65results about How to "Solve the problem of "white pollution"" patented technology

The invention discloses a method for preparing a bionic modified bamboo fiber reinforced polybutylene succinate (PBS) composite material. The method comprises the following steps: (1) screening a bamboo fiber, keeping the length less than 380mu m, and performing soaking treatment with a dopamine hydrochloride solution; 2) putting trismetyl aminomethane (Tris) into the soaked mixed system to adjust the pH value to alkalescence, stirring at normal temperature and normal pressure, filtering, and drying so as to obtain a polydopamine modified bamboo fiber of which the water content is less than 1%; and 3) uniformly mixing the modified bamboo fiber with PBS granules in a mass ratio of 1:1 in a high-speed mixing machine, pelletizing in a double-screw extruder, performing compression molding on mixed granules in a hot press, naturally cooling in a cold press, and demolding, thereby obtaining a modified bamboo fiber/PBS composite material. According to the method disclosed by the invention, dopamine has biocompatibility, the fiber is slightly damaged, no complex container is needed in the modification process, the production method is simple and convenient and safe and environmentally friendly, and the mechanical properties of the composite material are remarkably improved.

The invention provides totally biologically degradable polylactic acid composite material and a preparation method thereof, belonging to the technical filed of macromolecule composite material. The composite material is composed of knitted or unknitted natural fiber which is modified at the surface, polylactic acid and silane coupling agent. The method includes the following steps: getting specific amount of knitted or unknitted natural fiber and dipping the natural fiber in the aqueous solution of silane coupling agent for 1-100min, taking out and drying the natural fiber, thus producing natural fiber with modified surface; then pressing the polylactic acid into sheet in a plate vulcanization machine; disposing 2-10 polylactic acid sheets into a die and arranging one modified natural fiber sheet between every two polylactic acid sheets; pressing and molding the sheets; in this way totally biologically degradable polylactic acid composite material can be made. Compared with pure polylactic acid, the polylactic acid composite material is improved in both mechanical property and thermal property. The composite material after use can be totally degraded in natural environment; therefore the composite material is environment-friendly.

The invention belongs to the technological field of the polymer material, particularly relating to a preparation method of the completely biodegradable polyester copolymer. The invention uses the method of the fusion and direct polymerization to prepare the carboxyl-terminated lactic acid prepolymer and then copolymerize with the aliphatic polycarbonate; then the reaction is done in the twin-screw extruder to screw out the extension chain and the good polylactic acid copolymer is made. The concrete steps are: the lactic acid and small-molecule dicarboxylic acid react under the condition with the presence of the catalyst to directly polymerize the carboxyl-terminated lactic acid prepolymer; then the aliphatic polycarbonate diol and the catalyst are added; with the presence of the N2, the reaction is kept for 1 to 10 hours at the temperature of 150 to 200 Celsius system to get the poly lactic acid and polycarbonate copolymer of the low molecular weight; then the reaction is done in the twin-screw extruder at the temperature of 150 to 190 Celsius system to screw out the extension chain; finally the polylactic copolymer of the high molecular weight, toughness and heat resistance is made. The process of the method of the invention is simple and easy in the industrialized production; the copolymer resin product produced by the method is completely biodegradable and the application scope is wide.

The invention provides degradable polyurethane. The degradable polyurethane comprises the following raw materials by mass: 5.30 to 38.00% of poly(propylene carbonate) polyol, 0 to 31.00% of polyester dihydric alcohol, 0 to 15.50% of polyether dihydric alcohol, 9.20 to 13.50% of diisocyanate, 0.02 to 0.04% of a catalyst, 1.80 to 3.10% of a chain extender and 50.00% of an organic solvent, wherein the contents of the above-mentioned raw materials sum to 100%. The invention further discloses a preparation method for the polyurethane. The method comprises the following steps: preparing three precursors from weighed raw materials, selecting one of the three precursors, putting the selected precursor in a reaction vessel, subjecting the precursor to vacuum-pumping and dehydration so as to obtain a dehydrated precursor and then mixing diisocyanate, the catalyst and the dehydrated precursor so as to obtain a prepolymer; and mixing the organic solvent, the chain extender and the prepolymer so as to obtain the degradable polyurethane. The degradable polyurethane provided by the invention has good storage stability, excellent film properties and good degradability.

