Polyamide6-graphene quantum dot/carbon nanotube anti-static fiber and preparation

A technology of graphene quantum dots and anti-static fibers, which is applied in the manufacture of conductive/anti-static filaments and single-component polyamide artificial filaments. It can solve the problems of insufficient transparency of carbon nanomaterial dispersed fibers and reach the edge The effect of rich structure, excellent electrical conductivity, and small radial size

Inactive Publication Date: 2016-04-06
CHONGQING INST OF GREEN & INTELLIGENT TECH CHINESE ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0007] The object of the present invention is to provide a polyamide 6-graphene quantum dot / carbon nanotube antistatic fiber and its preparation, to solve the problem that the dispersibility of carbon nanomaterials in the composite fiber and the fiber transparency are not good enough, and the fiber has light weight, Good conductivity, high transparency, etc.

Method used

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  • Polyamide6-graphene quantum dot/carbon nanotube anti-static fiber and preparation

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Embodiment 1

[0026] A preparation method of polyamide 6-graphene quantum dot / carbon nanotube antistatic fiber, comprising the following steps:

[0027] 1. Preparation of graphene quantum dots / carbon nanotubes (GQD / CNT) composites

[0028] (1) Take 8g of graphene quantum dots and 4g of nonylphenol polyoxyethylene ether (OP-10), dissolve them in 488g of deionized water, and disperse them by ultrasonic (using an ultrasonic cell disruptor with a power of 2000W) to obtain uniform dispersion Graphene quantum dot aqueous solution;

[0029] (2) Add 4g of carbon nanotubes, 4g of nonylphenol polyoxyethylene ether (OP-10), and 492g of deionized water to (1), and then filter through ultrasonic dispersion with an ultrasonic cell disruptor (power 2000W) and centrifugation at 1000g , to obtain a uniformly dispersed GQD / CNT mixture. The graphite sheets of the graphene quantum dots used in this step are 1 to 3 layers, with a size of 10 to 100 nm, and the carbon nanotubes are single-walled carbon nanotube...

Embodiment 2

[0039] A preparation method of polyamide 6-graphene quantum dot / carbon nanotube antistatic fiber, comprising the following steps:

[0040] 1. Preparation of graphene quantum dots / carbon nanotubes (GQD / CNT) composites

[0041] (1) Get graphene quantum dot 10g, sodium lauryl sulfate 10g, be dissolved in the deionized water of 480g, through homogeneous dispersion (using super high pressure homogenizer JN-10HC, its power 2500W), obtain the evenly dispersed Graphene quantum dot aqueous solution;

[0042] (2) Add 2g of carbon nanotubes, 4g of sodium lauryl sulfate, and 494g of deionized water to (1), ultrasonically disperse with an ultrasonic cell disruptor (power 1000W), and filter after centrifugal force at 1000g to obtain evenly dispersed GQD / CNT mixed solution. The graphite sheets of the graphene quantum dots used in this step are 1 to 3 layers, with a size of 10 to 100 nm, and the carbon nanotubes are single-walled carbon nanotubes with a diameter of 2 to 10 nm and a length ...

Embodiment 3

[0052] A preparation method of polyamide 6-graphene quantum dot / carbon nanotube antistatic fiber, comprising the following steps:

[0053] 1. Preparation of graphene quantum dots / carbon nanotubes (GQD / CNT) composites

[0054] (1) Get graphene quantum dot 6g, alkylphenol polyoxyethylene ether 6g, be dissolved in the deionized water of 488g, through ultrasonic dispersion (using ultrasonic cell breaker, its power 4000W), obtain the graphene quantum dot of uniform dispersion aqueous solution;

[0055] (2) Add 10g of carbon nanotubes, 10g of alkylphenol polyoxyethylene ether, and 480g of deionized water to (1), and ultrasonically disperse them with an ultrasonic cell disruptor (power 2000W), filter them after centrifugal force at 1000g, and obtain evenly dispersed GQD / CNT mixed solution. The graphite sheets of the graphene quantum dots used in this step are 1 to 3 layers, with a size of 10 to 100 nm, and the carbon nanotubes are single-walled carbon nanotubes with a diameter of 2...

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Abstract

The invention provides polyamide6-graphene quantum dot/carbon nanotube anti-static fiber and preparation. According to the method, the molecular template effect of graphene quantum dots is utilized for being compounded with a carbon nanotube to form a self-assembled three-dimensional network structure first and then combined with a PA6 knitting state structure to form a dislocation effect to construct a conductive path, conductivity is improved on the condition of not losing a mechanical property of PA6 fiber, and meanwhile conductivity and the mechanical property of the PA fiber are promoted. Moreover, by means of compounding of the graphene quantum dots and the carbon nano tube and the self-assembled three-dimensional network structure, electronic transmission efficiency in the carbon nano tube is improved, a small quantity of GQD/CNT is added, conductivity of the fiber can be improved, and transparency is improved at the same time, which is beneficial for treatment technologies like dyeing in the fiber preparing process. By means of the traditional mature PA6 melt spinning technology, the high-strength and high-conductivity PA6-GQD/CNT composite fiber with tensile strength being 0.52-0.81 GPa and line resistance being magnitude 106 is prepared and can be applied to anti-static clothes, needle-punched carpet, filter felt, industrial non-woven fabric, medical supplies and the like.

Description

technical field [0001] The invention belongs to the technical field of composite fibers, and relates to a polyamide 6-graphene quantum dot / carbon nanotube antistatic fiber and its preparation. Background technique [0002] Static electricity can be generated when any two objects of different materials are in contact and then separated. The static charge is not terrible. The static electricity on the human body can sometimes accumulate to tens of thousands of volts. The terrible thing is that the static electricity is released unevenly and violently, which can easily cause circuit breakdown, fire, information interference and other vicious events. Therefore, the prevention of static electricity is very important. important. Anti-static textiles are commonly used in daily life to remove harmful static electricity, and anti-static fabrics are mainly woven with anti-static fibers. Antistatic fibers generally use conductive fibers and antistatic fibers. The antistatic effect o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F6/90D01F1/09C08G69/16
CPCC08G69/16D01F1/09D01F6/90
Inventor 褚金李朝龙张恒池铫史浩飞杜春雷
Owner CHONGQING INST OF GREEN & INTELLIGENT TECH CHINESE ACADEMY OF SCI
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