1151 results about "Lanthanum nitrate" patented technology

The invention relates to a preparation method of an SCR denitration catalyst, which comprises the following steps: (1) Al2O3 sol is prepared, which comprises the steps that hot ammonia, the Al2O3 is added in drops into the ammonia and then HCI is added and the mixture is stirred; (2) Al2O3-SiO2-TiO2 composite sol is prepared, which comprises the steps that tetratethoxy-silane, butyl titanate, deionized water are sequentially put into ethanol to be aging and then the sol prepared by step (1) is adding to be stirred and aging; (3) vector is coated, which comprises the steps that cordierite honeycomb immersed into the sol of step (2) and the raffinate in a channel is cleaned, dried and roasted after being taken out; (4) active component impregnating solution is prepared, which comprises the steps that lanthanum nitrate, ammonium metavanadate and ammonium paratungstate are dissolved into the deionized water after being mixed together and oxalate acid is added to be aging; (5) the active component is loaded, which comprises the steps that the vector of the step (3) is immersed into the impregnating solution of the step (4) and then the raffinate in the channel is cleaned to be dried and roasted. The invention also relates to the denitration catalyst which is prepared by the method.

The invention belongs to the new field of chemical engineering, and particularly relates to a nano material with clay as a carrier and perovskite type compound nano particles as active components and a preparation method and application thereof to the field of optical coupling-SCR denitration. Lanthanum nitrate, nickel nitrate, ferric nitrate, citric acid and the clay are added to deionized water to be stirred, then the mixture is transferred into a water bath kettle to evaporate to obtain wet gel, and the nano material can be obtained through drying, calcining and drying. The composite is adopted as a catalyst for photocatalytic denitration, and compared with traditional SCR denitration, the amount of adopted NH3 is reduced, and the conversion efficiency on NO at low temperature is improved.

The invention relates to a method for preparing a catalyst for preparing synthesis gas by reforming methane and carbon dioxide, which comprises the following steps: soaking a carrier into a mixed solution of cerium(III) nitrate and lanthanum nitrate, and drying and roasting the soaked carrier for 2 to 10 hours to obtain a modified carrier (A); soaking the (A) into a soluble nickel salt solution orsoaking the (A) into a chloroplatinic acid solution, and drying and roasting the soaked carrier to obtain (B) or (C); soaking the (B) into the chloroplatinic acid solution or soaking the (C) into thesoluble nickel salt solution, and drying and roasting the soaked carrier to obtain a catalyst precursor, or soaking the modified carrier into a mixed solution of the soluble nickel salt solution andthe chloroplatinic acid, and drying and roasting the soaked carrier to obtain a catalyst precursor; and reducing the precursor in hydrogen and nitrogen mixed gas to obtain the catalyst. The catalyst has the advantages of low cost, good catalytic activity under the reaction condition of large space velocity, high selectivity for H2 and CO, and good sintering resistance and carbon deposition resistance.

A Fe-based catalyst for the Fischer-Tropsch synthesis contains Re2O3, Fe3O4, La2O3, CuO, K2O and SiO2. It is prepared through using oxidant to oxidize partially the ferrous sulfate to obtain the mixed solution of iron sulfate and ferrous sulfate, mixing with the mixed solution of lanthanum nitrate and copper salt, fast depositing by alkaline compound, washing the deposited slurry, adding potassium silicate-water glass solution, and spray drying.

