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Rat-proof PVC (polyvinyl chloride) modified material and preparation method thereof

A technology of modified material and PVC resin, which is applied in the field of rodent-proof PVC modified material and its preparation, can solve the problems of poor thermal stability, mouse gnawing, poor fluidity, etc., and achieve excellent processing performance, fast plasticizing speed, and relative good capacitive effect

Inactive Publication Date: 2016-03-30
广东祺龙科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Polyvinyl chloride (PVC) is one of the earliest industrialized and widely used general-purpose thermoplastics. It has light weight, high strength, insulation, flame retardancy, corrosion resistance, It has the advantages of excellent comprehensive performance, low price and wide source of raw materials; but it also has the following disadvantages: 1. Poor toughness, easy to be brittle when impacted, so it cannot be used as a structural material. In addition, the brittleness of polyvinyl chloride is greatly affected by temperature. Large, the lower limit of general PVC products is -15°C, and the lower limit of soft PVC is -30°C; 2. Poor thermal stability, it begins to decompose HCl at 100°C, and decomposes more rapidly when it is higher than 150°C. The melting temperature of PVC is about 210°C; 3. The viscosity of PVC is extremely high and its fluidity is extremely poor, which limits its use to a certain extent.
[0005] The above-mentioned existing PVC sheathed cables, PVC plugs, PVC films and PVC pipes all have hidden dangers of being eaten by mice. Therefore, it is particularly important to develop a mouse-proof PVC material

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0054] A kind of anti-rat PVC modified material, described anti-rat PVC modified material comprises the raw material of following weight portion:

[0055] 80 parts of PVC resin

[0056] 45 parts plasticizer

[0057] Filling agent 25 parts

[0058] 3 parts heat stabilizer

[0059] Impact modifier 2 parts

[0060] Rodent-proof agent 0.8 parts

[0061] Lubricant 0.6 parts

[0062] 0.3 parts of other additives.

[0063] The PVC resin is a mixture of calcium carbide-based PVC resin and ethylene-based PVC resin in a weight ratio of 2:1.

[0064] The plasticizer is a mixture composed of diisononyl cyclohexane 1,2-dicarboxylate, triethyl citrate and epoxidized soybean oil in a weight ratio of 1.5:0.8:1.

[0065] The filler is a mixture of heavy calcium carbonate, light calcium carbonate and kaolin at a weight ratio of 1:0.8:1.

[0066] The heat stabilizer is a mixture of calcium-zinc composite heat stabilizer and hydrotalcite heat stabilizer at a weight ratio of 0.8:1; the cal...

Embodiment 2

[0076] A kind of anti-rat PVC modified material, described anti-rat PVC modified material comprises the raw material of following weight portion:

[0077] PVC resin 90 parts

[0078] 50 parts of plasticizer

[0079] Filling agent 30 parts

[0080] 4 parts heat stabilizer

[0081] Impact modifier 2.5 parts

[0082] Rodent-proof agent 1.0 parts

[0083] Lubricant 0.7 parts

[0084] 0.4 parts of other additives.

[0085] The PVC resin is a mixture of calcium carbide-based PVC resin and ethylene-based PVC resin at a weight ratio of 2.5:1.

[0086] The plasticizer is a mixture composed of diisononyl cyclohexane 1,2-dicarboxylate, triethyl citrate and epoxidized soybean oil in a weight ratio of 1.8:0.9:1.

[0087] The filler is a mixture of heavy calcium carbonate, light calcium carbonate and kaolin at a weight ratio of 1.2:0.9:1.

[0088] The heat stabilizer is a mixture of calcium-zinc composite heat stabilizer and hydrotalcite heat stabilizer at a weight ratio of 0.9:1; t...

Embodiment 3

[0098] A kind of anti-rat PVC modified material, described anti-rat PVC modified material comprises the raw material of following weight portion:

[0099] PVC resin 100 parts

[0100] 55 parts of plasticizer

[0101] Filling agent 35 parts

[0102] Heat stabilizer 5 parts

[0103] Impact modifier 3 parts

[0104] 1.2 copies of anti-rodent agent

[0105] Lubricant 0.8 parts

[0106] 0.5 parts of other additives.

[0107] The PVC resin is a mixture of calcium carbide-based PVC resin and ethylene-based PVC resin in a weight ratio of 3:1.

[0108] The plasticizer is a mixture composed of diisononyl cyclohexane 1,2-dicarboxylate, triethyl citrate and epoxidized soybean oil in a weight ratio of 2:1:1.

[0109] The filler is a mixture of heavy calcium carbonate, light calcium carbonate and kaolin at a weight ratio of 1.5:1:1.

[0110] The heat stabilizer is a mixture of a calcium-zinc composite heat stabilizer and a hydrotalcite heat stabilizer at a weight ratio of 1:1; the cal...

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Abstract

The invention relates to the technical field of PVC (polyvinyl chloride) materials, in particular to a rat-proof PVC modified material and a preparation method thereof. The rat-proof PVC modified material comprises raw materials in parts by weight as follows: 80-120 parts of PVC resin, 45-65 parts of a plasticizer, 25-45 parts of a filling agent, 3-7 parts of a heat stabilizer, 2-4 parts of an impact modifier, 0.8-1.6 parts of a rat proof agent, 0.6-1.0 part of a lubricating agent and 0.3-0.7 parts of other aids. According to the rat-proof PVC modified material, each property of the prepared rat-proof PVC modified material exceeds the national standard with the adoption of the raw materials and through strict control of the weight ratio of the raw materials, the rat proof effect is good, and the rat-proof PVC modified material is environment-friendly and has excellent temperature resistance and weather fastness, high strength, excellent impact resistance, good flame retardant effect, excellent processing performance and excellent overall performance.

Description

technical field [0001] The invention relates to the technical field of PVC materials, in particular to a rat-proof PVC modified material and a preparation method thereof. Background technique [0002] Polyvinyl chloride (PVC) is one of the earliest industrialized and widely used general-purpose thermoplastics. It has the advantages of light weight, high strength, insulation, flame retardancy, corrosion resistance, excellent comprehensive performance, low price and wide source of raw materials; but also There are the following disadvantages: 1. The toughness is poor, and it is easy to be brittle when impacted, so it cannot be used as a structural material. In addition, the brittleness of polyvinyl chloride is greatly affected by temperature. The lower limit of general PVC products is -15°C. The lower limit of use of PVC is -30°C; 2. Poor thermal stability, it begins to decompose HCl at 100°C, and decomposes more rapidly when it is higher than 150°C, and the melting temperatur...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08L91/00C08L23/28C08K13/02C08K3/22C08K5/20C08K3/38C08K3/26B29C47/92B29C48/92
CPCC08L27/06B29C48/92B29C2948/92704C08K2201/014C08L2201/02C08L2201/08C08L2205/025C08L2205/035C08L2205/06C08L91/00C08L23/286C08K13/02C08K3/2279C08K5/20C08K2003/387C08K2003/265
Inventor 宁建华
Owner 广东祺龙科技有限公司
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