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Preparation method of water-soluble varnish compounded with Ag-carrying chitosan

A water-based varnish and chitosan technology, used in biocide-containing paints, polyester coatings, antifouling/underwater coatings, etc., can solve the problems of fast drying speed, low sterilization broad spectrum, small fineness, etc. , to achieve the effect of enhanced bactericidal effect, strong bactericidal broad-spectrum and excellent dispersibility

Active Publication Date: 2015-06-24
长兴艾飞特科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The disadvantage of the above two products is that the antibacterial ingredients are only physically mixed with other ingredients. Although they have an antibacterial effect, the dispersibility and effect are average.
The water-based ink for smoking water pine paper of the invention has the advantages of small fineness, fast drying speed, high consistency, low viscosity, good dispersion stability, no induration precipitation, no coagulation, no residual odor, etc., but the invention uses the fungicide directly Mixed into water-based ink, although the bactericide can play a bactericidal effect, but the bactericidal broad-spectrum of a single bactericide is small, the bactericidal effect is limited, and it may also be harmful to the human body and cause side effects

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] A kind of preparation method of the water-based varnish compounded with silver-loaded chitosan is carried out as follows, wherein the following material parts are parts by weight,

[0041] (1) Preparation of silver-loaded chitosan:

[0042] Take 10 parts of nano-chitosan and add it to 100 parts of deionized water and stir until dissolved, then add 10 parts of silver nitrate to the chitosan solution, stir evenly, add dilute nitric acid aqueous solution dropwise until the pH of the solution is 3-4, Then stir and heat in a water bath at 60°C for 3 hours under the condition of avoiding light, then centrifuge the suspension successively, wash the solid matter and dry it in vacuum, take 10 parts of the above solid matter and 0.5 part of sodium borohydride and add them to 0.01mol / L Add deionized water to the aqueous sodium hydroxide solution to adjust the pH to 7.5-8, and finally stir and centrifuge to collect the solid, wash and dry to obtain the silver-loaded chitosan.

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Embodiment 2

[0057] A kind of preparation method of the water-based varnish compounded with silver-loaded chitosan is carried out as follows, wherein the following material parts are parts by weight,

[0058] (1) Preparation of silver-loaded chitosan:

[0059] Take 10 parts of nano-chitosan and add it to 100 parts of deionized water and stir until dissolved, then add 10 parts of silver nitrate to the chitosan solution, stir evenly, add dilute nitric acid aqueous solution dropwise until the pH of the solution is 3-4, Then stir and heat in a water bath at 60°C for 3 hours under the condition of avoiding light, then centrifuge the suspension successively, wash the solid matter and dry it in vacuum, take 10 parts of the above solid matter and 0.5 part of sodium borohydride and add them to 0.01mol / L Add deionized water to the aqueous sodium hydroxide solution to adjust the pH to 7.5-8, and finally stir and centrifuge to collect the solid, wash and dry to obtain the silver-loaded chitosan.

[0...

Embodiment 3

[0076] A kind of preparation method of the water-based varnish compounded with silver-loaded chitosan is carried out as follows, wherein the following material parts are parts by weight,

[0077] (1) Preparation of silver-loaded chitosan:

[0078] Take 10 parts of nano-chitosan and add it to 100 parts of deionized water and stir until dissolved, then add 10 parts of silver nitrate to the chitosan solution, stir evenly, add dilute nitric acid aqueous solution dropwise until the pH of the solution is 3-4, Then stir and heat in a water bath at 60°C for 3 hours under the condition of avoiding light, then centrifuge the suspension successively, wash the solid matter and dry it in vacuum, take 10 parts of the above solid matter and 0.5 part of sodium borohydride and add them to 0.01mol / L Add deionized water to the aqueous sodium hydroxide solution to adjust the pH to 7.5-8, and finally stir and centrifuge to collect the solid, wash and dry to obtain the silver-loaded chitosan.

[0...

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Abstract

The invention relates to the technical field of water-soluble varnish and discloses a preparation method of water-soluble varnish compounded with Ag-carrying chitosan. The preparation method comprises the following steps: (1) preparing Ag-carrying chitosan; (2) compounding Ag-carrying chitosan with a water-soluble resin liquid A and a water-soluble resin liquid B and then compounding a mixed resin liquid with water-soluble wax emulsion, deionized water, ethanol, tea saponin, a defoaming agent, a levelling agent and a buffer agent, thus preparing the water-soluble varnish compounded with Ag-carrying chitosan. The preparation method has the beneficial effects that containing various antibacterial components, such as nano-silver, chitosan, titanium dioxide and tea saponin, the water-soluble varnish prepared by the preparation method has strong bactericidal broad-spectrum property; the bactericidal components have synergistic effects, so that the bactericidal effects are greatly enhanced; the dispersibility of the bactericidal components in the water-soluble varnish is quite outstanding.

Description

technical field [0001] The invention relates to the technical field of water-based varnish, in particular to a preparation method of water-based varnish compounded with silver-loaded chitosan. Background technique [0002] As a new green printing material, water-based varnish is widely used in the printing of food packaging, pharmaceutical packaging, cigarette packs, books, calendars, etc. Water-based varnish has excellent surface gloss, because its solvent is mainly water, not It will emit harmful volatile gases into the atmosphere, which is more environmentally friendly and conforms to the current concept of promoting environmental protection and health. Therefore, water-based varnish has a broad space for development in the future. [0003] For water-based varnish used in areas with high hygienic requirements such as cigarette packs, medical packaging, food packaging and printing, the water-based varnish itself is required to be non-toxic and harmless. However, although...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D133/00C09D161/20C09D167/06C09D175/04C09D5/14C09D7/12
CPCC08L2205/035C09D5/14C09D7/62C09D133/00C08L61/20C08L5/08C08L91/06C08K9/00C08K2003/0806C08K5/1545C08K9/06C08K2003/2237C08L75/04C08L35/00
Inventor 杨俊波杨志德
Owner 长兴艾飞特科技股份有限公司