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Method for Comprehensive Recovery of Phosphorus and Rare Earth from Monazite-containing Rare Earth Phosphate Rock

A monazite and rare earth technology, which is applied in the field of comprehensive recovery of phosphorus and rare earths, can solve the problems of failure to achieve effective recycling, inability to completely decompose monazite, and difficulty in effective sorting of ores, so as to achieve low-cost comprehensive recovery of rare earths and improve Rare earth recovery rate and the effect of improving the recovery rate

Active Publication Date: 2018-03-16
GRIREM ADVANCED MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When recovering rare earth elements and phosphorus elements in this mixed ore, it is difficult to achieve effective separation of ores by physical beneficiation due to the difficulty of enveloping and dissociation of various substances in the mixed ore
In particular, since the decomposition of monazite requires relatively harsh conditions, such as higher temperature and pH, etc., when using the sulfuric acid method in the prior art to wet treat phosphate rock containing monazite, it is often impossible to completely decompose monazite. can realize its effective recycling

Method used

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  • Method for Comprehensive Recovery of Phosphorus and Rare Earth from Monazite-containing Rare Earth Phosphate Rock
  • Method for Comprehensive Recovery of Phosphorus and Rare Earth from Monazite-containing Rare Earth Phosphate Rock

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-1

[0054] With 50g containing monazite 23.6%, the phosphate rock that the total amount of rare earth is 15.5% is raw material, and adopting mass concentration is 15% (in terms of P 2 o 5 Control the liquid-solid ratio of the system at 2:1, add 100mL of phosphoric acid solution, react at 55°C for 8 hours, and obtain 124mL of rare earth-containing monocalcium phosphate solution and 12g of monazite slag after filtration.

[0055] Add sodium carbonate to the solution containing monocalcium phosphate, adjust the pH of the solution to 0.5, and precipitate the rare earth in the solution, and obtain 130 mL of monocalcium phosphate solution and 5.5 g of phosphate-containing rare earth slag after filtration. After adjusting the pH value, the content of calcium ions in the dicalcium phosphate formed in the system accounts for 1.3% of the total content of calcium ions in the system.

[0056] Add sulfuric acid to the obtained monocalcium phosphate solution to remove calcium, and separate sol...

Embodiment 1-2

[0060] The preparation process is the same as that of Example 1-1, the difference is that, after adding phosphoric acid for leaching, instead of filtering, sodium carbonate is directly added to precipitate the rare earth in the solution, and a mixture of phosphate-containing rare earth slag and monazite-containing slag is obtained. scum. in:

[0061] The weight of the obtained mixed slag is 17.7g, which accounts for 35.4% of the weight of the phosphate rock raw material.

[0062] The amount of rare earth contained in the monocalcium phosphate solution obtained through testing and calculation is 0.37g; except for the rare earth contained in the monocalcium phosphate solution, other rare earths all enter the obtained mixed slag. At this time, the obtained rare earth amount is 7.38g , which is 95.2% of the total rare earth content in the phosphate rock raw material.

Embodiment 2-1

[0064] With 50g containing monazite 10.0%, the total amount of rare earth is 6.2% phosphate rock as raw material, adopting mass concentration is 18% (in terms of P 2 o 5 leaching with phosphoric acid solution, control the liquid-solid ratio of the system to 4:1, react at 60°C for 0.5h, and obtain a rare earth-containing monocalcium phosphate solution and monazite-containing slag after filtration.

[0065] Sodium hydroxide is added to the solution containing the monocalcium phosphate, the pH of the solution is adjusted to 1.0, the rare earth in the solution is precipitated, and the monocalcium phosphate solution and the phosphate-containing rare earth slag are obtained after filtering. After adjusting the pH value, the content of calcium ions in the dicalcium phosphate formed in the system accounts for 2.2% of the total content of calcium ions in the system.

[0066] Add sulfuric acid to the obtained monocalcium phosphate solution to remove calcium, and separate solid and liqu...

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Abstract

The invention discloses a method for comprehensively recycling phosphorus and rare earth from rare earth phosphorite containing monazite. The method includes the following steps that rare earth phosphorite containing monazite is obtained from phosphoric acid in a leaching manner, and a monocalcium phosphate solution containing rare earth and slag containing monazite are obtained through filtration; the monocalcium phosphate solution containing rare earth is processed through a precipitation method, dissolved rare earth precipitates, a monocalcium phosphate solution and rare earth slag containing phosphoric acid are obtained through filtration, and the rare earth slag containing phosphoric acid and slag containing monazite are mixed to form mixed slag; and phosphorus in the monocalcium phosphate solution is recycled, and rare earth in the mixed slag is recycled. Acid leaching is conducted by adding phosphoric acid, phosphorus in rare earth phosphorite containing monazite forms monocalcium phosphate high in solubility, and therefore monazite existing in a precipitation manner and phosphorus can be separated. Then, the monocalcium phosphate solution containing rare earth is processed through the precipitation method, and rare earth and phosphorus elements in phosphorite can be effectively separated. Rare earth and phosphorus are effectively separated through two times of separation steps, and therefore the rare earth recycling rate is increased.

Description

technical field [0001] The invention relates to the field of rare earth recovery, in particular to a method for comprehensively recovering phosphorus and rare earth from monazite-containing rare earth phosphate ore. Background technique [0002] Rare earth minerals often coexist with barite, calcite, apatite, silicate ore and other minerals in nature. Due to the different mineralization reasons of minerals, the occurrence state and content of rare earth elements in minerals are also different. In the rare earth-containing ores currently mined, the content of rare earth oxides is only a few percent, or even lower. In order to meet the needs of rare earth metallurgical production, the rare earth must be separated from other ores by beneficiation before smelting, so that the rare earth minerals can be enriched. The content of rare earth oxides in minerals enriched by ore dressing can reach more than 60%-70%. Minerals enriched with rare earths are usually called rare earth co...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22B3/06C22B3/44C22B59/00C01B25/01
CPCY02P10/20
Inventor 黄小卫王良士巫圣喜龙志奇冯宗玉崔大立董金诗黄莉
Owner GRIREM ADVANCED MATERIALS CO LTD
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