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Low-temperature self-welding method of carbon-coating copper nanowires

A copper nanowire, carbon coating technology, applied in welding equipment, metal processing equipment, manufacturing tools and other directions, can solve the problems of low working temperature and low solder utilization rate, and achieve high utilization rate of copper atoms, large flow rate adjustment range, and high working efficiency. low temperature effect

Active Publication Date: 2015-09-30
咸阳瞪羚谷新材料科技有限公司
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Problems solved by technology

[0007] The present invention mainly aims at the shortcomings and deficiencies in the field of nano-welding technology at present, and proposes a low-temperature self-welding method of carbon-coated copper nanowires based on the diffusion phenomenon of copper atoms after heating. The method has the advantages of low working temperature and large flow rate. Adjustable, high solder utilization rate and large-scale multi-point simultaneous welding, etc., are expected to be widely used in flexible electronic systems, semiconductor integrated circuits, micro-nano electronic device packaging, transparent electrodes and other fields

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[0020] The present invention will be further introduced below in conjunction with the accompanying drawings and specific implementation methods.

[0021] attached figure 1 It is a transmission electron microscope photo of copper nanowires coated with amorphous carbon shells on the surface synthesized by hydrothermal method in the present invention: figure 1 (a) is a photo of the nanowire at a lower magnification, and the diffraction spot proves the five-time twinning structure of the copper nanowire, figure 1 (b) is a high-resolution electron micrograph of the nanowires. It can be seen that the surface of the copper nanowires is covered by an amorphous shell. The details of the synthesis process of the whole copper nanowires are as follows:

[0022] Add 21 mg of copper chloride and 49 mg of glucose into 10 mL of deionized water in sequence, then add 180 mg of surfactant octadecylamine, and mix thoroughly for 5 hours with magnetic stirring; then transfer the solution to a 25 mL...

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Abstract

The invention discloses a low-temperature self-welding method of carbon-coating copper nanowires, and relates to the field of nano welding. According to the technical scheme of the welding method, the copper nanowires wrapped with carbon shells and provided with five-fold twinned crystal structures are synthesized through a hydrothermal method. When the copper nanowires are in lap joint to form point contact and heated under a low-vacuum condition to 40-70% of a bulk copper melting point, namely 300-725 DEG C, copper atoms diffuse and are accumulated at contact points through a channel formed by the carbon shells, and accordingly under the condition that no other welding flux is used, self-welding is achieved, and the effect that the copper nanowires are connected is achieved. The nano welding technology has the advantages that work temperature is low, flow speed is high, the range is adjustable, welding can be achieved at multiple points on a large scale at the same time, no welding flux is needed, and pollution is not caused. Tests prove that welding points have excellent mechanical and electric characteristics, and the method is expected to be widely used in the fields of flexible electronic systems, semiconductor integrated circuits, micro-nano electronic packaging, transparent electrodes and the like.

Description

technical field [0001] The invention relates to the technical field of nano-welding, in particular to a low-temperature self-welding method for carbon-coated copper nanowires. Background technique [0002] Nanomaterials have attracted widespread attention due to their unique optical, electrical, magnetic and other physical properties. Scientists and engineers have controllably prepared a variety of nanomaterials through various synthetic methods. However, if these nanomaterials are to be formed with a certain structure And functional devices, these materials must be assembled using certain welding techniques. However, because the traditional macroscopic welding method cannot operate on nanoscale materials, nano-welding technology has become a hot and difficult issue in the field of nano-scale research. [0003] At present, there are three main types of connection technologies at the nanometer scale, namely electron beam / ion beam assisted deposition (EBID / IBID), nano fusion ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B23K31/02
CPCB23K31/02
Inventor 单智伟陈凯万景春沈昊王晓光
Owner 咸阳瞪羚谷新材料科技有限公司
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