Plastic filling master batch and preparation method thereof

A technology for filling master batches and plastics, applied in the field of plastic filling master batches and their preparation, can solve the problems of difficulty in powder cleaning and conversion, large energy waste, and high manufacturing costs, and achieves less energy consumption, short operating procedures, and less dust. Effect

Active Publication Date: 2016-02-24
SHANGHAI KINGFA SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The traditional method is to add powder to the plastic through the side feeding method of the extruder, but there are problems in this method: a large amount of powder floats during the plastic processing process and it is difficult to clean the machine and change production
But this method also has great defects, the main defect comes from the manufacture of filler masterbatch
In the prior art, preheating, melting, plasticizing, kneading, cooling and other processes are required to manufacture filler masterbatches, resulting in a large waste of energy and high manufacturing costs; and the mixture must be in a melt state before it can be granulated, which limits the amount of fillers. The content is below 80%, which is not as high as the traditional way of adding powder; at the same time, this kind of masterbatch is only suitable for adding to filling products compatible with the masterbatch carrier resin, and the versatility is very poor

Method used

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  • Plastic filling master batch and preparation method thereof
  • Plastic filling master batch and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Take 90 parts of 3000 mesh calcium carbonate, 1 part of zinc stearate, 1 part of aminosilane coupling agent, put them into the mixer and mix for 1-5min, the speed is 1000rpm, and the surface temperature of the mixture is controlled at 40-50℃; Change, add 7.8 parts of liquid bisphenol A epoxy resin, continue mixing for 10-20min, control the temperature at 50-60℃; put 0.2 parts of maleic anhydride into the mixture and continue stirring for 5-15min, the temperature rises to 70- At 80°C, the masterbatch particles are basically formed, and the diameter of the obtained masterbatch is 0.1-1.0mm, which is spherical. At this point, the material can be discharged and cooled to obtain the finished masterbatch.

Embodiment 2

[0032] Take 85 parts of 1250 mesh talc powder, 1 part of zinc stearate, and 1 part of epoxy silane coupling agent, put them into the mixer and mix for 1-5min, the speed is 1000rpm, and the surface temperature of the mixture is controlled at 40-50℃; Keep it unchanged, add 12.8 parts of liquid bisphenol A epoxy resin, continue mixing for 10-20min, control the temperature at 50-60℃; put 0.2 parts of phthalic anhydride into the mixture and continue stirring for 5-15min, the temperature When the temperature rises to 70-80°C, the masterbatch particles are basically formed, and the diameter of the obtained masterbatch is 0.1-0.3mm, which is spherical. At this point, the material can be discharged and cooled to obtain the finished masterbatch.

Embodiment 3

[0034] Take 88 parts of 3000 mesh barium sulfate, 1 part of zinc stearate, and 1 part of titanate coupling agent, put them into the mixer and mix for 1-5 minutes, the speed is 1000 rpm, and the surface temperature of the mixture is controlled at 40-50 °C; No change, add 9.8 parts of liquid bisphenol A epoxy resin, continue mixing for 10-20min, control the temperature at 50-60℃; put 0.2 parts of methyl hexahydrophthalic anhydride into the mixture and continue stirring for 5-15min, the temperature rises At 70-80°C, the masterbatch particles are basically formed, and the diameter of the obtained masterbatch is 0.1-0.5mm, which is spherical. At this point, the material can be discharged and cooled to obtain the finished masterbatch.

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Abstract

The invention discloses plastic filling master batch which is prepared from the following components in parts by weight: 85 to 90 parts of padding, 0.5 to 1 part of lubricating agent, 0.5 to 1 part of coupling agent, 6 to 13 parts of binding agent and 0.1 to 0.5 part of curing agent; the binding agent is liquid bisphenol A-type ethoxyline resin, and the curing agent is maleic anhydride, phthalic anhydride, methyl tetrahydrophthalic anhydride or methylhexahydrophthalic anhydride; the invention also discloses the preparation method of the plastic filling master batch. Compared with the prior art, the plastic filling master batch provided by the invention has the characteristics of high purity, easiness in fluidity, high dispersion, no floating and environment friendliness. The method for preparing the master batch has the advantages of short flow, less energy consumption, and less dust during a production process.

Description

technical field [0001] The invention relates to the field of masterbatch production, in particular to a plastic filling masterbatch and a preparation method thereof. Background technique [0002] Mineral powder-filled modified plastics is one of the most important ways to modify plastics at present. It can not only achieve functional modification, but also greatly reduce material costs and improve market competitiveness. Commonly used fillers include talcum powder, calcium carbonate, barium sulfate and mica powder, etc. They have different shapes and particle sizes, but the common technical difficulty of their modified plastics is: how to smoothly add them to the matrix resin and distribute them evenly , At the same time, it can minimize the dust in the working environment. [0003] The traditional method is to add powder to the plastic through the side feeding method of the extruder, but there are problems in this method: a large amount of powder floats during the plastic ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L63/00C08G59/42C08K9/06C08K9/04C08K3/34C08K3/26C08K3/30C08J3/22
Inventor 周杰叶晓光钱永红杜赏
Owner SHANGHAI KINGFA SCI & TECH
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