Copper chromium zirconium alloy and preparing method thereof

A copper-chromium-zirconium alloy technology, applied in the field of copper-chromium-zirconium alloy and its preparation, to achieve the effects of improving subsequent deformation ability, reducing electron scattering probability, and improving electrical conductivity

Active Publication Date: 2016-05-04
SHANTOU HUAXING (RAOPING) COPPER IND CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In summary, the existing chromium-zirconium copper alloys are difficult to meet the re

Method used

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Examples

Experimental program
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Effect test

Embodiment 1

[0023] In the present embodiment, the preparation method of chromium-zirconium-copper alloy comprises the following steps in sequence:

[0024] (1) Copper, chromium, zirconium, magnesium, and yttrium elements are prepared in proportion, and the cast slab is obtained through vacuum purification melting and split pouring;

[0025] In this step, by weight, the prepared raw materials contain: 1.3% chromium, 0.2% zirconium, 0.02% magnesium, 0.04% yttrium, and the balance is copper. Chromium element is added as chromium powder (the particle size of chromium powder is 200-500 mesh), zirconium element is added as zirconium sponge, magnesium element is added as magnesium-copper master alloy, yttrium element is added as yttrium-copper master alloy, and copper element is added as copper block ( Copper elements also include copper contained in magnesium-copper master alloys and yttrium-copper master alloys).

[0026] In this step (1), the process of vacuum purification smelting and split...

Embodiment 2

[0036] In the present embodiment, the preparation method of chromium-zirconium-copper alloy comprises the following steps in sequence:

[0037] (1) Copper, chromium, zirconium, magnesium, and yttrium elements are prepared in proportion, and the cast slab is obtained through vacuum purification melting and split pouring;

[0038] In this step, by weight, the prepared raw materials contain: 0.7% chromium, 0.3% zirconium, 0.08% magnesium, 0.1% yttrium, and the balance is copper. Chromium element is added as chromium powder (the particle size of chromium powder is 200-500 mesh), zirconium element is added as zirconium sponge, magnesium element is added as magnesium-copper master alloy, yttrium element is added as yttrium-copper master alloy, and copper element is added as copper block ( Copper elements also include copper contained in magnesium-copper master alloys and yttrium-copper master alloys).

[0039]In this step (1), the process of vacuum purification smelting and split p...

Embodiment 3

[0049] In the present embodiment, the preparation method of chromium-zirconium-copper alloy comprises the following steps in sequence:

[0050] (1) Copper, chromium, zirconium, magnesium, and yttrium elements are prepared in proportion, and the cast slab is obtained through vacuum purification melting and split pouring;

[0051] In this step, by weight, the prepared raw materials contain: 2.0% chromium, 0.07% zirconium, 0.05% magnesium, 0.02% yttrium, and the balance is copper. Chromium element is added as chromium powder (the particle size of chromium powder is 200-500 mesh), zirconium element is added as zirconium sponge, magnesium element is added as magnesium-copper master alloy, yttrium element is added as yttrium-copper master alloy, and copper element is added as copper block ( Copper elements also include copper contained in magnesium-copper master alloys and yttrium-copper master alloys).

[0052] In this step (1), the process of vacuum purification smelting and spli...

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Abstract

A copper chromium zirconium alloy comprises, by weight, 0.7% to 2.0% of chromium, 0.05% to 0.3% of zirconium, 0.01% to 0.08% of magnesium, 0.01% to 0.1% of yttrium and the balance copper. The invention further provides a preparing method of the copper chromium zirconium alloy. The preparing method sequentially comprises the following steps that firstly, the copper, the chromium, the zirconium, the magnesium and the yttrium are prepared according to the proportion and are subject to vacuum purified smelting and flow dividing type casting, and a casting blank is prepared; secondly, the casting blank is subject to homogenization treatment and hot extrusion, and a sheared billet is prepared; thirdly, the sheared billet is subject to solid-solution treatment; fourthly, the sheared billet obtained after the solid-solution treatment is subject to cold deformation machining; and fifthly, a material obtained after cold deformation machining is subject to aging treatment, and the needed copper chromium zirconium alloy is obtained. The copper chromium zirconium alloy has the good comprehensive performance, the room temperature tensile strength of the copper chromium zirconium alloy is larger than 520 MPa, the room temperature elongation of the copper chromium zirconium alloy is larger than or equal to 22%, the room temperature electric conductivity of the copper chromium zirconium alloy is larger than or equal to 90%IACS, and the 350 DEG C high-temperature tensile strength of the copper chromium zirconium alloy is larger than 390 MPa.

Description

technical field [0001] The invention relates to the technical field of copper alloy materials, in particular to a copper-chromium-zirconium alloy and a preparation method thereof. Background technique [0002] As a high-strength and high-conductivity precipitation-strengthened copper alloy, copper-chromium-zirconium alloys have important uses in the fields of rail transit, electronics, electric power, and equipment manufacturing. The key material of cast steel crystallizer and blast furnace cooling plate. Compared with foreign countries, my country's current copper-chromium-zirconium alloy still has a large gap, and the production volume is very small. The main problems are low alloy strength, low electrical conductivity, and poor processing performance, which cannot meet the current domestic economic development needs. [0003] In recent years, domestic research institutes of universities have carried out research and development of high-strength and high-conductivity copp...

Claims

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Application Information

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IPC IPC(8): C22C9/00C22F1/08
CPCC22C9/00C22F1/08
Inventor 杨院生佘京鹏李应举李立鸿张奎良钟敏冯小辉吴渊罗天骄
Owner SHANTOU HUAXING (RAOPING) COPPER IND CO LTD
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