The invention discloses a
lithium-rich
manganese-based positive
electrode material compositely coated with an alpha-ZrP-conducting
polymer, a preparation method of the
lithium-rich
manganese-based positive
electrode material and application of a
solid-state battery. According to the material, a bulk phase modified
lithium-rich
manganese-based material is used as a core, and a
composite coating layer composed of a delaminated alpha-ZrP
nanosheet and a
conductive polymer is constructed on the surface of the lithium-rich manganese-based material. The
composite coating layer can realize internal
proton self-exchange response with the
conductive polymer based on the
solid acid characteristic of alpha-ZrP, and an overpass type rapid
ion-
electron dual-
transmission channel is formed in the material body. Meanwhile, the
coating layer is used as a compact physical and chemical barrier, and harmful side reactions between the positive
electrode and the
solid electrolyte are effectively blocked. When the prepared positive
electrode material is applied to a solid-state battery, high first-circle coulombic efficiency and excellent
cycling stability and rate capability are shown, and the two core problems of unstable interface and slow dynamics of a lithium-rich manganese-based material in the solid-state battery are effectively solved.