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Flotation separation method of low / extra-low grade copper-molybdenum ore or chat

A separation method and technology for copper-molybdenum ore, applied in flotation, solid separation and other directions, can solve problems such as increased energy consumption, low molybdenum selection yield, violation of flotation column, etc., and achieves flexible adjustment, convenient configuration, and a single unit Small volume effect

Inactive Publication Date: 2015-06-24
四川省冶金地质勘查院 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, because the flotation column does not have the strong stirring and capturing power of the flotation machine, the minerals are less likely to be scrubbed and contacted with the beneficiation agent, so the copper and molybdenum minerals with poor floatability are easy to fall into the tail of the flotation column. Even if the flotation machine is used to scavenge it, it will fall into the tailings due to insufficient flotation time—unless the number of flotation machines used for scavenging is increased at the cost of increasing energy consumption—so it adopts The method of roughing with flotation column and sweeping with flotation machine is unreasonable, and also violates the original intention of using flotation column to save energy
Especially for copper-molybdenum ore with molybdenum grade < 0.01% ore or mine waste rock discarded in mining, when using flotation column to directly produce molybdenum concentrate, the molybdenum concentration yield is small, and its foam layer is not easy to control and adjust, and it is difficult to obtain high-quality molybdenum concentrate

Method used

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  • Flotation separation method of low / extra-low grade copper-molybdenum ore or chat
  • Flotation separation method of low / extra-low grade copper-molybdenum ore or chat

Examples

Experimental program
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Effect test

Embodiment 1

[0037] figure 1 It is the basic process flow of the present invention for the flotation separation method of low / ultra-low grade copper-molybdenum ore or mine waste rock, as described above. On this basis, a preferred comprehensive processing flow such as figure 2 Shown:

[0038] 1': Copper-molybdenum ore containing 0.33% copper and 0.018% molybdenum is used as raw material, crushed and ground to a fineness of -0.074mm with an occupancy rate of 65%, and the raw ore after grinding is prepared into a 35% raw ore slurry.

[0039] The raw ore pulp is adjusted to pH 7~9 with lime in the mixing tank, and according to the content of copper and molybdenum minerals in the raw ore and the amount of mud (the same below), add collector Ⅰ 38g / t, collector Ⅱ 15g / t, collector III 30g / t, foaming agent 50g / t, add ore dressing agent and stir for 4 minutes, use flotation machine to carry out roughing of copper-molybdenum mixed flotation twice to get copper-molybdenum mixed flotation Coarse c...

Embodiment 2

[0047] According to the treatment process of Example 1, the low-grade refractory mine waste rock discarded in the open-pit mining of copper mines with an average copper grade of 0.19% and a molybdenum grade of 0.01% was crushed and ground to a fineness of -0.074 The occupancy rate of mm is 60%, and it is prepared with water to make a raw ore slurry with a weight concentration of 25%~40%, put it in a mixing tank, add lime 1500g / t to adjust the pH value to 8~9, add collector diesel oil 20~60g / t, Ethyl xanthate 5~15g / t and butyl xanthate 5~20g / t, foaming agent terpineol oil 50~100g / t, after stirring, use a flotation machine to carry out 2 times of rough separation of copper and molybdenum mixed flotation , mix the rougher froth of the 1st and 2nd copper-molybdenum mixed flotation to obtain the coarse concentrate and middle ore of copper-molybdenum mixed flotation. The medium mine uses a flotation machine to carry out 2 times of sweeping, and the concentrate obtained from the firs...

Embodiment 3

[0054] According to the processing flow of Example 1, after the self-mining ore containing 0.25% copper and 0.02% molybdenum is crushed, it will be ground to a fineness of -0.074mm with an occupancy rate of 65% through a closed-circuit grinding system formed with a cyclone. After roughing raw materials with copper and molybdenum, add water to prepare a slurry with a weight concentration of 35%, add lime 2000g / t to the mixing tank to adjust the pH value to 8~9, add diesel oil 35g / t, ethylxanthate collector 20g / t, butyl xanthate 10g / t, No. 2 oil 110g / t. After stirring for 5 minutes, it enters the flotation machine, and carries out 2 times of copper-molybdenum mixed roughing and 1 time of sweeping. The concentrates of the second copper-molybdenum mixed roughing are combined into one to obtain copper-molybdenum mixed rough concentrate, and the concentrate obtained by sweeping is returned to the second copper-molybdenum mixed roughing as its raw material, and the copper grade of th...

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Abstract

The invention discloses a flotation separation method of low / extra-low grade copper-molybdenum ores or chats. The raw material is smashed until the fineness of the raw material is 0.074 mm, the occupying rate ranges from 50% to 80%, the raw material is prepared into ore pulp with the weight ranging from 25% to 40%, the PH value of lime is adjusted and ranges from 7 to 9, and then copper-molybdenum bulk flotation and rougher flotation are conducted by a flotation machine, so that copper-molybdenum bulk flotation rough concentrate is acquired; the copper-molybdenum bulk flotation rough concentrate is smashed until the fineness of the copper-molybdenum bulk flotation rough concentrate is 0.043 mm, the occupying rate ranges from 50% to 80%, and the copper-molybdenum bulk flotation rough concentrate is prepared into ore pulp with the weight ranging from 20% to 35%; a flotation column is adopted to conduct the detailed flotation of the copper-molybdenum bulk flotation, and copper-molybdenum bulk concentrate is acquired, the copper-molybdenum bulk concentrate is re-smashed until the until the fineness of the copper-molybdenum bulk concentrate is 0.038 mm, the occupying rate ranges from 70% to 90%, and the copper-molybdenum bulk concentrate is prepared into ore pulp with the weight ranging from 15% to 30%; the flotation column is used for conducting the rougher flotation of copper-molybdenum, one or more times of flotation on the occupied copper rough concentrate and molybdenum rough concentrate are conducted by the flotation machine / flotation column, and the final copper concentrate and molybdenum concentrate are acquired. The flotation separation method can deal with extra-low hard-flotation copper-molybdenum ores or chats with the copper grade lower than 0.2% and the molybdenum grade lower than 0.01%, and the copper concentrate with the copper grade higher than 23% and the molybdenum concentrate with the molybdenum grade higher than 43% are acquired.

Description

technical field [0001] The invention relates to a flotation separation method for low-grade and / or extra-low-grade copper-molybdenum ores or mine waste rocks, which can handle copper-containing <0.4%, molybdenum <0.03%, especially copper-containing <0.2% %, molybdenum <0.01% ultra-low grade refractory copper-molybdenum ore or mine waste rock discarded by mining, and obtain copper concentrate with copper grade > 23% and / or molybdenum concentrate with molybdenum grade > 43%. Background technique [0002] The commonly used method to obtain copper concentrate and molybdenum concentrate from copper-molybdenum ore dressing is flotation. The current flotation equipment mainly includes flotation machines and flotation columns. The flotation machine has the advantages of strong stirring power, large air volume, strong capture power and easy adjustment; the flotation column has the advantages of high enrichment ratio, simple structure and power saving, especially fo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B03D1/00B03B1/00
Inventor 邱允武代清华周正董大刚石磊艾立胜杜新李乾德王艳董天秋
Owner 四川省冶金地质勘查院
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