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Nanoparticle filling modified PBT powder

A nanoparticle modification technology, applied in the field of nanoparticle-filled modified PBT powder, can solve the problems of low notched impact strength, reduced mechanical properties, and high brittleness of PBT, and achieve excellent toughness, good processing fluidity, and excellent electrical properties Effect

Inactive Publication Date: 2015-08-19
QINGDAO WANLI TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Polybutylene terephthalate (PBT for short) is a crystalline polymer with excellent comprehensive performance and wide application, but its application is limited due to the shortcomings of PBT's high brittleness, low notched impact strength and insufficient toughness.
Although the use of elastomer toughening can improve the impact toughness of PBT, it greatly reduces its mechanical properties and affects its use.

Method used

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Embodiment Construction

[0016] The technical solutions of the present invention will be further described below in conjunction with specific embodiments.

[0017] A modified PBT powder filled with nanoparticles, its components are proportioned by mass percentage: PBT 71%, glass fiber 15%, nanoparticles 10%, anti-aging agent 2%, erucamide 0.8%, TAF 1%, Antioxidant 0.2%. Wherein, the PBT is polybutylene terephthalate resin; the glass fiber is an alkali-free chopped glass fiber with a diameter of 8-12 μm and the surface is treated with a silane coupling agent KH550; the nanoparticle It is nano-precipitated barium sulfate after surface activation treatment; the anti-aging agent is a compound of hindered amine light stabilizer HS-944 and HS-622 with a mass ratio of 1:1; the TAF is modified ethylene difatty acid Amide; the antioxidant is a compound of hindered phenolic antioxidant 1076 and phosphite antioxidant 168 at a mass ratio of 1:1.

[0018] Its preparation method is as follows: (1), dry PBT at 120...

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PUM

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Abstract

The present invention discloses a nanoparticle filling modified PBT powder, which comprises, by mass, 70-80% of PBT, 5-15% of glass fibers, 5-20% of nanoparticles, 0.5-2% of an anti-aging agent, 0.1-1% of erucylamide, 0.1-1% of TAF, and 0.1-0.5% of an antioxidant, wherein the nanoparticles are nanometer precipitation barium sulfate being subjected to a surface activation treatment. The nanoparticle filling modified PBT powder of the present invention has beneficial effects of good mechanical property maintaining, excellent toughness, excellent rigidity, excellent heat resistance, notched impact strength of 15-30 kJ / m<2>, tensile strength of 30-55 MPa, good processing fluidity, strong aging resistance, and excellent electrical property, can be used in the fields of manufacturing of electronic apparatuses, vehicles, machinery parts and the like, and has good prospects.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a modified PBT powder filled with nanoparticles. Background technique [0002] Polybutylene terephthalate (PBT for short) is a crystalline polymer with excellent comprehensive properties and wide application, but its application is limited due to the disadvantages of high brittleness, low notched impact strength and insufficient toughness of PBT. Although the use of elastomer toughening can improve the impact toughness of PBT, it greatly reduces its mechanical properties and affects its use. Contents of the invention [0003] The object of the present invention is to provide a nano particle filled modified PBT powder with good mechanical properties and impact toughness. [0004] The technical solution adopted by the present invention to solve the technical problem is: nano-particle filled modified PBT powder, its components are proportioned by mass percentage: PBT 70...

Claims

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Application Information

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IPC IPC(8): C08L67/02C08K13/06C08K9/06C08K7/14C08K3/30C08K5/20C08K5/134C08K5/526
Inventor 不公告发明人
Owner QINGDAO WANLI TECH
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