Xanthene dye for color filter, and color filter using said dye
A color filter and pigment technology, which is applied in the directions of instruments, optical filters, benzoxanthamine/xanthone/thioxanthone/selenoxanthone/tellurium xanthone dyes, etc. Solve the problems of deterioration of display contrast, transparency, and improvement of color purity of color liquid crystal display devices, and achieve the effect of high heat resistance and excellent solubility
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Embodiment 1
[0056] The embodiments of the present invention will be specifically described below through examples, but the present invention is not limited to the following examples.
[0057] [Synthesis of xanthene pigments]
[0058] Add 500 g of C.I. Acid Red 289 (purity 85%), 3.0 L of water, and 150 mL of toluene to a reaction vessel, and heat to 80° C. to dissolve C.I. Acid Red 289. A mixed solution of 209 g of dodecyl ethanolamine, 94 g of concentrated hydrochloric acid, and 1.5 L of water was added to this solution, and stirred at 80° C. for 1 hour. After removing the solution portion by decantation, adding 4.0 L of water, and stirring at 80° C. for 30 minutes, the operation of adding 1.7 L of methanol and 1.0 L of toluene to the residue was repeated twice, followed by stirring at 50° C. for 1 hour. After removing the insoluble matter by filtration, the solvent was distilled off under reduced pressure to obtain 545 g (yield 99%) of a xanthene-based dye (C-1) represented by the follo...
Embodiment 2
[0061] [evaluation of pigment]
[0062] The obtained xanthene pigment (C- 1) Decomposition initiation temperature and solubility in PGME at 25° C. under normal pressure, and the measurement results are summarized in Table 1.
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