The invention discloses a preparation method of a rare-earth-based composite multi-component denitrification and dioxin removal catalyst. According to the preparation method, titanium dioxide (titanium white) and silicon powder as carriers and ammonium metatungstate, ammonium metavanadate, cerous nitrate and lanthanum nitrate as active components, the steps of mixing, kneading, molding, drying and roasting are carried out in the presence of auxiliary materials to prepare the catalyst, wherein the auxiliary materials include monoethanolamine, citric acid, ammonium hydroxide, lactic acid, stearic acid, glass fibers, macromolecular polymer fibers RP-CHOP, hydroxypropyl methyl cellulose, polyoxyethylene and water. The prepared catalyst can simultaneously decompose nitric oxides and dioxin and can improve the mercury removal efficiency of the existing smoke control device. The prepared catalyst is not only applicable to new power plants, but also suitable for the modification of a wet-method desulphurization device of an old power plant, 80 to 95 percent of HgO generated in a coal burning power plant can be oxidized to Hg<2+> by utilizing the prepared catalyst, and a majority of particle-state Hg<2+> can be removed by utilizing a dust removal device.

The invention discloses a high-precision rare-earth polishing powder and a method for preparing the same. The high-precision rare-earth polishing powder is characterized in that D50 particle diameter is between 0.5 and 1.80 mu m; the powder also meets the conditions that D10 is more than or equal to 0.5D50, D90 is less than or equal to 2D50, and D100 is less than or equal to 3D50; a cerium lanthanum nitrate or cerium lanthanum chloride solution is added to an ammonium oxalate solution with PH value of between 4.5 and 5.5 to generate monodisperse lanthanum cerium oxalate or lanthanum cerium praseodymium oxalate deposit; and the deposit is used as a crystal seed to prepare the high-precision rare-earth polishing powder. The high-precision rare-earth polishing powder prepared by the method does not need airflow pulverization and precise classification and has the characteristics of small median particle diameter and narrow granularity distribution range; the stability of the wearing resistance and polishing precision is easy to control; and the quality of a product has small fluctuation.

The invention discloses a making method of Li-La-Ti oxide in the lithium ion battery domain, which comprises the following steps: adopting lithium nitrate, lanthanum nitrate and butyl titanate as raw material with molecular formula as Li3xLa2/3-xTiO3 (0<x<0.16); setting the molar rate of Li, La and Ti at 1: 1: 2; adopting alcohol or ethylene glycol monomethyl ether as solvent; or adjusting pH value under 1 through water and acetate; drying solution; sintering under 800-900 deg.c for 2h; obtaining pure LLTO. the invention shortens experimental period and synthesizing temperature with grain size about 200nm, which possesses excellent compact and electric property.

The invention discloses a preparation method of a high-strength and antioxidant rare-earth-based smoke denitration catalyst. The preparation method of the high-strength and antioxidant rare-earth-based smoke denitration catalyst comprises the following steps: by taking titanium dioxide and montmorillonite as carriers and ammonium metatungstate, cerous nitrate and lanthanum nitrate as active components, mixing, ageing, kneading, forming, drying and roasting with the accompanying of auxiliary materials. The auxiliary materials comprise ammonia water, lactic acid, citric acid, stearic acid, glass fiber, wood pulp, hydroxypropyl methyl cellulose, polyoxyethylene, monoethanolamine and water. The product prepared by the method is separated under a high SO2 smoke condition, nitric oxide in the smoke can be decomposed; meanwhile, the purpose of removing mercury and dioxin can be achieved. According to the preparation method of the high-strength and antioxidant rare-earth-based smoke denitration catalyst, the rare earth elements, namely cerium and lanthanum are used as the active components, so that the addition amount of vanadium is reduced, the toxicity of the product is reduced or the product is non-toxic product, the pressure of the post treatment of the product is reduced; the environmental protection pressure is reduced; the product is environmentally friendly; the product can be widely used in the field of thermal power plants, glass factories and chemical plants.