A highly-filled fully-biodegradable packaging material is obtained by mixing and extruding the following components on a weight basis: 70-90 parts of fillers, 10-30 parts of biodegradable polymer, 0.5-3 parts of coupling agents, and 2-5 parts of plasticizers. The fillers are dried at 100-200 DEG C to obtain a water content of not more than 0.5%; the coupling agent is mixed and stirred with the dried fillers according to a certain ratio in a high-speed mixing machine; the biodegradable polymer and the plasticizer are added proportionally, and well mixed; the mixture is extruded and granulated in an extruder to obtain a material for packaging; and the a material for packaging can be processed into various packaging materials by blow molding, injection molding, molding, and the like. When the packaging plastic of the invention becomes waste, the material can degrade into carbon dioxide, water and inorganic mineral in natural environment, which solves the problem of white pollution, and the material is a green and environment-friendly packaging material; the content of the inorganic filler is high, and reaches above 70%, which greatly decreases the production cost. The production cost is low; the preparation process is simple; and the economic practicality is strong.

The invention discloses a degradable rigid polyurethane foam material which is prepared by A and B components in the ratio of 1:1-1:1.1; wherein, the component A consists of materials with the following parts by weight: 50-100 portions of biomass polyols, 0-50 portions of general polyols, 0.3-5 portions of catalyst, 0.5-5 portions of water, 1-4 portions of silicone surfactant oil, 0-30 portions of physical foaming agent; the component B is pure industrial diphenyl-methane-diisocyanate. The invention also discloses a preparation method for the rigid polyurethane foam material. The method is that the component A is prepared by biomass polyols, general polyols, catalyst, water, silicone surfactant oil, and physical foaming agent in the ratio, the component A and component B are mixed and sprayed out for solidification by a polyurethane spray gun according to the proportion of 1:1-1.1. The degradable rigid polyurethane foam material is characterized by good soil burial degradability, thus solving the problem of 'white pollution' caused by using the traditional rigid polyurethane foam material.

The invention provides a preparation method for hollow polystyrene plastic spheres, and spheres prepared by the method, and an application of the spheres, and relates to the plastic field. The preparation method for the hollow polystyrene plastic spheres comprises the steps of dissolving an oil-phase solute in an organic solvent, adding a foaming agent, mixing uniformly to obtain an oil phase, wherein the oil-phase solute is polystyrene or a mixture of polystyrene and styrene monomers; dissolving a dispersing agent or the dispersing agent and an emulsifying agent in water to obtain a water phase; mixing the oil phase and the water phase uniformly, so as to make the oil phase dispersed uniformly in the water phase to obtain an emulsion; heating to evaporate the organic solvent while curing and foaming the oil-phase droplets; then separating a solid phase from the emulsion; and drying to obtain the hollow polystyrene plastic spheres. The hollow polystyrene plastic spheres have an internal hollow-core structure, are small in particles and controllable in particle size distribution, and can be well applied in the fields of petroleum drilling fluids, cosmetics, coatings, etc. The preparation method is simple in process and short in preparation time and can be easily industrialized.

The invention discloses a full-biodegradable starch-based in-situ fiber reinforced composite material and a preparation method thereof. The starch-based full-biodegradable in-situ fiber reinforced composite material comprises the components in parts by weight: 60-80 parts of natural starch, 15-25 parts of plasticizer, 5-20 parts of fiber-forming resin and 0.5-2 parts of compatibilizer. The preparation method comprises the three steps of: mixing the natural starch, the plasticizer and the fiber-forming resin with the compatibilizer for 20-30 minutes at high speed according to a certain ratio; carrying out melt blending and extrusion in a double-screw extruder with an extrusion temperature of 145-190 DEG C, an extrusion die temperature of 130-170 DEG C and a screw rotation speed of 20-40 r/min; and cooling in natural air; and pelletizing to prepare the starch-based in-situ fiber reinforced composite material. The full-biodegradable starch-based in-situ fiber reinforced composite material contains thermoplastic starch as high as over 80% and has good processing property and application performance.

The invention provides a method for producing an environmentally-friendly full-degradable liquid mulch film capable of turning into a fertilizer by using coal humic acid. The process comprises the following steps: finely selecting weathered coal, brown coal, peat or rogued turf, removing impurities, and then adding the coal into a crusher and crushing the coal into coal powder with the grain size of 100-150 meshes; adding raw materials into a reaction kettle in a raw material weight ratio of coal powder to potassium hydroxide to potassium carbonate to water equal to (100-120):(0.2-0.7):(0.2-0.6):(200-320), stirring, heating the mixture, standing for settling, and then taking liquid supernatant, thereby acquiring a potassium humate solution; and enabling raw materials to react in a raw material weight ratio of potassium humate solution to boric acid to potassium silicate to cellulose to cross-linking agent to water to propylene glycol monomethyl etheracetate to ammonium nitrate equal to (10-12):(1.8-2.5):(1.2-1.7):(0.15-0.17):(0.25-0.27):(20-30):(0.2-0.3):(0.1-0.2), thereby generating the environmentally-friendly full-degradable liquid mulch film capable of turning into the fertilizer. The process provided by the invention is used for producing the environmentally-friendly full-degradable liquid mulch film by using coal humic acid. After being used, the liquid mulch film is free from being cleared away and is turned into the fertilizer which is absorbed by crops, thereby solving the 'plastic pollution' problem of plastic mulch films.

