Silica gel based carbon material oriented heat conduction interface material and production method thereof

A technology of interface material and production method, which is applied in the field of silica gel-based carbon material-oriented thermally conductive interface materials, and achieves the effects of high mechanical properties, strong bonding ability, and simple production methods

Inactive Publication Date: 2015-12-30
PINGHU ALLIED IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The thermal conductivity of type II diamond reaches 10000W / m-K at a temperature of 77K, and the thermal conductivity of carbon nanotubes reaches between 3000 and 3500W / m-K at room temperature, surpassing the thermal conductivity of diamond and becoming the highest thermal conductivity. However, the above-mentioned carbon materials all have directionality in thermal conductivity, such as artificial graphite heat sinks, which have ultra-high thermal conductivity in the range of 1500-2500W / m-K in the plane, but only 10-20W / m-K in the vertical direction Thermal properties

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A heat-conducting interface material, comprising the following components by weight percentage: 9.5% of siloxane-based resin with a viscosity of 200cp-2000cp, 19.5% of heat-conducting filler, 70% of anisotropic carbon material, and 1% of auxiliary agent.

[0021] The thermal conductive filler is a mixture of alumina, boron nitride, aluminum hydroxide, and copper powder, and the mass ratio of alumina, boron nitride, aluminum hydroxide, and copper powder is 2:1:1:2, which has good practical performance and guarantees The thermal conductivity in the vertical direction of the carbon material orientation direction ensures the balanced heat conduction treatment of heat.

[0022] The anisotropic carbon material is a mixture of graphite and carbon fiber, and the mass ratio of graphite and carbon fiber is 3:2, which can improve the effect of directional heat transfer

[0023] The auxiliary agent is a mixture of silane coupling agent, anti-settling agent, defoaming agent and anti...

Embodiment 2

[0031] A heat-conducting interface material, comprising the following components by weight percentage: 15.63% of siloxane-based resin with a viscosity of 200cp-2000cp, 25.79% of heat-conducting filler, 53.76% of anisotropic carbon material, and 4.82% of additives.

[0032] The thermally conductive filler is a mixture of zinc oxide, silicon nitride, and aluminum powder, and the mass ratio of zinc oxide, silicon nitride, and aluminum powder is 2:2:1.

[0033] The anisotropic carbon material is carbon nanotube and graphene, and the mass ratio of carbon nanotube and graphene is 3:2.

[0034] The auxiliary agent is a mixture of aluminate coupling agent, platinum catalyst, leveling agent and antioxidant, and the mass ratio of aluminate coupling agent, platinum catalyst, leveling agent and antioxidant is 3:2:2:1.

[0035] A method for producing a thermally conductive interface material, comprising the following steps:

[0036] a) Put siloxane-based resin, aluminate coupling agent, p...

Embodiment 3

[0042] A heat-conducting interface material, comprising the following components by weight percentage: 20% of siloxane-based resin with a viscosity of 200cp-2000cp, 35% of heat-conducting filler, 35% of anisotropic carbon material, and 10% of additives.

[0043] The thermal conductive filler is aluminum nitride and copper powder, and the mass ratio of aluminum nitride and copper powder is 2:1.

[0044] The anisotropic carbon material is a mixture of carbon nanotubes, graphene and diamond, and the mass ratio of carbon nanotubes, graphene and diamond is 2:3:1.

[0045] The auxiliary agent is a mixture of titanate coupling agent, wetting agent and antioxidant, and the mass ratio of titanate coupling agent, wetting agent and antioxidant is 2:1:2.

[0046] A method for producing a thermally conductive interface material, comprising the following steps:

[0047] a) Put the siloxane-based resin and additives into the double planetary mixer for stirring, the vacuum degree in the doub...

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PUM

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Abstract

The invention relates to a silica gel based carbon material oriented heat conduction interface material. The material comprises components in percentage by weight as follows: 9.5%-20% of siloxane-based resin with the viscosity being 200 cp-2,000 cp, 19.5%-35% of heat conductive filler, 35%-70% of an anisotropic carbon material and 1%-10% of an auxiliary agent and is prepared with a stirring and curing production method. The silica gel based carbon material oriented heat conduction interface material has the advantages as follows: according to the heat conductive interface material prepared by mixing the siloxane-based resin with the viscosity being 200 cp-2,000 cp, the heat conductive filler, the anisotropic carbon material and the auxiliary agent, the anisotropic carbon material mixed in gel is orientated through electric fields on upper and lower surfaces, longitudinal orientation of the carbon material is realized, the conduction path of the heat conductive material is in the direction where the large heat conduction coefficient is large, and the heat conduction performance is realized to the maximum; with the addition of the heat conductive filler, the defect that the heat conduction performance of the carbon material in direction, perpendicular to the orientation direction, of the carbon material, namely, in the horizontal direction of mixed gel, is poor after the anisotropic carbon material is orientated is overcome, balanced conduction of heat is guaranteed, and a production method is simple.

Description

technical field [0001] The invention relates to a silica gel-based carbon material orientation type heat-conducting interface material and a production method thereof. Background technique [0002] Carbon is a non-metallic element, but it has the electrical and thermal conductivity of metal materials, as well as plasticity like organic plastics, and has special chemical stability, lubrication, and can be coated on solid surfaces. Some good technological properties. Carbon materials have a very large number of isomers, occupying a pivotal low position in terms of thermal properties. The thermal conductivity of different isomers of carbon materials spans a large range—five orders of magnitude—the thermal conductivity of amorphous carbon is 0.01W / m-K, and the thermal conductivity of diamond or graphene at room temperature is About 2000W / m-K. The thermal conductivity of type II diamond reaches 10000W / m-K at a temperature of 77K, and the thermal conductivity of carbon nanotubes...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/04C08K13/04C08K3/22C08K7/06C08K3/08C08K3/38C08K3/04C08K3/34C08K3/28C08K7/24
Inventor 范勇
Owner PINGHU ALLIED IND
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