The invention relates to an anti-carbon-deposition Ni-based catalyst for hydrogen production by methane steam reforming and a preparation method thereof. By taking lanthanum nitrate, praseodymium nitrate, samarium nitrate, yttrium nitrate, zirconium nitrate, zirconium carbonate, zirconium oxychloride, and the like as precursors and taking ammonia as a precipitant, a pyrochlore composite oxide is prepared through using a coprecipitation method; and then the pyrochlore composite oxide is mixed with alumina by using a mechanical mixing method so as to obtain a pyrochlore alumina composite carrier. Nickel nitrate, nickel chloride, nickel sulfate, nickel oxalate and the like serving as nickel sources are loaded on the pyrochlore alumina composite carrier through direct immersion. The loading capacity of nickel in the catalyst accounts for 5-30% of the weight of the catalyst, the pyrochlore content of the catalyst is 5-50%, and the alumina content of the catalyst is 20-90%. By taking the pyrochlore alumina composite oxide as a carrier, the reaction activity and anti-carbon-deposition performance of the catalyst can be greatly increased; the preparation method of the catalyst is simple; and the catalyst has excellent catalytic activity and stability to methane steam reforming in a stationary bed.

The preparation method for lanthanum nickelate conductive metal oxide film material includes: preparing precursor solution, mixing solvent acetic acid, deionized water and additive methanamide and solute nickel acetate and lanthanum nitrate at a certain temperature in the concentration of 0.3 M to obtain precursor solution, and preparing film material, making the prepared precursor solution form gel film on the substrate by adopting rotating coating mode, then making heat treatment by sections in quick annealing furnace to form film material. Said film material possesses high selective orinetation and good metal characteristics, and its room temp. electric resistivity is about 7.6X10 to the minus fourth ohm cm. Said film material can be used to prepare high-quality ferroelectric film material on it or can be used as bottom electrode of ferroelectric film device.

The invention discloses a catalyst for synthesizing methanol by direct hydrogenation of carbon dioxide and a preparation method thereof and relates to the catalyst. The invention provides the catalyst for synthesizing the methanol by direct hydrogenation of the carbon dioxide and the preparation method thereof. The catalyst is LaCr1-xCuxO3, wherein x is the relative mole fraction of a main component of Cu, x is equal to 0.1-0.9, and La: Cr: Cu is equal to 1: (1-x): x. The preparation method comprises the steps of preparing copper nitrate, chromium nitrate, lanthanum nitrate and citric acid into water solution, forming a sol under the radiation of an infrared lamp, heating, decomposing nitrogen oxides and organic acids, pre-baking in an atmosphere furnace at the temperature of 350-450 DEG C for 2-4h, baking at the temperature of 700-800 DEG C, and obtaining the catalyst for synthesizing the methanol by direction hydrogenation of the carbon dioxide. The citric acid complexation-rapid combustion method is adopted for overcoming the disadvantages of lower conversion rate, poorer selectivity of the methanol and the like during the catalysis of the carbon dioxide by using the existing catalyst for synthesizing the methanol by hydrogenation of the carbon dioxide, and the prepared catalyst has stable performances.

The invention discloses a composite porous activated carbon flue gas adsorbent which is characterized by comprising the following raw materials in parts by weight: 98-105 parts of shell activated carbon, 36-40 parts of diatomite, 2-3 parts of sodium metasilicate, 2-3 parts of rosin, 2-3 parts of VAE emulsion, 2-3 parts of polyvinyl alcohol, 1-2 parts of sodium alcohol ether sulphate, 1-2 parts of sodium citrate, 1-2 parts of gypsum residue, 2.5-3.5 parts of pulverized fuel ash, 4-5 parts of edible corn starch, 2-3 parts of lanthanum nitrate, 9-12 parts of glass fiber powder, 4-6 parts of adsorption aids and a proper amount of water. The composite porous activated carbon flue gas adsorbent disclosed by the invention is reasonable in formula, viscous matters such as polyvinyl alcohol and edible corn starch are added, the toughness and strength of the activated carbon are improved, and the service life is prolonged; and due to the addition of the adsorption aids, the adsorbent has special porosity, the contact time between gas and the adsorbent is prolonged, and the effects of inhibiting bacteria and purifying the air are achieved. Therefore, the adsorption efficiency is high, the production process is simple, and the adsorbent is suitable for industrial dry desulfurization, automobile exhaust desulfurization and daily air purification.

