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Herbicide mixture and weeding microemulsion special for rhizoma atractylodis

A herbicide and mixture technology, applied in the field of pesticides, can solve the problems of short residual period, difficult degradation, environmental pollution, etc.

Inactive Publication Date: 2015-11-18
安徽新北卡化学有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, herbicide residues in the soil affect the persistence of herbicides and the safety of the environment
From the aspect of weed control, herbicides should have a certain residual period. If the residual period is too short, the weeding effect will not be good, but if the residual period is too long, it will cause phytotoxicity to the recommended crops.
However, from an environmental point of view, the shorter the residual period of herbicides, the better. Herbicides are too stable, not easy to degrade, and have a large amount of residues in the environment, which will cause environmental pollution.

Method used

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  • Herbicide mixture and weeding microemulsion special for rhizoma atractylodis
  • Herbicide mixture and weeding microemulsion special for rhizoma atractylodis
  • Herbicide mixture and weeding microemulsion special for rhizoma atractylodis

Examples

Experimental program
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preparation example Construction

[0037] Further preferably, the surfactant provided by the present invention is octylphenol polyoxyethylene ether sulfonate, and its preparation method comprises:

[0038] The first step, the chlorination of octylphenol polyoxyethylene ether;

[0039] The second step is the sulfonation of octylphenol polyoxyethylene ether after chlorination.

[0040] The first step is further specifically adding octylphenol polyoxyethylene ether (OP-4) and pyridine into the reaction vessel at a molar ratio of 1:1, adding thionyl chloride dropwise under constant temperature water bath conditions, chlorine The molar ratio of sulfoxide to octylphenol polyoxyethylene ether was 1.5:1, stirred and reacted at 70°C to 80°C for 2 hours, and chlorooctylphenol polyoxyethylene ether was synthesized.

[0041] The second step is further specifically adding chlorooctylphenol polyoxyethylene ether to water, the mass ratio of chlorooctylphenol polyoxyethylene ether to water is 1:1.5, and then adding sulfonatin...

Embodiment 1

[0047] Embodiment 1 octylphenol polyoxyethylene ether sulfonate

[0048] Mix 10 mol of octylphenol polyoxyethylene ether (OP-4) and 10 mol of pyridine into the reaction vessel, add 15 mol of thionyl chloride dropwise in a constant temperature water bath, stir and react at 80°C for 2 hours, and synthesize chlorooctyl Base phenol polyoxyethylene ether, get the obtained 7.5mol chlorooctylphenol polyoxyethylene ether and join in water, the mass ratio of chlorooctylphenol polyoxyethylene ether and water is 1:1.5, then add 5mol sulfonating agent Sodium sulfite (Na 2 SO 3 ), placed in a high-pressure reactor, and reacted at 150°C for 8 hours under vigorous stirring to obtain a light yellow viscous substance. The crude product was dissolved in a mixture of isopropanol and water with a volume ratio of 2:1, and then extracted with petroleum ether , to remove unreacted raw materials and other oil-soluble impurities, separate the lower layer, distill under reduced pressure, and dry in v...

Embodiment 2

[0050] Embodiment 2 Microemulsion 1

[0051] With phenoxypyramid 50g, metolachlor 40g, thifensulfuron-methyl 15g, imidazoquinac thifensulfuron-methyl 10g, surfactant 10g prepared in Example 1, emulsifier di-isooctyl succinate sulfonic acid Put 150g of sodium, 100g of cosolvent ethanol, 30g of antifreeze propylene glycol, and 40g of synergist synergist into the reaction kettle, stir evenly and completely dissolve, slowly add 600g of water, continue mixing and stirring for 2 hours, and obtain a microemulsion.

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Abstract

The invention provides a herbicide mixture and weeding microemulsion special for rhizoma atractylodis. The herbicide mixture or the weeding microemulsion comprises the following raw materials: effective active components, a surfactant, dioctyl sulfosuccinate sodium salt as an emulsifier, ethyl alcohol as a co-solvent, water, propylene glycol as an antifreezing agent and piperonyl butoxide as a potentiator, wherein the effective active components comprise saflufenacil, metolachlor, thifensulfuron methyl and imazaquin; the surfactant comprises one or more of octyl phenol polyoxyethylene ether sulfonate, fatty alcohol polyoxyethylene ether and naphthalene sulfonate formaldehyde condensate. The herbicide mixture and the weeding microemulsion have a quite good effect of eliminating rhizoma atractylodis weeds, and are safe, efficient, good in chemical degradation effect and small in residue quantity; the microemulsion can be used for eliminating weeds better through adopting the surfactant provided by the invention.

Description

technical field [0001] The invention relates to the technical field of pesticides, in particular to herbicide mixture and herbicide microemulsion of Atractylodes atractylodis. Background technique [0002] Atractylodes atractylodis is the most famous wild Chinese herbal medicine. It is the representative of the wild and authentic medicinal materials in Northeast China. It is also one of the most widely used wild medicinal materials. It is irreplaceable and indispensable. The current annual demand is about 3-4 kilotons. [0003] Atractylodes atractylodis had amazing brilliance, it is well known and paid attention to by the majority of drug dealers, and it is very popular. Cangzhu main functions: dry dampness and invigorate the spleen, dispel wind and cold, improve eyesight, and be used for abdominal fullness, diarrhea and edema, beriberi, flaccidity, rheumatic arthralgia, wind-cold cold, night blindness; governing dampness and spleen and stomach; fatigue and sleepiness; Dis...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A01N47/36A01P13/00A01N37/22A01N43/50A01N43/54
Inventor 汪长青
Owner 安徽新北卡化学有限公司
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