Dianthracene compounds containing pyridyl at terminals and application thereof
A compound, the technology of dianthracene, applied in the field of dianthracene compounds, can solve the problems of single luminescence performance, shortened product life, unfavorable for industrial production, etc. Effect
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Embodiment 1
[0097] Preparation of compound HP-NP14-PY4
[0098]
[0099] Mix 1,4-dibromonaphthalene (4mmol, 1.14g), pyridine-4-boronic acid (4mmol, 0.49g) and tetrakis(triphenylphosphine) palladium (100mg), add toluene (6ml) / ethanol (6ml) / 2M Na 2 CO 3 (1ml) mixed solution. The reaction was stirred at 100 °C for 4 hours, then cooled to room temperature. The reaction system was diluted with water (50ml) and extracted with ethyl acetate (3*50ml). The organic phase was dried with anhydrous magnesium sulfate, the organic phase was concentrated and passed through a column with silica gel to obtain a pale white solid HP-NP14-PY4 (0.56 g, yield 50%).
Embodiment 2
[0101] Preparation of compound HP-NP14-PY3
[0102]
[0103] Compound HP-NP14-PY3 was obtained through the same reaction as in Example 1 except that pyridine-3-boronic acid was used instead of pyridine-4-boronic acid.
Embodiment 3
[0105] Preparation of Compound HP-NP14-PY2
[0106]
[0107] Except replacing pyridine-4-boronic acid with pyridine-2-boronic acid, compound HP-NP14-PY2 was obtained through the same reaction as in Example 1.
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