The invention relates to a preparation method of an active carbon fiber phosphorous removing agent carrying lanthanum hydroxide. The invention belongs to the technical field of phosphorous removing agent preparation technology. The novel phosphorous removing agent provided by the invention has advantages of high phosphorous removing rate, high absorption rate, and the like. The phosphorous removing rate reaches above 99.5%. The method of the invention is characterized in that: a mixed suspension composed of a concentration of lanthanum nitrate solution and a concentration of sodium hydroxide solution is adopted; a certain amount of active carbon fiber is added to the mixed suspension; the mixture is stirred, filtered, washed, and a solid phosphorous removing agent is finally obtained. According to the phosphorous removing agent, a weight ratio of active carbon fiber to lanthanum hydroxide is 1:1 to 1:1.2.

The invention relates to a solar glass self-cleaned high anti-reflection coating and a production method thereof, wherein the solar glass self-cleaned high anti-reflection coating is composed of antireflection components, self-cleaning components, latent light conversion components, film coating regulators and solvent water, and simultaneously has triple functions including self-cleaning, antireflection and near ultraviolet light conversion. In the formula of the coating, the antireflection components are nano SiO2 hydrosols of different sizes; the self-cleaning components are lanthanum cerium doped nano TiO2 and nano SiO2; the latent light conversion components are lanthanum nitrate, cerous nitrate, terbium nitrate, ammonium dihydrogen phosphate, phosphoric acid and ascorbic acid; after the latent light conversion components are treated, a silica coated phosphate fluorescent material La1-x-yCexTbyPO4 is generated, wherein x=0.02-0.5, and y=0.02-0.05; the film coating regulators include a surface active agent and an organosilicone coupling agent. Once the solar glass self-cleaned high anti-reflection coating disclosed by the invention is applied to solar glass, the light transmittance of the solar glass and the photoelectric conversion efficiency of crystalline silicon solar batteries can be significantly improved and stabilized, and the manual cleaning cost and maintenance management cost of the solar batteries in the process of running are reduced, therefore, the solar glass self-cleaned high anti-reflection coating can replace existing solar glass anti-reflection coatings.

The invention relates to an applique antibacterial ceramic cutter, and belongs to the technical field of daily ceramics. The cutter comprises a cutter blank, and is characterized in that the outer surface of the cutter blank is covered with a layer of antibacterial self-cleaning ceramic glaze; the antibacterial self-cleaning ceramic glaze is prepared from the following raw materials in percentageby weight: 15 to 30 percent of quartz, 20 to 40 percent of feldspar, 10 to 20 percent of borax, 6 to 18 percent of boric acid, 3 to 7 percent of barium carbonate, 2 to 5 percent of sodium carbonate, 4to 9 percent of bentonite, 0 to 6 percent of phosphorus pentoxide, 10 to 20 percent of zinc oxide, 0 to 6 percent of titanium oxide, 1 to 5 percent of strontium carbonate, 0 to 4 percent of lithium carbonate, 1 to 4 percent of cooked steatite, 1 to 6 percent of alumina, and 1 to 4 percent of rare-earth; and the rare-earth is one or a mixture of arbitrary two of the cerium oxide, the cerium lanthanum chloride and the lanthanum nitrate. The cutter has the effect of antibacterial self-cleaning, has beautiful appearance, and is suitable for the occasion of high-grade application.

