095] The underlying PDMS layer is a thin PDMS membrane (about 20 μm thick) containing micropores. The PDMS underlayer was made by spin-coating a thin layer of PDMS precursor (siloxane monomer: curing agent = 20:1) on the surface of the second silicon master. The silicon master contains an array of micropillars with a diameter of 200 μm. The micropillar size determines the micropore size of the ...
Embodiment 2
[0097] Example 2: Fabrication of polydopamine microspots on fluoropolymer membranes
[0098] The dopamine used in this example was purchased from Sigma-Aldrich Company, and the FEP (20 μm) used was purchased from Shanghai Yuyisong Plastic Products Co., Ltd.
[0099] Prepare fresh dopamine solution (pH 8.5, 2 g / L). A 1 cm x 1 cm FEP membrane was washed three times with ultrasonic waves passing through surfactant, ethanol and deionized water before use.
[0100] The PDMS microfluidic system prepared in Example 1 was tightly combined with the FEP membrane by the clamp method, and degassed in a vacuum desiccator for 30 minutes ( figure 2 a). After completing the degassing step, fresh dopamine solution (pH = 8.5) was introduced into the microfluidic system. The solution immediately fills the upper channel layer and then gradually fills the empty space in the lower micropores. The degassed PDMS system accelerated the filling process by adsorbing air in the microchannels and por...
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