Fluidized bed reactor, fluidized bed reaction apparatus, and methane water-vapour reforming method

A fluidized bed reactor, methane steam technology, applied in chemical instruments and methods, inorganic chemistry, chemical/physical processes, etc., can solve the problem of rapid decline of catalyst activity, reduce energy consumption and hydrogen consumption, improve reaction degree, avoid the effect of unnecessary decline

Active Publication Date: 2015-05-06
CHINA PETROLEUM & CHEM CORP +1
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0009] The inventors of the present invention found in the research process that the existing adsorption-enhanced methane steam reforming hydrogen production technology has the problem of rapid decline in catalyst activity

Method used

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  • Fluidized bed reactor, fluidized bed reaction apparatus, and methane water-vapour reforming method
  • Fluidized bed reactor, fluidized bed reaction apparatus, and methane water-vapour reforming method
  • Fluidized bed reactor, fluidized bed reaction apparatus, and methane water-vapour reforming method

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Embodiment 1

[0084] This embodiment adopts figure 1 Shown fluidized bed reactor, wherein:

[0085] (1) The reaction zone of the fluidized bed reactor is a cylinder with an inner diameter of 160mm and a height of 1200mm, the angle between the outer contour line of the expanding diameter zone and the horizontal plane is 60°, and the settling zone is a cylinder with an inner diameter of 240mm and a height of 400mm cylinder;

[0086] (2) In the reaction zone, 20 metal foam plates (produced by Beijing Zhongshi Qiangye Foam Metal Co., Ltd.) are arranged at equal intervals along the longitudinal direction. The metal foam plates are formed of nickel and tungsten, and the weight ratio of nickel to tungsten is 1 : 0.1, the thickness of the foam metal plate is 2mm, the average pore diameter of the pores on the foam metal plate is 1mm, the porosity of the foam metal plate is 95% by volume), the minimum distance between the upper end surface of the foam metal plate and the top of the reaction zone is ...

Embodiment 2

[0096] Adopt the method identical with embodiment 1 to produce hydrogen, difference is:

[0097] (1) In the reaction zone, 20 metal foam plates (produced by Beijing Zhongshi Qiangye Foam Metal Co., Ltd., inactive foam metal plates formed of copper) are arranged at uniform intervals along the horizontal direction. Loaded with nickel and tungsten, wherein the loading of nickel is 10% by weight, the weight ratio of nickel to tungsten is 1:0.2, the thickness of the inactive foam metal plate is 5mm, and the average of the pores on the inactive foam metal plate The pore diameter is 2mm, the porosity is 95%), the side wall of the metal foam plate is connected with the inner wall of the reaction zone;

[0098] (2) Filling fluidizable particles between the metal foam plates and between the metal foam plates and the inner wall of the reaction zone, the fluidizable particles are calcium oxide particles with a volume average particle diameter of 70 μm.

[0099] Methane is steam reformed ...

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Abstract

The invention provides a fluidized bed reactor. A reaction area of the reactor is provided with foam metal plates with catalytic activity, the foam metal plates are longitudinally and/or transversely arranged along the reaction area, the space among the foam metal plates and/or the space between the foam metal plates with the inner wall of the reaction area are/is used to hold a fluidizable particle, and the fluidizable particle can pass through pores on the transversely-arranged foam metal plates. The invention also provides a fluidized bed reaction apparatus which comprises the fluidized bed reactor and a regenerator. The invention also provides a methane water-vapour reforming method using the fluidized bed reaction apparatus, and the foam metal plates have catalytic activity on the methane water-vapour reforming reaction, and at least a part of the fluidizable particle has adsorption effect on carbon dioxide. In the method, the catalyst does not need frequently regenerating along with the adsorbent, when the adsorbent is guaranteed to be always capable of satisfying usage requirements, energy consumption during regeneration is reduced, and senseless reduction of the catalyst activity is avoided.

Description

technical field [0001] The invention relates to a fluidized bed reactor, and also relates to a fluidized bed reaction device using the fluidized bed reactor, and further relates to a methane steam reforming method. Background technique [0002] With the development of economy and society, the demand for energy is gradually increasing; however, oil resources are becoming increasingly depleted and environmental pollution is becoming more and more serious, so the development and utilization of clean energy has become a research hotspot. Hydrogen not only has a high calorific value of combustion, but also has no adverse effects on the environment because the combustion product is water, so it is an efficient and ideal clean energy. [0003] Hydrogen can be produced from methane (that is, natural gas) through steam reforming, and natural gas reserves are abundant worldwide. Therefore, the development and utilization of hydrogen energy has gradually attracted attention. [0004] ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J8/24C01B3/44
CPCB01J8/26C01B3/44
Inventor 赵俊杰侯栓弟张同旺武雪峰宋宁宁
Owner CHINA PETROLEUM & CHEM CORP
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