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High-energy lithium iron phosphate battery doped with graphene

A lithium iron phosphate battery, high-energy technology, applied in battery electrodes, secondary batteries, circuits, etc., can solve the problems of short battery life, slow charging rate, poor conductivity, etc., and achieve long battery life, long-lasting charging and discharging, and safety The effect of sexual stability

Inactive Publication Date: 2016-05-04
SHENZHEN HENGFENG WEIZHI TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, lithium iron phosphate itself has poor conductivity, and the slow diffusion of lithium ions causes the disadvantages of low actual specific capacity, slow charging rate, and short endurance when the battery is charged and discharged at a high rate.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0012] In the embodiment of the present invention, a graphene-doped high-energy lithium iron phosphate battery uses lithium iron phosphate, lithium manganate or lithium manganese iron phosphate as the positive electrode active material, and the gram specific capacity of the positive electrode is 170mAh / g, and the first efficiency 98.8%, double-sided density of 11mg / cm 2 , the compacted density of positive electrode is 1.7g / cm 2 ;With graphite as the negative electrode active material, the gram specific capacity of graphite is 355mAh / g; the negative electrode compaction density is 1.2g / cm 2 , and the areal density of the negative electrode is calculated by taking the corresponding positive electrode active material excess ratio of 5%.

Embodiment 2

[0014] In the embodiment of the present invention, a high-energy lithium iron phosphate battery doped with graphene uses lithium iron phosphate, lithium manganate or lithium iron manganese phosphate as the positive electrode active material, and the gram specific capacity of the positive electrode is 175mAh / g, and the first efficiency 99%, double-sided density of 22mg / cm 2 , positive compaction density 2g / cm 2 ;With graphite as the negative electrode active material, the gram specific capacity of graphite is 358mAh / g; the negative electrode compaction density is 1.4g / cm 2 , and the areal density of the negative electrode is calculated based on the corresponding positive electrode active material excess ratio of 11%.

Embodiment 3

[0016] In the embodiment of the present invention, a graphene-doped high-energy lithium iron phosphate battery uses lithium iron phosphate, lithium manganate or lithium manganese iron phosphate as the positive electrode active material, and the gram specific capacity of the positive electrode is 180mAh / g, and the first efficiency It is 99.2%, and the double-sided density is 33mg / cm 2 , positive electrode compaction density 2.25g / cm 2 ;With graphite as the negative electrode active material, the gram specific capacity of graphite is 360mAh / g; the negative electrode compaction density is 1.6g / cm 2 , and the areal density of the negative electrode is calculated based on the corresponding positive electrode active material excess ratio of 17.5%.

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Abstract

The invention discloses a high-energy lithium iron phosphate battery doped with graphene. Raw materials of the high-energy lithium iron phosphate battery comprise a positive electrode active material adopting lithium iron phosphate, lithium manganate or lithium manganese iron phosphate and a negative electrode active material adopting graphene, the specific capacity of the positive electrode active material is 170-190 mAh / g, the initial efficiency is 98.8%-99.6%, the double-sided area density is 11-55 mg / cm<2>, and the positive electrode compaction density is 1.7-2.8 g / cm<2>. The specific capacity of graphene is 355-365 mAh / g, the negative electrode compaction density is 1.2-1.99 g / cm<2>, and the negative electrode area density is calculated according to the condition that the excess ratio of the corresponding positive electrode active material is 5%-30%. The high-energy lithium iron phosphate battery has the advantages of stable safety, high durability, small size, high charging speed, durability and long endurance; the electric energy is improved through improvement of tap density; the electric energy is improved by adding graphene to the positive electrode material, and compared with batteries in the like industry, the battery in the same size is more durable by higher than 20%.

Description

technical field [0001] The invention relates to a lithium battery, in particular to a graphene-doped high-energy lithium iron phosphate battery. Background technique [0002] A lithium battery is a primary battery that uses lithium metal or lithium alloy as the negative electrode material and uses a non-aqueous electrolyte solution. It is different from a rechargeable battery. Lithium-ion batteries are different from lithium-ion polymer batteries. The inventor of the lithium battery is Edison. Due to the very active chemical properties of lithium metal, the processing, storage and use of lithium metal have very high environmental requirements. Therefore, lithium batteries have not been used for a long time. With the development of microelectronics technology at the end of the 20th century, miniaturized equipment is increasing day by day, which puts forward high requirements for power supply. Lithium batteries have entered a large-scale practical stage. [0003] With the ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/0525H01M4/62
CPCH01M4/625H01M10/0525Y02E60/10
Inventor 刘巍
Owner SHENZHEN HENGFENG WEIZHI TECH CO LTD
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