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Highly hydrophobicuv (ultraviolet) leather surface treating agent and preparation method thereof

A technology of surface treatment agent and treatment method, applied in the preparation of UV high hydrophobic leather surface treatment agent, in the field of UV high hydrophobic leather surface treatment agent, can solve the problems of large environmental pollution, poor stability, complex preparation method, etc., to improve leather The effect of hydrophobicity, simple equipment use, and simple preparation method

Inactive Publication Date: 2015-04-01
佛山金智节能膜有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] An object of the present invention is to propose a uv highly hydrophobic leather surface treatment agent, which solves the problems of single treatment effect and poor stability of leather surface treatment agents in the prior art
[0004] Another object of the present invention is to propose a method for preparing a UV highly hydrophobic leather surface treatment agent, which solves the problems of complex preparation methods, unreasonable process design and large environmental pollution in the prior art

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] According to the content provided by the present invention, the inventors have prepared uv highly hydrophobic leather surface treatment agent 1, wherein the proportioning and preparation process of each component are as follows:

[0025] 5g of polyester acrylate, 60g of ethylene glycol diacrylate, 30g of photoinitiator (type 907), 2g of silicone, 3g of polyacrylic acid.

[0026] Mix 2g of polyester acrylate, 30g of ethylene glycol diacrylate, 10g of photoinitiator (type 907), 1g of silicone, and 1g of polyacrylic acid, stir at high speed, and the stirring speed is 1000 rpm, controlled The temperature is fully dissolved at 45°C until it is completely transparent, and intermediate raw materials are obtained;

[0027] Add the remaining prepolymer, the remaining active monomer, the remaining photoinitiator, the remaining binder, and the remaining thickener to the intermediate raw material in sequence, stir for 5 minutes, then disperse at high speed for 30 minutes, and contr...

Embodiment 2

[0029] According to the content provided by the present invention, the inventor has prepared uv highly hydrophobic leather surface treatment agent 2, wherein the proportioning and preparation process of each component are as follows:

[0030] 40g of amino acrylate, 24g of hexanediol diacrylate, 20g of photoinitiator (model ITX), 6g of polyurethane, 10g of associative polyurethane.

[0031] 20g of amino acrylate, 12g of hexanediol diacrylate, 10g of photoinitiator (type ITX), 3g of polyurethane, 5g of associative polyurethane, mixed at high speed, the stirring speed is 25000 rpm, controlled The temperature is fully dissolved at 30°C until it is completely transparent, and intermediate raw materials are obtained;

[0032] Add the remaining amino acrylate, hexanediol diacrylate, photoinitiator, polyurethane, and associative polyurethane to the intermediate raw material in turn, stir for 5 minutes, then disperse at high speed for 120 minutes, control the speed at 15,000 rpm, and d...

Embodiment 3

[0034] According to the content provided by the present invention, the inventors have prepared uv highly hydrophobic leather surface treatment agent 3, wherein the proportioning and preparation process of each component are as follows:

[0035] 40g of bisphenol A type epoxy acrylate, 45g of epoxy soybean oil acrylate, 3g of diethylene glycol diacrylate, 3g of trimethylolpropane triacrylate, 4g of pentaerythritol hexaacrylate, 1g The photoinitiator (model is BP), 2g of MS modified silane, 2g of silicone.

[0036] Mix 40g of bisphenol A type epoxy acrylate, 3g of diethylene glycol diacrylate, 0.5g of photoinitiator (model BP), 1g of MS modified silane, and 1g of silicone, at high speed Stirring, the stirring speed is 3000 rpm, and the temperature is controlled below 50°C to fully dissolve completely until transparent to obtain intermediate raw materials;

[0037] In the intermediate raw material, add the remaining 45g epoxy soybean oil acrylate successively, the trimethylolprop...

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PUM

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Abstract

The invention discloses a highly hydrophobicuv (ultraviolet) leather surface treating agent which comprises raw materials in percentage by weight as follows: 5%-85% of prepolymer, 10%-60% of an activated monomer, 0.01%-30% of aphotoinitiator, 1%-6% of a binder and 0.1%-10% of a thickener. The leather surface treating agent improves the hydrophobicity, oil rub resistance and scratch resistance of leather. The invention discloses a preparation method of the highly hydrophobicuvleather surface treating agent. The method is simple, reasonable in technological design, energy-saving, environment-friendly and suitable for large-scale production and application, and equipment use is simple.

Description

technical field [0001] The invention belongs to the field of post-finishing of coatings, natural leather, artificial leather, synthetic leather and textile fabrics, and particularly relates to a UV highly hydrophobic leather surface treatment agent, and also relates to a preparation method of the UV highly hydrophobic leather surface treatment agent. Background technique [0002] Traditional leather surface treatment mainly includes the following: 1. Oil-soluble treatment agent; 2. Water-based treatment agent, usually a physical mixture of water-based PA and PU resin. The physical mixture of water-based PA and PU resins are traditional treatment agents, some of which have hydrophobic effect, and the effect is single. Contents of the invention [0003] An object of the present invention is to propose a UV highly hydrophobic leather surface treatment agent, which solves the problems of single treatment effect and poor stability of the leather surface treatment agent in the p...

Claims

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Application Information

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IPC IPC(8): C09D167/06C09D175/14C09D163/10C09D4/02C14C11/00D06M13/224D06M15/51D06M13/325D06M15/55
CPCC09D167/06C08L2205/03C09D163/10C14C11/00
Inventor 刘洪万李永鸿陈广建
Owner 佛山金智节能膜有限公司
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