Method for preparing actinidia chinensis preservative film master batch containing rare-earth complex
A technology of rare earth complexes and rare earth compounds, which is applied in the field of preparation of functional plastic film masterbatches, can solve the problems of failing to meet the commercialization needs of fresh kiwi fruit, and achieve the effects of strengthening antibacterial and fresh-keeping effects, rich resources, and material safety
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Embodiment 1
[0036] The components of the masterbatch consist of 6.36kg of linear low-density polyethylene, 1.0kg of tourmaline powder, 2.2kg of rare earth complexes, 0.25kg of diatomaceous earth, 0.11kg of oleic acid amide, and 0.08kg of sodium stearate.
[0037] Masterbatch is prepared according to the following steps:
[0038] 1. Preparation of rare earth complexes
[0039] (1) Dissolve 2kg chitin in 60L acetic acid solution, stir evenly, add 80L methanol, the solution is no longer viscous, add 1L acetic anhydride, react at 30°C for 1h, add the viscous liquid obtained from the reaction to 150 In ethanol, a precipitate is formed, the solid is filtered out, washed three times with absolute ethanol, dissolved in acetic acid solution, and the insoluble matter is filtered off to obtain an acetylated chitosan solution.
[0040] (2) Weigh a total of 2kg of lanthanum nitrate, yttrium nitrate, neodymium nitrate and cerium nitrate respectively according to the molar ratio of lanthanum, yttrium, ne...
Embodiment 2
[0048] The components of the masterbatch consist of 5.89kg of linear low-density polyethylene, 1.2kg of tourmaline powder, 2.4kg of rare earth complexes, 0.3kg of diatomaceous earth, 0.11kg of oleic acid amide, and 0.10kg of sodium stearate.
[0049] Masterbatch is prepared according to the following steps:
[0050] 1. Preparation of rare earth complexes
[0051] (1) Dissolve 2kg chitin in 60L acetic acid solution, stir evenly, add 80L methanol, the solution is no longer viscous, add 1L acetic anhydride, react at 30°C for 1h, add the viscous liquid obtained from the reaction to 150 In ethanol, a precipitate is formed, the solid is filtered out, washed three times with absolute ethanol, dissolved in acetic acid solution, and the insoluble matter is filtered off to obtain an acetylated chitosan solution.
[0052] (2) Weigh a total of 2kg of lanthanum nitrate, yttrium nitrate, neodymium nitrate and cerium nitrate respectively according to the molar ratio of lanthanum, yttrium, n...
Embodiment 3
[0059] The components of the masterbatch consist of 5.67kg of linear low-density polyethylene, 1.4kg of tourmaline powder, 2.4kg of rare earth complexes, 0.3kg of diatomaceous earth, 0.13kg of oleic acid amide, and 0.10kg of sodium stearate.
[0060] Masterbatch is prepared according to the following steps:
[0061] 1. Preparation of rare earth complexes
[0062] (1) Dissolve 2kg chitin in 60L acetic acid solution, stir evenly, add 80L methanol, the solution is no longer viscous, add 1L acetic anhydride, react at 30°C for 1h, add the viscous liquid obtained from the reaction to 150 In ethanol, a precipitate is formed, the solid is filtered out, washed three times with absolute ethanol, dissolved in acetic acid solution, and the insoluble matter is filtered off to obtain an acetylated chitosan solution.
[0063] (2) Weigh a total of 2kg of lanthanum nitrate, yttrium nitrate, neodymium nitrate and cerium nitrate respectively according to the molar ratio of lanthanum, yttrium, n...
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