A polylactic acid/polyadipate-butylene terephthalate (PLA/PBAT) modified material and a polyadipate-butylene terephthalate/thermoplastic starch (PBAT/TPS) modified material which can meet the blow molding requirement are prepared through melting reaction in a blending manner based on a multi-element blending modification technique of fully biodegradable materials; and a full-biodegrade three-layercoextrusion film is prepared by virtue of a multilayer coextrusion technique, the upper and lower layers are PLA/PBAT modified films, and the middle layer is a PBAT/TPS modifying film. The biology base content of the film can reach up to over 50%, the tensile strength is higher than that of a traditional PE film, the cost is relatively low, and the film has very important significances to the solving of ''white pollution'' problem and the promotion of the application of a full-biodegrade material in the field of waistcoat pockets.

The invention discloses a low-cost wood-plastic composite material and a preparation method thereof. The low-cost wood-plastic composite material comprises, by weight, 40-60 parts of corn stalks, 25-40 parts of sisal dregs, 35-50 parts of abandoned plastics, 15-20 parts of polyvinyl chloride, 3-5 parts of aramid fibers, 5-7 parts of cotton fibers, 6-9 parts of calcium stearate, 2-3 parts of antioxidant, 2-4 parts of light stabilizer and 3-5 parts of magnesium hydroxide fire retardant. The preparation method includes the processing steps of modified pretreatment, high-speed material mixing, hot press molding, cooling and shaping. According to the low-cost wood-plastic composite material and the preparation method thereof, the corn stalks, the sisal dregs and the abandoned plastics are comprehensively used as main raw materials, so that cost is lowered, and the environmental pollution problem of waste is further solved. The obtained wood-plastic composite material has the advantages of being high in compressive strength, high in abrasion resistance and the like. The wood-plastic composite material further has the advantages of being simple in processing technology, short in processing time, low in cost and the like, thereby being suitable for industrial production.

The invention provides a preparation method for a plastic hollow globule and the prepared plastic hollow globule and application thereof. The preparation method comprises the following steps: dissolving an oil phase solute in an organic solvent to obtain an oil phase, wherein the oil phase solute is polycarbonate or a mixture of polystyrene and/or a styrene monomer and polycarbonate; adding an emulsifier into water to obtain a first water phase; adding a dispersant or a mixture of the dispersant and the emulsifier into water to obtain a second water phase; fully emulsifying the oil phase and the first water phase to prepare a first emulsion; adding the second water phase into the first emulsion for complete emulsification so as to obtain a second emulsion and heating the second emulsion to allow the organic solvent to evaporate and an oil phase liquid drop to be cured and foamed; and carrying out liquid-solid separation, separating out a solid phase and drying the solid phase to prepare the plastic hollow globule with a hollow structure inside and an average particle size of 1 to 300 mu. The plastic hollow globule has a small and controllable particle size and can be used in fields like oil drilling fluids, cosmetics and paints.

The invention relates to a full-biodegradation bacterial cellulose/polylactic acid composite material and a preparing method thereof. The composite material is prepared from, by weight, 75 parts to 99 parts of polylactic acid, 1 part to 25 parts of bacterial cellulose and 1 part to 3 parts of coupling agents. The preparing method includes the steps that the polylactic acid and the bacterial cellulose are stirred to be mixed by weight, the coupling agents are added by weight, then the mixture is put into a mixing apparatus, the temperature is controlled to range from 170 DEG C to 220 DEG C, melt mixing is carried out, extruding and prilling are carried out, and premix particles are obtained; the premix particles are added into an injection molding machine or a compression molding machine, the temperature is controlled to range from 170 DEG C to 220 DEG C, the melting time is controlled to range from 2 min to 3 min, melt molding is carried out, and sample strips of the composite material are obtained; then drying treatment and heat treatment are carried out to increase the practical using temperature of the material. Compared with the prior art, the full-biodegradation bacterial cellulose/polylactic acid composite material and the preparing method thereof are simple in preparing technology, good in controllability, wide in raw material source and low in processing cost, and the prepared composite material is excellent in mechanical property, good in heat stability, capable of achieving full biodegradation in the natural environment and is environmentally friendly.

