A composite piezoelectric material prepared from piezoceramic powder, carbon black and asphalt and a preparing method thereof

A technology of piezoelectric ceramics and piezoelectric materials is applied in the field of preparation of composite piezoelectric materials, which can solve the problems of reducing the degree of polarization of ceramics, increasing dielectric loss, insufficient polarization, etc., so as to improve the interface compatibility, The effect of improving piezoelectric performance and durable aging resistance

Inactive Publication Date: 2015-09-09
HARBIN ENG UNIV
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  • Summary
  • Abstract
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  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

If the polarization voltage is too low, the polarization effect will be poor, and the piezoelectric properties of piezoelectric materials cannot be fully utilized. If the polarization voltage is too high, it may break down the material, resulting in increased dielectric loss and insufficient polarization.
Conductive carbon black is a material with excellent electrical properties. It can not only improve the dielectric constant and conductivity of polymers and asphalt, but also solve the problems of interfacial compatibility, reduce the applied polarization voltage, and reduce the operating temperature. Difficulty, improve the piezoelectric response of the composite piezoelectric material; but the amount of carbon black needs to be strictly controlled, too much conductive carbon black will increase the conductivity of the composite material rapidly, and part of the electrical energy will be consumed in the form of leakage current and reduced The degree of polarization of the ceramic

Method used

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Experimental program
Comparison scheme
Effect test

specific Embodiment approach 1

[0023] (1) Raw materials are prepared in proportions by weight of 25-60 parts of asphalt, 2-5 parts of carbon black, 320-630 parts of piezoelectric ceramic powder and 1-10 parts of asphalt modifier.

[0024] (2) Pretreatment of piezoelectric ceramic powder: disperse 320 to 630 parts of piezoelectric ceramic powder and 2 to 5 parts of carbon black in step (1) in ethanol solution at 70°C, and then continuously stir in a magnetic stirrer until all the ethanol solution evaporated.

[0025] (3) Mixing of asphalt and modifier: put the asphalt in step (1) into a mold and heat to 170° C., then add the asphalt modifier in step (1) and stir for 5 minutes at a speed of 140 rpm.

[0026] (4) Mixing: Add the mixture of piezoelectric ceramic powder and carbon black obtained in step (2) and the mixture of asphalt and modifier obtained in step (3) and stir for 3 minutes at a stirring speed of 150 rpm to obtain a mixed material.

[0027] (5) Preheating the mold: put the mold into a drying ove...

specific Embodiment approach 2

[0033]This embodiment is based on Embodiment 1, and the asphalt is one or a mixture of petroleum asphalt and natural asphalt. Others are the same as the first embodiment.

[0034] When the asphalt described in this embodiment is a mixture, each component is mixed in any ratio.

specific Embodiment approach 3

[0035] This embodiment is based on the specific embodiment 1 or 2, and the piezoelectric ceramic powder is one or a mixture of lead-containing piezoelectric ceramic powder and lead-free piezoelectric ceramic powder. Others are the same as those in Embodiment 1 or 2.

[0036] The particle size of the piezoelectric ceramic powder in this embodiment is 0.5 μm to 70 μm, and the piezoelectric ceramic powder with a particle size of 0.5 μm to 2 μm and the piezoelectric ceramic powder with a particle size of 50 μm to 70 μm The volume ratio of powder is (0~5):1 mixture.

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Abstract

A composite piezoelectric material prepared from piezoceramic powder, carbon black and asphalt and a preparing method thereof are provided. The composite piezoelectric material is prepared from 25-60 parts by weight of the asphalt, 2-5 parts by weight of the carbon black, 320-630 parts by weight of the piezoceramic powder and 1-10 parts by weight of an asphalt modifier. The problems of interfacial compatibility and difficult polarization processes are overcome. The composite piezoelectric material can provide electricity for monitoring systems, can be used as sensors, and is good in compatibility with road surfaces. Natural asphalt and petroleum asphalt have good compatibility and durable ageing resistance, thus largely improving pavement performance of the substrate asphalt. The piezoceramic-carbon black-asphalt composite material improves interfacial compatibility of the piezoceramic and the asphalt, reduces the polarization voltage of the composite piezoelectric material, and improves piezoceramic properties of the composite piezoelectric material.

Description

technical field [0001] The invention relates to a composite piezoelectric material. The invention also relates to a preparation method of the composite piezoelectric material. Background technique [0002] China's highway system is gradually developing in the direction of informationization, technology and greening. While paying attention to the high-speed development of highways, more attention should be paid to the quality of highways and future maintenance work. With the increase in the functional requirements of road surfaces and the demand for long-term durability evaluation, it is necessary to monitor their health. However, existing sensors and The compatibility of the road surface is not good, not only it is easy to cause damage to the road surface and sensors, but also cannot accurately reflect the internal health status, such as: fiber grating sensors, electrostatic capacitance pressure sensors, etc. At the same time, the power supply of the existing online health...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B26/26C04B14/00
Inventor 吕建福孙雷郭庆勇王玮琛刘立明
Owner HARBIN ENG UNIV
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