Color-deepening finishing agent for dyed polyester textiles

A technology of polyester fabric and finishing agent, applied in fiber processing, textile and papermaking, etc., can solve problems such as restricting product development and promotion, and achieve the effect of improving color fastness performance, enhancing color depth effect, and saving textile resources.

Inactive Publication Date: 2015-09-09
科凯精细化工(上海)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Because the synthesis method adopts cationic emulsion polymerization instead of nonionic emulsifier, the development and promotion of products are limited

Method used

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  • Color-deepening finishing agent for dyed polyester textiles
  • Color-deepening finishing agent for dyed polyester textiles
  • Color-deepening finishing agent for dyed polyester textiles

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The preparation of the darkening finishing agent that dyed polyester fabric is used comprises the steps:

[0027] Add 1g of nano-titanium dioxide particles to 50mL of 5% triethanolamine aqueous solution, stir and mix for 2 hours, raise the temperature to 80°C, and add 50mL of γ-methacryloyl with a mass fraction of 0.5% (ethanol) dropwise. Oxypropyltrimethoxysilane was used for modification, and the stirring speed and reaction temperature were kept, and the reaction was carried out for 2 hours to prepare a modified nano-titanium dioxide emulsion. According to mass percentage, 2g of cetyltrimethylammonium bromide and 6g of fatty alcohol polyoxyethylene ether AEO-3 were dissolved in 50mL of deionized water, and 20g of octamethylcyclotetrasiloxane and 2g of N- (β-Aminoethyl)-γ-aminopropylmethyldimethoxysilane, and high-speed stirring, homogenization for 30 minutes to obtain a milky white pre-emulsion; dissolve 2g of cetyltrimethylammonium bromide Use 50mL of deionized wate...

Embodiment 2

[0033] The preparation of the darkening finishing agent that dyed polyester fabric is used comprises the steps:

[0034] According to the mass percentage, 0.1g of nano-titanium dioxide particles were added to 50mL of 0.5% octylphenol-10 aqueous solution, fully stirred and mixed for 1 hour, the temperature was raised to 75°C, and the mass fraction was added dropwise to 0.2% (the solvent was ethanol ) of γ-methacryloxypropyltrimethoxysilane for modification, keeping the stirring speed and reaction temperature, and reacting for 1 hour to prepare a modified nano-titanium dioxide emulsion. According to mass percentage, dissolve 2g of cetyltrimethylammonium bromide and 6g of fatty alcohol polyoxyethylene ether AEO-7 in 50mL of deionized water, add 20g of octamethylcyclotetrasiloxane and 2g of γ-ammonia dropwise Propyltriethoxysilane, and high-speed stirring, homogenization for 30 minutes, obtained a milky white pre-emulsion; 2g of cetyltrimethylammonium bromide was dissolved in 50mL...

Embodiment 3

[0041] The preparation of the darkening finishing agent that dyed polyester fabric is used comprises the steps:

[0042] According to the mass percentage, 2g of nano-titanium dioxide particles were added to 50mL of 5% Tween-80 aqueous solution, fully stirred and mixed for 1.5 hours, the temperature was raised to 60°C, and 50mL of 5% (solvent was ethanol) was added dropwise. γ-glycidyl etheroxypropyl trimethoxysilane was used for modification, and the stirring speed and reaction temperature were kept, and the reaction was carried out for 2 hours to prepare a modified nano-titanium dioxide emulsion. According to mass percentage, dissolve 2g octadecyltrimethylammonium chloride, 3g fatty alcohol polyoxyethylene ether AEO-3 and 3g octylphenol polyoxyethylene ether OP-10 in 50mL deionized water, and add 20g Hexamethyltrisiloxane and 1g N-(β-aminoethyl)-γ-aminopropylmethyldimethoxysilane were stirred at high speed and homogenized for 40 minutes to obtain a milky white pre-emulsion; 2...

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Abstract

The invention relates to a color-deepening finishing agent for dyed polyester textiles. Nano-titanium dioxide particles serving as solids and an amino modified polyorganosiloxane microemulsion serving as a film-forming material are compounded to form the color-deepening finishing agent for the polyester textiles. Due to the small grain size effect and the large specific surface area of the nanoparticles, the contact of the nanoparticles with fibers is increased and a relatively high adsorption rate can be formed; due to the flexibility and the film-forming property of the organic silicon junction fragment of the film-forming material covering the nanoparticles, the color-deepening finishing agent is capable of forming an uneven thin film capable of generating scattering reflection on the surface of the treated fabric, and consequently, the absorptive amount of the fabric to the incident light can be greatly increased, the reflected light can be reduced and the effect of enhancing the color depth of the fabric can be achieved. The dyed polyester textiles treated by use of the color-deepening finishing agent are deepened in color under the circumstance that the inherent characteristics of the dyed fiber products are not damaged; besides, the treated dyed polyester textiles have good color fastness and also have antibacterial property.

Description

technical field [0001] The invention belongs to the field of textile dyeing and finishing auxiliaries, in particular to a darkening finishing agent for dyeing polyester fabrics. Background technique [0002] As a traditional pillar industry of our country, the textile industry is widely used in industry, agriculture, aquatic products, medicine, national defense industry, etc., and plays a great role in promoting the development of the national economy. Synthetic fibers have been widely used in recent years because they are strong and can be mass-produced. Especially polyester fiber (that is, polyester), has the advantages of high strength, good elasticity, good dimensional stability, and wear resistance. Durable, it is a variety of synthetic fiber textiles with many varieties, large output and fast development. However, since there are basically no active groups in the polyester structure, there are few dyeing positions, high crystallinity, tight fiber structure, and smoot...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M11/46D06M15/643D06M23/00D06P5/02D06P5/08D06M101/32
Inventor 任一波周文张萍顾永欢
Owner 科凯精细化工(上海)有限公司
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