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A kind of preparation method of chemical residue-free wallpaper base paper

A wallpaper and base paper technology, applied in paper, papermaking, textiles and papermaking, etc., can solve the problems of poor water solubility and less application of chitin natural polymer materials, increase stiffness and tensile strength, protect and resist The effect of good tensile energy and water solubility

Inactive Publication Date: 2017-07-07
FUJIAN YOUYA ENVIRONMENTAL PROTECTION WALLPAPER CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chitin has excellent spinnability. The chitin fiber prepared by wet spinning process not only has long-lasting, broad-spectrum antibacterial properties, is non-toxic, non-irritating to the human body, and can be biodegraded. It also has excellent synthetic properties. Silk, moderate fineness, good alkali resistance, easy dyeing, good moisture absorption and moisture conductivity, good air permeability, etc., are currently widely used in textiles, medicine and other fields to make various antibacterial and deodorant textiles, chitin sutures and artificial skin, but less in the paper industry
[0004] Chinese patent application number 201310307451.5 discloses the preparation of a new type of green environmental protection wallpaper, the following formula is disclosed: pulp 50-60%; coconut shell activated carbon 0-10%; negative ion additive: 0.5-20%; water 1.0-40% ;Adjuvant 0.1-20%, wherein the pulp contains chitin natural polymer material, which can play a certain antibacterial effect, but the chitin natural polymer material in the pulp has poor water solubility and cannot meet the requirements of sizing

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A method for preparing wallpaper base paper without chemical residues, comprising the following preparation steps:

[0019] (1) Preparation of modified chitin slurry: Weigh 50g of chitin, add 400ml of potassium hydroxide with a mass concentration of 25%, heat the reaction in a water bath for 30min, control the temperature of the water bath at 98°C, then adjust the pH to 7.0, and pump it with a vacuum pump filter, then add 15 g of chitin deacetylase, and react for 12 hours at a pH of 4.0 and a temperature of 40°C;

[0020] (2) Add the modified chitin slurry of step (1) in the pulp mixing tank, the amount of modified chitin slurry is 20% of the pulp weight;

[0021] (3) Internet surfing, pressing and drying;

[0022] (4) Add paper stiffness improver: the formula of the paper stiffness improver is: 2 parts by weight of chitosan alkenoic acid aqueous solution with a mass concentration of 3%, 1 part by weight of polyacrylamide aqueous solution, 2 parts by weight of acetic a...

Embodiment 2

[0025] A method for preparing wallpaper base paper without chemical residues, comprising the following preparation steps:

[0026] (1) Preparation of modified chitin slurry: Weigh 55g of chitin, add 450ml of potassium hydroxide with a mass concentration of 28%, heat the reaction in a water bath for 35min, control the temperature of the water bath at 99°C, then adjust the pH to 7.1, and use a vacuum pump Suction filtration, then add 16 g of chitin deacetylase, and react for 14 hours under the conditions of pH 4.2 and temperature 45°C;

[0027] (2) Add the modified chitin slurry of step (1) in the pulp mixing tank, the amount of the modified chitin slurry is 25% of the pulp weight;

[0028] (3) Internet surfing, pressing and drying;

[0029] (4) Add paper stiffness improver: the formula of the paper stiffness improver is: 2.5 parts by weight of chitosan alkenoic acid aqueous solution with a mass concentration of 3%, 1.5 parts by weight of polyacrylamide aqueous solution, 2 part...

Embodiment 3

[0032] A method for preparing wallpaper base paper without chemical residues, comprising the following preparation steps:

[0033] (1) Preparation of modified chitin slurry: Weigh 60g of chitin, add 500ml of potassium hydroxide with a mass concentration of 30%, heat the reaction in a water bath for 40min, control the temperature of the water bath at 100°C, then adjust the pH to 7.2, and use a vacuum pump Suction filtration, then add 18 g of chitin deacetylase, and react for 16 hours under the conditions of pH 4.5 and temperature 50°C;

[0034] (2) Add the modified chitin slurry of step (1) in the pulp mixing tank, the amount of the modified chitin slurry is 30% of the pulp weight;

[0035] (3) Internet surfing, pressing and drying;

[0036] (4) Add paper stiffness improver: the formula of the paper stiffness improver is: 3 parts by weight of chitosan alkenoic acid aqueous solution with a mass concentration of 3%, 2 parts by weight of polyacrylamide aqueous solution, 3 parts by ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The invention relates to the technical field of wallpaper preparation, and provides a method for preparing wallpaper base paper without chemical residues by applying modified chitin to the wallpaper field. The wallpaper prepared by the method has no chemical residues, is environmentally friendly and non-toxic, and It has antibacterial function, including the following preparation steps: (1) preparation of modified chitin slurry; (2) adding the modified chitin slurry in step (1) to the mixing tank, the amount of modified chitin slurry 20-30% of the pulp weight; (3) surfing, pressing, and drying; (4) adding paper stiffness improver; (5) drying: the drying temperature is controlled at 110-120 ° C, and the gradient temperature is used to dry slowly , The heating rate is 5-10°C / min.

Description

technical field [0001] The invention relates to the technical field of wallpaper preparation, in particular to a method for preparing wallpaper base paper without chemical residues. Background technique [0002] Wallpaper, also known as wallpaper, is a specially processed paper used to decorate walls. The birthplace of wallpaper is in Europe, and now it is the most popular in developed countries in Northern Europe, with the best environmental protection and quality, followed by Southeast Asian countries, and the penetration rate of wallpaper in Japan and South Korea is as high as nearly 90%. No matter in terms of production technology, process, or use, compared with other building materials, it can be said that wallpaper is the least toxic. The main raw materials of modern new wallpaper are made of bark and chemically synthesized pulp, which is very natural. When it is used, it will not emit harmful ingredients to human health, but its function is relatively single. In the...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D21H21/14D21H17/24
Inventor 商剑晖
Owner FUJIAN YOUYA ENVIRONMENTAL PROTECTION WALLPAPER CO LTD
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