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Environment-friendly accelerator ZBEC pre-dispersed master batch and preparation method thereof

A pre-dispersed masterbatch and accelerator technology, which is applied in the field of rubber additives and its preparation, can solve problems affecting rubber production efficiency and quality, long mixing time, slow feeding speed, etc., and achieve broad industrialization prospects and easy The effect of mixing ingredients and fast feeding speed

Active Publication Date: 2016-06-22
NINGBO ACTMIX POLYMER
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] It is worth noting that ZBEC is in the form of white powder. If it is added directly during mixing, there will be problems of uneven dispersion and dust pollution during the rubber mixing process, and the feeding speed is slow and the mixing time is long, which will affect the rubber production efficiency and quality

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] The rubber accelerator tetrabutyl thiuram disulfide pre-dispersed masterbatch of embodiment one, by weight, the composition of the masterbatch is: 71 parts of zinc dibenzyl dithiocarbamate, ternary ethyl 13 parts of propylene rubber, 1 part of EVA resin, 1 part of stearic acid, 1 part of active agent, 10 parts of industrial white oil, 3 parts of saturated fatty acid zinc. The preparation method of this master batch, comprises the following steps:

[0017] (1) Prepare the sheet rubber matrix;

[0018] (2) Accurately weigh the raw materials required for the preparation of masterbatch according to the ratio;

[0019] (3) Feed each raw material three times into the internal mixer, mix evenly and then discharge, the discharge temperature is 80°C to obtain the rubber compound;

[0020] (4) Control the given speed of the main engine to be 120r / min, feed the rubber material obtained in step (3) to the extruder, the feeding speed is 40r / min, the temperature control area of ​​t...

Embodiment 2

[0021] The rubber accelerator tetrabutylthiuram disulfide pre-dispersed masterbatch of embodiment two, by weight, the composition of the masterbatch is: 72 parts of zinc dibenzyl dithiocarbamate, ternary ethyl 14 parts of propylene rubber, 2 parts of EVA resin, 1 part of stearic acid, 1 part of active agent, 8 parts of industrial white oil, 2 parts of saturated fatty acid zinc. The preparation method of this master batch, comprises the following steps:

[0022] (1) Prepare the sheet rubber matrix;

[0023] (2) Accurately weigh the raw materials required for the preparation of masterbatch according to the ratio;

[0024] (3) Feed each raw material three times into the internal mixer, mix evenly and then discharge, the discharge temperature is 82°C to obtain the rubber compound;

[0025] (4) Control the given speed of the main engine to be 118r / min, feed the rubber material obtained in step (3) to the extruder, the feeding speed is 39r / min, the temperature control area of ​​th...

Embodiment 3

[0026] The rubber accelerator tetrabutylthiuram disulfide pre-dispersed masterbatch of embodiment three, by weight, the composition of the masterbatch is: 70 parts of zinc dibenzyl dithiocarbamate, ternary ethyl 14 parts of propylene rubber, 1 part of EVA resin, 1 part of stearic acid, 1 part of active agent, 11 parts of industrial white oil, 2 parts of saturated fatty acid zinc. The preparation method of this master batch, comprises the following steps:

[0027] (1) Prepare the sheet rubber matrix;

[0028] (2) Accurately weigh the raw materials required for the preparation of masterbatch according to the ratio;

[0029] (3) Feed each raw material three times into the internal mixer, mix evenly and then discharge, the discharge temperature is 84°C to obtain the rubber compound;

[0030] (4) Control the given speed of the main engine to be 122r / min, feed the rubber material obtained in step (3) to the extruder, the feeding speed is 42r / min, the temperature control area of ​​...

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Abstract

The invention discloses an environment-friendly accelerator ZBEC pre-dispersed master batch and a preparation method thereof. The environment-friendly accelerator ZEBC pre-dispersed master batch comprises, by weight, 69-72 parts of dibenzyldithiocarbamic acid, zinc salt, 14-20 parts of rubber matrix, 8-13 parts of industrial mineral oil and 2-5 parts of saturated fatty acid zinc salt. The preparation method of the environment-friendly accelerator ZBEC pre-dispersed master batch is simple and easy to operate; according to the preparation method, mixing time for subsequent procedures of preparing the master batch is reduced effectively, the accelerator ZBEC pre-dispersed master batch prepared by the method maintains original activity of ZBEC effectively and is free of caking at room temperature, is convenient to weigh and easy to blend for mixing and has good flow characteristic after being blended with rubber; feeding time is accelerated while dust flying is avoided and skin allergy to operators is avoided, and utilization rate of raw materials is high; the master batch disperses uniformly in rubber products after blending and mixing and thus production efficiency and quality of the rubber products are guaranteed. The environment-friendly accelerator ZBEC pre-dispersed master batch has great significance in promoting sustainable development of rubber manufacturing and has wide industrial prospect.

Description

technical field [0001] The invention relates to the technical field of rubber additives and their preparation, in particular to an environment-friendly accelerator ZBEC pre-dispersed masterbatch and a preparation method thereof. Background technique [0002] The vulcanization accelerator ZBEC (zinc dibenzyl dithiocarbamate) belongs to the super speed accelerator. The name of similar products at home and abroad is VulkacitZBEC (Bayer). ZBEC is a new type of environmentally friendly secondary aminothiocarbamate vulcanization accelerator. It will not produce carcinogenic nitrosamines during use. The vulcanization activity temperature is low and the operation is relatively safe. It is an excellent activity of thiazole accelerators. It can be used to replace PZ, EZ, ZDBC, TMTM, etc., and can be used as the main accelerator or secondary accelerator of natural rubber, styrene-butadiene rubber, butyl rubber, EPDM rubber, natural latex and synthetic latex. Of all the dithiocarbamat...

Claims

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Application Information

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IPC IPC(8): C08L23/16C08L23/08C08L91/06C08K5/09C08K5/39C08K5/098C08J3/22B29C47/92B29C48/92
CPCB29C48/92B29C2948/9259B29C2948/92704C08J3/226C08J2423/16C08L23/16C08L2205/03C08L23/0853C08L91/06C08K5/09C08K5/39C08K5/098
Inventor 连千荣
Owner NINGBO ACTMIX POLYMER
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