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Method for preparing actinidia chinensis preservative film master batch containing rare-earth complex

A technology of rare earth complexes and rare earth compounds, which is applied in the field of preparation of functional plastic film masterbatches, can solve the problems of failing to meet the commercialization needs of fresh kiwi fruit, and achieve the effects of strengthening antibacterial and fresh-keeping effects, rich resources, and material safety

Inactive Publication Date: 2016-06-22
FUJIAN NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Preservation methods related to new preservatives such as oxalic acid treatment, 1-MCP treatment, ClO 2 Although some progress has been made in processing, etc., it still fails to meet the commercial needs of fresh kiwi fruit preservation, and there are many problems in actual promotion and application.

Method used

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  • Method for preparing actinidia chinensis preservative film master batch containing rare-earth complex
  • Method for preparing actinidia chinensis preservative film master batch containing rare-earth complex
  • Method for preparing actinidia chinensis preservative film master batch containing rare-earth complex

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] The components of the masterbatch consist of 6.36kg of linear low-density polyethylene, 1.0kg of tourmaline powder, 2.2kg of rare earth complexes, 0.25kg of diatomaceous earth, 0.11kg of oleic acid amide, and 0.08kg of sodium stearate.

[0037] Masterbatch is prepared according to the following steps:

[0038] 1. Preparation of rare earth complexes

[0039] (1) Dissolve 2kg chitin in 60L acetic acid solution, stir evenly, add 80L methanol, the solution is no longer viscous, add 1L acetic anhydride, react at 30°C for 1h, add the viscous liquid obtained from the reaction to 150 In ethanol, a precipitate is formed, the solid is filtered out, washed three times with absolute ethanol, dissolved in acetic acid solution, and the insoluble matter is filtered off to obtain an acetylated chitosan solution.

[0040] (2) Weigh a total of 2kg of lanthanum nitrate, yttrium nitrate, neodymium nitrate and cerium nitrate respectively according to the molar ratio of lanthanum, yttrium, ne...

Embodiment 2

[0048] The components of the masterbatch consist of 5.89kg of linear low-density polyethylene, 1.2kg of tourmaline powder, 2.4kg of rare earth complexes, 0.3kg of diatomaceous earth, 0.11kg of oleic acid amide, and 0.10kg of sodium stearate.

[0049] Masterbatch is prepared according to the following steps:

[0050] 1. Preparation of rare earth complexes

[0051] (1) Dissolve 2kg chitin in 60L acetic acid solution, stir evenly, add 80L methanol, the solution is no longer viscous, add 1L acetic anhydride, react at 30°C for 1h, add the viscous liquid obtained from the reaction to 150 In ethanol, a precipitate is formed, the solid is filtered out, washed three times with absolute ethanol, dissolved in acetic acid solution, and the insoluble matter is filtered off to obtain an acetylated chitosan solution.

[0052] (2) Weigh a total of 2kg of lanthanum nitrate, yttrium nitrate, neodymium nitrate and cerium nitrate respectively according to the molar ratio of lanthanum, yttrium, n...

Embodiment 3

[0059] The components of the masterbatch consist of 5.67kg of linear low-density polyethylene, 1.4kg of tourmaline powder, 2.4kg of rare earth complexes, 0.3kg of diatomaceous earth, 0.13kg of oleic acid amide, and 0.10kg of sodium stearate.

[0060] Masterbatch is prepared according to the following steps:

[0061] 1. Preparation of rare earth complexes

[0062] (1) Dissolve 2kg chitin in 60L acetic acid solution, stir evenly, add 80L methanol, the solution is no longer viscous, add 1L acetic anhydride, react at 30°C for 1h, add the viscous liquid obtained from the reaction to 150 In ethanol, a precipitate is formed, the solid is filtered out, washed three times with absolute ethanol, dissolved in acetic acid solution, and the insoluble matter is filtered off to obtain an acetylated chitosan solution.

[0063] (2) Weigh a total of 2kg of lanthanum nitrate, yttrium nitrate, neodymium nitrate and cerium nitrate respectively according to the molar ratio of lanthanum, yttrium, n...

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Abstract

The invention relates to a method for preparing an actinidia chinensis preservative film containing a rare-earth complex. The technical scheme is as follows: the method comprises the steps: weighing acrylamide and purple soil powder, of which the grain size is 125 microns to 150 microns, putting the acrylamide and the purple soil powder into a reactor, adding distilled water into the reactor, heating the reactor to the temperature of 75 DEG C to 90 DEG C, adding potassium persulfate into the reactor with stirring, carrying out a stirring reaction for 1.5 to 2.5 hours at the temperature of 75 DEG C to 90 DEG C, adding an oil tea fruit peel extract into the reactor, and carrying out a stirring reaction for 1 to 3 hours at the temperature of 75 DEG C to 90 DEG C; adding a 10% (mass concentration) sodium hydroxide solution into the reactor, carrying out a stirring reaction for 1 to 3 hours at the temperature of 75 DEG C to 90 DEG C, adding acid to adjust the pH value to 7, and carrying out drying and crushing, thereby obtaining an oil tea fruit peel extract flocculant. According to the method, the oil tea fruit peel extract is used as a preparing raw material, the source is wide, and the cost is low; the comprehensive utilization of the oil tea fruit peel extract is facilitated, and the emission of wastes is reduced. The method has the advantages that the preparation process is simple, the conditions are mild, the cost is relatively low, the degradation is easy, the use is safe, and the like.

Description

technical field [0001] The invention relates to a preparation method of a functional plastic film masterbatch, in particular to a preparation method of a kiwifruit fresh-keeping film masterbatch containing a rare earth complex. Background technique [0002] Actinidia chinensis Planch belongs to Actinidia chinensis Planch, which is a high-grade fruit with high nutritional value, medicinal value and fresh eating rate. The fruit is sweet and sour, delicious and nutritious, especially famous for being rich in vitamin C. It is known as the "king of vitamin C". Kiwifruit has a long history of cultivation in my country. In recent years, with the continuous acceleration of the kiwifruit industry, the planting area and output of kiwifruit in my country have leapt to the first place in the world. However, the production period of kiwi fruit is concentrated, and the fruit is easy to lose water and shrink, soften and rot after harvesting, which greatly limits the development of kiwi fr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L5/08C08K9/10C08K3/34C08K9/04C08K3/38C08B37/08C08J3/22
CPCC08B37/003C08J3/226C08J2323/08C08J2423/08C08L23/0815C08L2203/16C08L5/08C08K9/10C08K3/34C08K9/04C08K2003/387
Inventor 黄雅卿卢玉栋陈彩珍李博文
Owner FUJIAN NORMAL UNIV