Herbicide mixture and weeding microemulsion special for rhizoma atractylodis
A herbicide and mixture technology, applied in the field of pesticides, can solve the problems of short residual period, difficult degradation, environmental pollution, etc.
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[0037] Further preferably, the surfactant provided by the present invention is octylphenol polyoxyethylene ether sulfonate, and its preparation method comprises:
[0038] The first step, the chlorination of octylphenol polyoxyethylene ether;
[0039] The second step is the sulfonation of octylphenol polyoxyethylene ether after chlorination.
[0040] The first step is further specifically adding octylphenol polyoxyethylene ether (OP-4) and pyridine into the reaction vessel at a molar ratio of 1:1, adding thionyl chloride dropwise under constant temperature water bath conditions, chlorine The molar ratio of sulfoxide to octylphenol polyoxyethylene ether was 1.5:1, stirred and reacted at 70°C to 80°C for 2 hours, and chlorooctylphenol polyoxyethylene ether was synthesized.
[0041] The second step is further specifically adding chlorooctylphenol polyoxyethylene ether to water, the mass ratio of chlorooctylphenol polyoxyethylene ether to water is 1:1.5, and then adding sulfonatin...
Embodiment 1
[0047] Embodiment 1 octylphenol polyoxyethylene ether sulfonate
[0048] Mix 10 mol of octylphenol polyoxyethylene ether (OP-4) and 10 mol of pyridine into the reaction vessel, add 15 mol of thionyl chloride dropwise in a constant temperature water bath, stir and react at 80°C for 2 hours, and synthesize chlorooctyl Base phenol polyoxyethylene ether, get the obtained 7.5mol chlorooctylphenol polyoxyethylene ether and join in water, the mass ratio of chlorooctylphenol polyoxyethylene ether and water is 1:1.5, then add 5mol sulfonating agent Sodium sulfite (Na 2 SO 3 ), placed in a high-pressure reactor, and reacted at 150°C for 8 hours under vigorous stirring to obtain a light yellow viscous substance. The crude product was dissolved in a mixture of isopropanol and water with a volume ratio of 2:1, and then extracted with petroleum ether , to remove unreacted raw materials and other oil-soluble impurities, separate the lower layer, distill under reduced pressure, and dry in v...
Embodiment 2
[0050] Embodiment 2 Microemulsion 1
[0051] With phenoxypyramid 50g, metolachlor 40g, thifensulfuron-methyl 15g, imidazoquinac thifensulfuron-methyl 10g, surfactant 10g prepared in Example 1, emulsifier di-isooctyl succinate sulfonic acid Put 150g of sodium, 100g of cosolvent ethanol, 30g of antifreeze propylene glycol, and 40g of synergist synergist into the reaction kettle, stir evenly and completely dissolve, slowly add 600g of water, continue mixing and stirring for 2 hours, and obtain a microemulsion.
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