Coloring composition, coloring cured film and display device
A technology of coloring composition and colorant, which is applied in optics, optomechanical equipment, instruments, etc., can solve problems such as heat resistance problems, and achieve the effect of high contrast and excellent heat resistance
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[0289] Hereinafter, an Example is given and the embodiment of this invention is demonstrated more concretely. However, the present invention is not limited to the following examples.
[0290]
Synthetic example 1
[0292] A 100mL three-neck flask equipped with a stirring bar and a reflux cooling tube and a thermometer was fully replaced with nitrogen, 15.0g of cyclohexanone was added, and heated to an internal temperature of 80±2°C under nitrogen flow. 4.50 g of pigment monomer (A1) represented by the following formula, 6.00 g of methyl methacrylate, 4.50 g of methacrylic acid, As a polymerization initiator, 2.18 g of 2,2'-azobis(2,4-dimethylvaleronitrile) (manufactured by Wako Pure Chemical Industries, Ltd., trade name V-65) and 45.0 g of cyclohexanone were prepared by The solution. After completion of the dropwise addition, stirring was further continued at this temperature for 1 hour. Thereafter, the reaction liquid was cooled to room temperature and added dropwise to a large amount of hexane. The obtained colored solid was dried under reduced pressure at 50° C. to obtain 14.1 g of a polymer (1). The Mw of the obtained polymer (1) was 4800. Polymer (1) corresponds to polymer α.
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Synthetic example 2~4
[0295] In Synthesis Example 1, polymers (2) to (4) were obtained in the same manner as Synthesis Example 1 except that the type and amount of monomers used for polymerization were changed as shown in Table 1. The structures of the dye monomers (A1) to (A4) are as above. Polymer (2) corresponds to polymer α, and polymers (3) to (4) correspond to polymer β.
[0296] Table 1
[0297]
[0298] The symbols used in Table 1 are as follows.
[0299] MMA: methyl methacrylate
[0300] MA: methacrylic acid
[0301] In addition, the dye monomers (A1) to (A4) were synthesized with reference to the following publications, respectively.
[0302] Dye monomer (A1): synthesized according to Synthesis Example 2 described in paragraphs [0145] to [0146] of JP-A-2013-178478. Equivalent to monomer α.
[0303] Pigment monomer (A2): synthesized according to Example 1-1 described in paragraphs [0096] to [0097] of JP-A-2013-173850. Equivalent to monomer α.
[0304] Dye monomer (A3): synthesiz...
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