Aluminum-zinc multi-component alloy-containing water-based epoxy coating for anti-corrosive treatment of submarine oil and gas pipelines and preparation method of water-based epoxy coating

A technology of water-based epoxy coating and multi-element alloy, applied in the field of coatings, can solve the problems of reducing the service life and safety of submarine steel pipes, preventing the intrusion of small molecule corrosive media, affecting the physical shielding performance of coatings, etc., and achieving enhanced electrochemical corrosion resistance and chemical corrosion performance, reduce the generation of free phase, and the effect of excellent anti-corrosion performance

Inactive Publication Date: 2015-03-25
NANJING UNIV OF AERONAUTICS & ASTRONAUTICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

First of all, because the coating has some holes and defects inside the coating, it cannot prevent the immersion of small molecule corrosive media, and cannot completely prevent corrosion, which in turn affects the physical shielding performance of the coating.
Secondly, the traditional water-based anti-corrosion coatings still have many deficiencies in the resistance to seawater chemical corrosion and electrochemical corrosion, which will greatly reduce the service life and safety of submarine steel pipes.

Method used

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  • Aluminum-zinc multi-component alloy-containing water-based epoxy coating for anti-corrosive treatment of submarine oil and gas pipelines and preparation method of water-based epoxy coating
  • Aluminum-zinc multi-component alloy-containing water-based epoxy coating for anti-corrosive treatment of submarine oil and gas pipelines and preparation method of water-based epoxy coating
  • Aluminum-zinc multi-component alloy-containing water-based epoxy coating for anti-corrosive treatment of submarine oil and gas pipelines and preparation method of water-based epoxy coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] 30g of aluminum-zinc multi-element alloy water-based epoxy coatings for anticorrosion treatment of submarine oil and gas pipelines, the coatings are composed of the following components by mass percentage:

[0035]

[0036] The film-forming substance is composed of 20% water-based phenolic epoxy resin and 14% water-based polyurethane according to the mass percentage; the pigment and filler include aluminum-zinc multi-element alloy powder; the solvent is deionized water.

[0037] Pigments and fillers are prepared from the following components according to the total mass percentage of the coating:

[0038]

[0039]

[0040] The aluminum-zinc multi-element alloy powder is scaly aluminum-zinc multi-element alloy powder, with an average sheet diameter of about 16 μm, a sheet thickness of about 0.4 μm, and an aspect ratio of 40.

[0041] The composition of the scale-shaped aluminum-zinc multi-element alloy powder is as follows according to the total mass percentage o...

Embodiment 2

[0053] 50g of aluminum-zinc multi-element alloy water-based epoxy coatings for anticorrosion treatment of submarine oil and gas pipelines, the coatings are composed of the following components by mass percentage:

[0054]

[0055] Wherein, the film-forming substance is composed of 16% of water-based phenolic epoxy resin and 14% of water-based polyurethane according to the mass percentage; the pigment and filler include aluminum-zinc multi-element alloy powder; and the solvent is deionized water.

[0056] Pigments and fillers are prepared from the following components according to the total mass percentage of the coating:

[0057]

[0058] The aluminum-zinc multi-element alloy powder is scaly aluminum-zinc multi-element alloy powder, with an average sheet diameter of about 14 μm, a sheet thickness of 0.4 μm, and an aspect ratio of about 60.

[0059] The composition of the scale-like aluminum-zinc multi-element alloy powder is based on the total mass percentage of the coat...

Embodiment 3

[0071] 100g of aluminum-zinc multi-element alloy water-based epoxy coatings for anticorrosion treatment of submarine oil and gas pipelines, the coatings are composed of the following components by mass percentage:

[0072]

[0073] Wherein, the film-forming substance is composed of 16% of water-based phenolic epoxy resin and 14% of water-based polyurethane according to the mass percentage; the pigment and filler include aluminum-zinc multi-element alloy powder; and the solvent is deionized water.

[0074] Pigments and fillers are prepared from the following components according to the total mass percentage of the coating:

[0075]

[0076] The aluminum-zinc multi-component alloy powder is a scaly aluminum-zinc multi-component alloy powder, with a sheet diameter of about 17 μm, a sheet thickness of 0.3 μm, and an aspect ratio of about 35.

[0077] The composition of the scaly aluminum-zinc multi-element alloy powder is as follows: Al: 3% (3g), Si: 0.2% (0.2g), rare earth:...

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Abstract

The invention discloses an aluminum-zinc multi-component alloy-containing water-based epoxy coating for anti-corrosive treatment of submarine oil and gas pipelines and a preparation method of the water-based epoxy coating. The water-based epoxy coating consists of the following raw materials in percentage by mass: 30-40% of a film forming matter, 20-30% of pigment-filler, 5-15% of auxiliary agents and 20-40% of a solvent, wherein the film forming matter consists of 16-24% of waterborne novolac epoxy resin and 14-16% of waterborne polyurethane in percentage by mass; the pigment-filler comprises aluminum-zinc multi-component alloy powder; and the solvent is deionized water. The aluminum-zinc multi-component alloy-containing water-based epoxy coating disclosed by the invention has excellent corrosion resistance integrating isolation, sacrificing and corrosion inhibition.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to epoxy coatings for anticorrosion treatment of submarine oil and gas pipelines. Background technique [0002] With the continuous exploitation of oil and natural gas, onshore oil and gas resources can no longer fully meet the needs of human beings, while there are abundant oil and gas resources stored in the ocean. The competition for offshore oil and gas resources has become the focus of attention of all countries in today's society. Submarine pipeline transportation is currently the most effective and safest way to exploit offshore oil and gas resources. However, there is a big gap between domestic submarine oil and gas pipelines and foreign products in terms of corrosion resistance and service life. Therefore, it is very important to develop anticorrosion coatings for oil and gas pipelines that are resistant to harsh marine environments. [0003] Most of the paints are now s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/04C09D175/04C09D7/12C09D5/10
CPCC08K2003/2241C09D163/04C09D5/103C09D5/106C09D7/62C08L75/04C08K13/06C08K3/34C08K3/346C08K3/36C08K2003/2272
Inventor 姚正军杜咪咪周金堂姚芮刘沛江王占红李天明孔颖李琳徐丹姚田甜
Owner NANJING UNIV OF AERONAUTICS & ASTRONAUTICS
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