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High-glossiness heat-resistant ABS/PET (acrylonitrile-butadiene-styrene/polyethylene terephthalate) bottle chip composite material and preparation method thereof

A composite material and high-gloss technology, applied in the field of high-gloss and heat-resistant ABS/PET bottle flake composite material and its preparation field, can solve the problem of reducing the toughness of high-gloss ABS alloy resin, the heat resistance cannot be improved, and the toughness of the composite material is reduced. and other problems, to achieve the effect of improving surface gloss and heat resistance, excellent toughness and high mechanical strength

Inactive Publication Date: 2015-10-14
重庆友强高分子材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] With the rapid development of the home appliance industry and the continuous improvement of people's consumption requirements, in some application fields, injection molded products are required not only to have excellent impact toughness, but also to have extremely high surface gloss, for example: for flat-panel LCD TVs For products such as frames, bases, laptop casings, and audio casings, the conventional single ABS resin system is difficult to meet the above requirements, so people have developed high-gloss ABS, such as patents CN102532788A, CN101531801A, etc., using ABS and PET or PMMA, etc. Blending to improve the surface gloss of ABS, but in order to improve the gloss while maintaining the toughness of ABS, it is usually necessary to add a certain amount of toughening agent, but this will inevitably reduce the heat resistance of tough high-gloss ABS alloy resin Sex, and heat resistance is often a very important indicator in the application of ABS alloy resin system
Usually, the heat-resistant agent added to improve the poor heat resistance of the ABS alloy resin system often leads to a decrease in the toughness of the composite material; other components added to improve its gloss often lead to a decrease in the toughness of the composite material. Decrease, heat resistance can not be improved

Method used

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  • High-glossiness heat-resistant ABS/PET (acrylonitrile-butadiene-styrene/polyethylene terephthalate) bottle chip composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] A preparation method of a high-gloss heat-resistant ABS / PET bottle flake composite material, which adopts the following raw materials and is prepared according to the following steps:

[0037] 1) Raw material composition

[0038] ABS resin 100kg, the weight percentage of acrylonitrile in this ABS resin is 18%;

[0039] ABS high rubber powder 15kg, the percentage by weight of rubber in this ABS high rubber powder is 60%;

[0040] 20kg of PET bottle flakes, the raw material of the PET bottle flakes is the copolymerization product obtained by adding isophthalic acid with a weight percentage of 2% in the conventional PET polymerization process, and its light transmittance is 80%. The viscosity number is 0.70dl / g; the PET bottle flakes are recycled PET slices with a white and transparent appearance, and the slice size is selected as 5mm×5mm;

[0041] Compatibilizer 5kg, the compatibilizer is selected as styrene-acrylonitrile-glycidyl methacrylate copolymer, its melt index ...

Embodiment 2

[0049] A preparation method of a high-gloss heat-resistant ABS / PET bottle flake composite material, which adopts the following raw materials and is prepared according to the following steps:

[0050] 1) Raw material composition

[0051] ABS resin 100kg, the weight percentage of acrylonitrile in this ABS resin is 20%;

[0052] ABS high rubber powder 20kg, the percentage by weight of rubber in this ABS high rubber powder is 50%;

[0053] 30kg of PET bottle flakes, the raw material of the PET bottle flakes is the copolymerization product obtained by adding isophthalic acid with a weight percentage of 4% in the conventional PET polymerization process, and its light transmittance is 85%. The viscosity number is 0.75dl / g; the PET bottle flakes are white and transparent recycled PET slices, and the slice size is 8mm×8mm;

[0054] Compatibilizer 10kg, the compatibilizer is selected as styrene-acrylonitrile-glycidyl methacrylate copolymer, its melt index is 9g / 10min under the conditi...

Embodiment 3

[0062] A preparation method of a high-gloss heat-resistant ABS / PET bottle flake composite material, which is prepared by using the following raw material composition, and its process operation and other parameters are set the same as in Example 1:

[0063] ABS resin 100kg, the weight percentage of acrylonitrile in this ABS resin is 24%;

[0064] ABS high rubber powder 10kg, the percentage by weight of rubber in this ABS high rubber powder is 70%;

[0065] PET bottle flakes 40kg, the raw material of the PET bottle flakes is the copolymerization product obtained by adding isophthalic acid with a weight percentage of 3% in the conventional PET polymerization process, and its light transmittance is 82%. The viscosity number is 0.60dl / g; the PET bottle flakes are white and transparent recycled PET slices, and the slice size is selected as 10mm×10mm;

[0066] Compatibilizer 20kg, the compatibilizer is selected as styrene-acrylonitrile-glycidyl methacrylate copolymer, its melt index...

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Abstract

The invention relates to a high-glossiness heat-resistant ABS / PET (acrylonitrile-butadiene-styrene / polyethylene terephthalate) bottle chip composite material. The composite material is composed of the following substances in parts by weight: 100 parts of ABS resin, 10-20 parts of ABS high rubber powder, 20-40 parts of PET bottle chip, 2-20 parts of compatilizer, 5-25 parts of heat-resistance modifier, 0.1-1 part of antioxidant and 0.1-1 part of lubricant. The method widens the high-added-value reutilization range of the recovered PET bottle chips, saves the limited resources, lowers the cost of the ABS composite material, has the advantages of low carbon and environment friendliness, enhances the surface glossiness and heat resistance of the ABS composite material, and widens the application range of the ABS composite material.

Description

technical field [0001] The invention relates to a polymer compound composition, in particular to a high-gloss heat-resistant ABS / PET bottle flake composite material and a preparation method thereof. Background technique [0002] Polyethylene terephthalate (PET), because of its excellent chemical and physical properties and low price, is not only widely used in fiber production, but also used in a large amount in beverage bottle production. However, the wide application of PET in the field of edible liquid flexible packaging has brought about the recycling of a large number of waste PET beverage bottles. With the gradual increase in the amount of PET, the amount of PET bottle recycling is also gradually increasing. According to statistics, the average recycling rate of PET bottle flakes is 20.4%. Countries with high recycling rates such as Switzerland, Germany and Japan are 100%, 49% and 46% respectively, while my country is only 1.7%. At present, most of the recycled PET b...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L55/02C08L67/02C08L25/14C08L25/12C08K5/134C08K5/526C08K5/18C08K5/098C08K5/20B29C47/92B29C48/92
Inventor 刘伯林谭如友
Owner 重庆友强高分子材料股份有限公司
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