The invention provides a full-biomass porous material slow-release antibacterial active preservative film and a preparation method thereof. The full-biomass porous material slow-release antibacterialactive preservative film comprises 35-45 wt% of a matrix resin, 30-40 wt% of a biological porous substance, 20-25 wt% of an antibacterial agent and 0.9-1.3 wt% of a processing aid. The preparation method comprises the following steps: mixing the biological porous substance with the antibacterial agent to make the biological porous substance fully adsorb the antibacterial agent, mixing the obtainedmixture with the matrix resin and the processing aid, granulating the obtained mixture, and carrying out tape casting to prepare the film. Hyphae, pomegranate rind, shaddock peel, orange peel, bark and straw are porous substances, and can effectively adsorb the active antibacterial agent so as to achieve the slow release effect of the active antibacterial agent and improve the film performance, so that the long-term antibacterial effect on mutton is achieved; and the raw materials are degradable substances, so the pollution problem of agricultural byproducts and the white pollution problem ofplastic package can be solved, and the additional values of agricultural products can be improved.

The invention discloses a wood plastic floor resistant to acid and alkali corrosion and a production technology thereof, and belongs to the technical field of construction materials. The wood plastic floor is prepared from the following raw materials in parts by weight: 20 to 40 parts of waste and old PVC aggregate, 3 to 8 parts of PVC plastic particle, 40 to 70 parts of waste and old wood powder or fiber powder, 5 to 10 parts of active calcium carbonate, 1 to 3 parts of filler, 5 to 10 parts of processing aid, 1 to 5 parts of anti-aging auxiliary agent, 0.1 to 0.15 part of copper powder, 0.01 to 0.02 part of molybdenum disulfide, and 5 to 10 parts of PTFE pellet. The raw materials mentioned above are subjected to steps of granulating, mixing, extruding, and moulding to produce the wood plastic floor. Compared with the conventional wood plastic floors, the provided wood plastic floor has the advantages of good mechanical properties, strong performance on resisting acid and alkali corrosion, and low manufacturing cost.

The invention discloses a polylactic acid bio-based special material for a disposable syringe. The polylactic acid bio-based special material is prepared from, by weight, 100 parts of polylactic acid (PLA), 5-30 parts of toughening agent, 0.1-2 parts of nucleating agent and 0.1-0.5 part of antioxidant. A degradable material vinyl acetate and vinyl laurate copolymer (VAc-VL) is adopted as the toughening agent, and N,N'-dicyclohexyl-2,6-naphthalenedicarboxamide (TMB-5000) is adopted as the nucleating agent. According to the polylactic acid bio-based special material for the disposable syringe, transparent crystallization nucleation and reaction blending modification technologies are adopted, the polylactic acid bio-based special material which is uniform in microstructure, friendly to environment, high in size stability, good in transparency, resistant to high temperature and capable of meeting the national standard GB15810-2001 for the disposable syringe is developed out, the polylactic acid bio-based special material is suitable for manufacturing the disposable syringes through precise injection molding, and important significance to solving of the white pollution caused by disposable medical products is achieved.

The invention discloses a waste film shredding machine which can effectively shred waste films. The waste film shredding machine comprises a machine frame, a feeding conveyor, a first knife roller assembly, a second knife roller assembly, a shredding roller assembly, a first motor, a second motor and a third motor, wherein the feeding conveyor is arranged on the front side of the machine frame, the first knife roller assembly and the second knife roller assembly are rotatably arranged on the machine frame, the shredding roller assembly is rotatably arranged on the machine frame and located behind the first knife roller assembly and the second knife roller assembly, the first motor is arranged on the machine frame and is in transmission connection with the first knife roller assembly through a first transmission mechanism, the second motor is arranged on the machine frame and is in transmission connection with the second knife roller assembly through a second transmission mechanism, andthe third motor is arranged on the machine frame and is in transmission connection with the shredding roller assembly through a third transmission mechanism. The first knife roller assembly comprisesa rotating shaft rotatably mounted on the machine frame and a plurality of cutters mounted on the rotating shaft at intervals. The second knife roller assembly and the first knife roller assembly arethe same in structure, cutters of the second knife roller assembly and the cutters of the first knife roller assembly are close to each other and partially coincide.

The invention discloses a degradable double-layer plastic express bag and a preparation method thereof. The express bag comprises an outer layer bag body and an inner layer bag body, wherein, in mass percentage, the outer layer bag body comprises the following components: 10-30% of LDPE, 50-80% of LLPDE and 10-30% of white master batches, and the inner bag body comprises the following components: 10-30% of LDPE, 50-80% of LLPDE, 1-5% of black master batches, 1-5% of an anti-block agent, and 2-4% of EPI. In the express bag, the EPI is a completely biodegradable plastic additive, and has a characteristic of oxidizing plastics so as to achieve the function of degrading the plastics and solve the white pollution problem caused by the plastics.