Metal-resin bonded body, and production method therefor
A metal resin and manufacturing method technology, applied in the direction of metal material coating process, etc., can solve the problems such as the surrounding environment is not polluted, the effect of bonding strength and adhesion is not clear, etc.
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Embodiment 1
[0114] (1) Fabrication of aluminum base material after surface treatment
[0115] An aluminum substrate having a size of 50 mm×25 mm was cut out from a commercially available aluminum plate (A5052; plate thickness 2.0 mm). Next, by the treatment method A (formation of the zinc-containing film), a surface-treated aluminum substrate for a test in which an oxygen-containing film containing zinc element was formed on the surface was produced.
[0116] With regard to the obtained surface-treated aluminum substrate, the oxygen content, oxygen strength, and film thickness of the oxygen-containing film were measured.
[0117] The results are shown in Table 1.
[0118] (2) Resin composition
[0119] As the thermoplastic resin composition, a PPS-based resin composition [PPS (1)] containing additive compound a and additive compound b and 50% of an inorganic filler shown in Table 1 was used. The PPS resin composition [PPS(1)] has a melt viscosity of 230Pa·s (310°C, 1000s -1 ) resin co...
Embodiment 2~47
[0128] For the aluminum base material, film formation treatment of oxygen-containing film, oxygen-containing film, resin composition, and resin molding conditions as shown in Tables 1 to 8, respectively, an evaluation test of bonding strength was performed in the same manner as in Example 1.
[0129] In addition, 30wt% HNO was used in Example 29 3 In the solution and Example 30, 0.1 M NaOH water was used to adjust the conductivity of the hot water to the values shown in Table 5.
[0130] In addition, in Examples 3, 4, 12 to 14, 18, 23, 24, 29 to 34, 42, 43, 45, and 46, the same PPS-based resin composition [PPS (1)] as in Example 1 was used. . In addition, in Example 2 using PPS resin [PPS(2)], 40% by mass of glass-based filler was added to the resin composition, and in Examples 5-9, 15-17, 19- 22, 25 to 28, 35, 36, 44, and 47, and Examples 10 and 11 using PP, 30% by mass of glass filler was added to the resin composition, and in Examples 37 to 47 using POM In 40, 25% by m...
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