The invention discloses a gold-containing catalyst for preparing vinyl chloride by using an acetylene method as well as a preparation method and application of the catalyst. The catalyst contains a gold element, a lanthanum element, a cobalt element, a co-catalytic metal element and a carrier with a porous micro-structure. The gold accounts for 0.3%-2% by mass of the catalyst; the gold element in the catalyst comes from gold chlorides or gold nitrates; the cobalt element comes from chlorides of the cobalt or cobalt nitrates; and the lanthanum element comes from lanthanum chlorides or lanthanum nitrates. The catalyst disclosed by the invention in use is free from inactivation phenomenon caused by sublimation of industrial catalyst mercury chloride, has no pollution to the environment, overcomes defects of high toxicity and high pollution of the conventional industrial catalyst mercury chloride, has the characteristics of simple preparation method, high conversion rate of the acetylene and selectivity of the vinyl chloride, long service life up to 1000 hours or more, high temperature resistance, and high intensity and is renewable, and the conversion rate of the acetylene and selectivity of the vinyl chloride approximate to or exceed the technical indexes of the mercury chloride catalyst.

The concentration of citrate complexing agent in an electroless cobalt or nickel plating bath is determined by titrating a sample of the electroless plating bath containing a small concentration of free fluoride ion with a standard lanthanum nitrate solution. During the titration, La<3+> ion first reacts preferentially with the citrate complexing agent and then with fluoride ion, which reduces the free fluoride ion concentration. The endpoint for the titration is indicated by a substantial decrease in the free fluoride ion concentration, which is detected via a fluoride ion specific electrode (ISE). The method can be used for analysis of other complexing agents.

A catalyst for preparing dimether by dewatering methanol contains CuO (20-40 Wt%), ZnO (5-30), La2O3 (1-10), Sm2O3 (1-10), V2O5 (1-10) and carrier (40-60). Its preparing process includes such steps as dissolving copper nitrate (or acetate), Zinc nitrate (or acetate) and lanthanum nitrate in solvent, adding carrier, stirring, adding superfine (250 meshes) particles of Sm2O3 and V2O5, stirring, infrared drying at 60-100 Deg C., calcining at 350-500 Deg C., pressing and sieving.

A La-doped strontium titanate (SrTiO3)-based oxide thermoelectric material and a preparation method thereof, belonging to the technical field of energy materials. The method is divided into two parts of powder synthesis and forming of bulk materials. The powder synthesis adopts the sol-gel method, takes tetrabutyl titanate, strontium nitrate and lanthanum nitrate as raw materials, takes deionized water and ethanol as solvents and takes acetic acid and glycerol as a catalyst and a chelating agent to prepare SrTiO3 gel with different La doping amount, and the temperature is kept at the temperature of 500-560 DEG C for 1-2 hours to obtain precursor powder. The bulk forming adopts the spark plasma sintering method, and the sintering conditions are as follows: the vacuum degree is 2-10Pa, the pressure is 40-50MPa, the heating rate is 100 DEG C/min, the sintering temperature is 900-1000 DEG C, and the holding time is 5-10min. The method synthesizes the La-doped SrTiO3-based bulk thermoelectric material with high chemical homogeneity, uniform and fine grains and single-phase perovskite structure under the conditions of lower reaction temperature and shorter reaction time. The preparation method has the advantages of simple and convenient process, short synthesis and forming time, and the like.

Production of rare earth ammonium dimolybdate is carried out by adding ammonium tetramolybdate with ammonium tetramolybdate : soft water: ammonia water = 1kg: 4-5L: 1L, heating agitating, forming mother liquid, regulating the pH value of mother liquid between 7-8.5, adding the cerium nitrates, lanthanum nitrates or illinium nitrates into the mother liquid, heating evaporating for 2.0-6.0hrs with heating temperature 100deg.C-130deg.C until the solution transparent, discharging the materials, pumping filtering, drying with temperature 110-150deg.C for 6-8hrs, and obtaining the rare earth ammonium dimolybdate. It achieves low cost, higher material processing and using performance and no environmental pollution.

