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Polystyrene composition, and heat insulation composite board produced by using composition

A styrene polymer and polystyrene technology, applied in the field of thermal insulation and flame retardant, can solve problems such as difficulty in obtaining market promotion, and achieve the effects of no decrease in mechanical properties and good flame retardant performance

Active Publication Date: 2015-12-23
TIANJIN SITANLI NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Most of the halogen-free flame-retardant products adopt inorganic flame-retardant series, and because of the obvious decline in the physical properties of expandable polystyrene products filled with inorganic substances, it is difficult to get market promotion

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Mix 150g of commercially available conventional uncolored expandable polystyrene pre-expanded particles cured as above with 1g of commercially available I-type room temperature-curable waterborne epoxy resin solution, and then mix with 250g of flame retardant binder (with In mass parts ratio, sodium silicate: sodium fluorosilicate: magnesium hydroxide = 80:10:10). After drying the mixture, the flame retardant coated pre-expanded beads were molded (300 x 300 x 50 mm) using standard expandable polystyrene equipment and molding conditions.

[0033] After the foam was dried in an oven for 48 hours / 70°C, it was further conditioned at 50% RH and 23°C for 24 hours before being cut into 190 x 90 x 20 mm specimens.

[0034] The compressive strength of the flame retardant board is 0.4MPa, the flame retardant effect is A2, and there is no obvious shrinkage and no dripping when encountering flames.

Embodiment 2

[0036]Mix 200 g of the expandable polystyrene flame retardant black pre-expanded particles (containing 5% carbon black) prepared by the extrusion method after curing as above, with 3 g of commercially available Type II room temperature-curable waterborne epoxy resin solution, and then After mixing with 200 g of flame retardant binder (in terms of mass parts ratio, sodium silicate: sodium fluorosilicate: aluminum hydroxide: red phosphorus=75:10:10:5). After drying the mixture, the flame retardant coated pre-expanded beads were molded (300 x 300 x 50 mm) using standard expandable polystyrene equipment and molding conditions.

[0037] After the foam was dried in an oven for 48 hours / 70°C, it was further conditioned at 50% RH and 23°C for 24 hours before being cut into 190 x 90 x 20 mm specimens.

[0038] The compressive strength of the flame-retardant board is 0.3MPa, the flame-retardant effect is A2, and there is no obvious shrinkage and no dripping when encountering flames.

Embodiment 3

[0040] 200g of the expandable polystyrene flame retardant black pre-expanded particles (containing 4% graphite) prepared by the extrusion method after curing as above were mixed with 3g of commercially available Type II room temperature-curable waterborne epoxy resin solution, and then mixed with Mixed with 200 g of flame retardant binder (in terms of mass parts ratio, sodium silicate: sodium fluorosilicate: magnesium hydroxide: red phosphorus=75:10:8:4). After drying the mixture, the flame retardant coated pre-expanded beads were molded (300 x 300 x 50 mm) using standard expandable polystyrene equipment and molding conditions.

[0041] After the foam was dried in an oven for 48 hours / 70°C, it was further conditioned at 50% RH and 23°C for 24 hours before being cut into 190 x 90 x 20 mm specimens.

[0042] The compressive strength of the flame-retardant board is 0.3MPa, the flame-retardant effect is A2, and there is no obvious shrinkage and no dripping when encountering flames...

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Abstract

The invention relates to a polystyrene composition. The polystyrene composition is prepared through mixing polystyrene beads, a coating adhesive and an inorganic flame retardation adhesive, wherein the inorganic flame retardation adhesive comprises silicate, fluosilicate and a flame retardant. The invention also relates to a high-flame retardation foam styrene polymer heat insulation composite board and an application thereof. The flame retardation performance of the heat insulation and flame retardation composite board produced in the invention is improved without reducing the mechanical strength or the toughness.

Description

technical field [0001] The invention relates to the field of thermal insulation and flame retardant, in particular to a polystyrene composition and a flame retardant thermal insulation composite board prepared therefrom. Background technique [0002] Expandable polystyrene (EPS) particles are polystyrene particles containing a physical blowing agent. After the polymer particles are pre-expanded by heating and matured, they are heated and formed into the desired polystyrene foam in a mold. The foam has a foaming ratio of 20-80 times, and has the structural characteristics of fine closed cells. [0003] The foam board made of expandable polystyrene (EPS) particles has been widely used in the fields of construction, cold storage, refrigerated vehicles and other thermal insulation due to its excellent and lasting thermal insulation properties. The external wall and external thermal insulation layer of polystyrene foam plastic sheets are used to realize building energy saving, i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L25/06C08L63/00C08K3/34C08K3/22C08K3/02C08K3/04C08J9/04
Inventor 周良陈志强
Owner TIANJIN SITANLI NEW MATERIAL