The invention relates to an improved MCM-41 mesoporous molecular sieve and a preparation method thereof, in particular relates to a dual-metal-atom improved MCM-41 mesoporous molecular sieve and the preparation method thereof. The molecular sieve consists of hexadecyl trimethyl ammonium bromide, ethyl orthosilicate, sodium hydroxide, Me metal salt (Co, Ni, Cr, Fe, Cu, V), lanthanum nitrate and water. The molecular sieve is prepared in the steps: at the room temperature, hexadecyl trimethyl ammonium bromide is mixed and dissolved with the sodium hydroxide, and is added with TEOS in dropping way, and simultaneously added with Me metal salt water solution and lanthanum nitrate solution in dropping way; the pH value of the mixed solution is adjusted by acetic acid to be 10 to 11, and is mixed for 1 to 2 hours after being stabilized; the sol is moved into a polyfluortetraethylene bottle to be heated and crystallized for 2 days in the oven at the temperature of 100 DEG C; after filtering, washing and drying for nights, and being calcined in a muffle at the temperature of 550 DEG C for 3 to 7 hours, the dual-metal-atom improved MCM-41 mesoporous molecular sieve is obtained. The product can simultaneously improve the acid performance and the water heating stability of the MCM-41 mesoporous molecular sieve, and can enlarge the actual application of the MCM-41 mesoporous molecular sieve in the catalyst filed.

The invention relates to a lanthanum-ferrite-doping formaldehyde gas sensitive material and a preparation method thereof, which belong to the formaldehyde gas sensitive material and the preparation method. The material of the invention comprises raw materials such as lanthanum nitrate, ferric nitrate, citric acid, dispersing agents, metal ions with the similar electronegativity and the ion diameter to iron ions or metal ions with the similar electronegativity and ion diameter to lanthanum ions and the like according to the mol ratio of 1/1/(0.05 to 1.5)/(0.001 to 0.1)/(0.1 to 0.5). The preparation method comprises the steps of solution mixing, microwave reaction, gel drying, grinding and the like. Thereby, the formaldehyde gas sensitive material with the advantages of high sensitivity, good selectivity and high response-recovery time is obtained.

The invention relates to a lanthanum doping nanometer barium ferrite thin film and a preparation method thereof, which is technically characterized in that the prescription is as follows: 1.48 g/100 ml to 1.60 g/100 ml of glycol, 2.51 g/100 ml to 2.71 g/100 ml of citric acid, 1.74 g/100 ml of iron nitrate, 0.125 g/100 ml of barium nitrate and 0.03 g/100 ml to 0.125 g/100 ml lanthanum nitrate. The preparation method is that the iron nitrate, the barium nitrate, the lanthanum nitrate, and the like, serve as raw materials to prepare a forerunner body the forerunner body of the lanthanum doping nanometer barium ferrite in a sol-gel method; sol-gel method; clean silicon dioxide serves as a support base, the iron nitrate, the barium nitrate and the lanthanum nitrate serve as main salt, the citric acid serves as complexing agent, the glycol serves as complexing agent assist, and the soakage-drawing method is adopted to make the film. The method has the advantages of simple process flow and low cost; the method is convenient for preparing the thin film on bases with different shapes, the lanthanum doping nanometer barium ferrite thin film with high purity is obtained, and the thin film can be used for preparing magnetic recording materials and absorbing materials.

The invention which belongs to the technical field of catalysis relates to a catalyst for methanation and a preparation method thereof. The preparation method comprises the following steps: 1, fully mixing alumina (or pseudoboehmite) with a pore forming agent and a binder, adding deionized water, granulating, drying, compression-molding, and roasting to prepare a catalyst carrier; and 2, dipping the catalyst carrier in a solution of nickel nitrate and lanthanum nitrate (or potassium nitrate, or potassium carbonate, or cerium nitrate, or cerous nitrate), drying, and roasting to prepare the catalyst. The catalyst prepared through the method of the invention, which has the advantages of high mechanical strength and good hydrothermal stability, is suitable for methanation reactions carried out under conditions that the CO content is high and the reaction temperature is high, and can effectively prevent carbon deposition.