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Refractory glass and preparation method thereof

A high-temperature-resistant glass technology, applied in the field of high-temperature-resistant glass and its preparation, can solve problems such as high melting point, high refractive index, and small thermal conductivity, and achieve the goal of keeping the color unchanged, simple preparation method, and good heat-resistant and explosion-proof performance Effect

Inactive Publication Date: 2016-07-27
SUZHOU YUNSHU NEW MATERIAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Zirconium dioxide has excellent thermal and chemical stability, high melting point, high boiling point, small thermal conductivity, high hardness, good wear resistance, insulator at room temperature, and high refractive index. Very high melting point, so limit its application in the field of glass

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] (1) Weigh 85 kg of silica, 5 kg of aluminum oxide, 4 kg of chopped glass fiber, 3 kg of zirconia with a particle size of 20 nm, 1 kg of calcium aluminate, 0.5 kg of boric acid, 0.2 kg of sodium nitrate, and 0.1 kg of strontium carbonate kg, potassium fluozirconate 0.05kg, zinc borate 0.03kg, isooctyl dimercaptoacetate di-n-octyltin 0.02kg, diyttrium trioxide 0.02kg;

[0034] (2) After the above raw materials are fully mixed, put them in a crucible, heat them to 1350°C, and keep them warm for 3 hours to obtain molten glass;

[0035] (3) Pour the molten glass described in step 2 into a preheated graphite mold to form it, and perform annealing treatment at 1100°C to obtain high temperature resistant glass.

[0036] The performance test results of the prepared high temperature resistant glass are shown in Table 1.

Embodiment 2

[0038] (1) Weigh (1) Weigh 85kg of silica, 5kg of aluminum oxide, 4kg of chopped glass fiber, 3kg of zirconia with a particle size of 20nm, 1kg of calcium aluminate, 0.5kg of boric acid, and 0.2 kg of sodium nitrate kg, 0.1 kg of strontium carbonate, 0.05 kg of potassium fluozirconate, 0.03 kg of zinc borate, 0.02 kg of di-n-octyl tin dimercaptoacetate, 0.02 kg of diyttrium trioxide, 0.2 kg of trimethyl metasilicate and 0.1 kg of toner kg;

[0039] (2) After the above raw materials are fully mixed, put them in a crucible, heat them to 1350°C, and keep them warm for 3 hours to obtain molten glass;

[0040] (3) Pour the molten glass described in step 2 into a preheated graphite mold to form it, and perform annealing treatment at 1100°C to obtain high temperature resistant glass.

[0041] The performance test results of the prepared high temperature resistant glass are shown in Table 1.

Embodiment 3

[0043] (1) Weigh 90kg of silica, 8kg of aluminum oxide, 6kg of chopped glass fiber, 6kg of zirconia with a particle size of 30nm, 2kg of calcium aluminate, 2kg of boric acid, 0.8kg of sodium nitrate, and 0.2kg of strontium carbonate , 0.08kg of potassium fluozirconate, 0.09kg of zinc borate, 0.3kg of isooctyl di-n-octyltin dimercaptoacetate, 0.04kg of diyttrium trioxide, 0.2kg of trimethyl metasilicate and 0.1kg of toner;

[0044] (2) After the above raw materials are fully mixed, put them in a crucible, heat them to 1450°C, and keep them warm for 3 hours to obtain molten glass;

[0045] (3) Pour the molten glass described in step 2 into a preheated graphite mold to form it, and perform annealing treatment at 1300°C to obtain high temperature resistant glass.

[0046] The performance test results of the prepared high temperature resistant glass are shown in Table 1.

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Abstract

The invention discloses refractory glass and a preparation method thereof. The refractory glass comprises the following components in parts by weight: 85-90 parts of silicon dioxide, 5-8 parts of aluminum oxide, 4-6 parts of chopped glass fiber, 3-6 parts of zirconium dioxide, 1-2 parts of calcium aluminate, 0.5-2 parts of boric acid, 0.2-0.8 part of sodium nitrate, 0.1-0.2 part of strontium carbonate, 0.05-0.08 part of potassium fluozirconate, 0.03-0.09 part of zinc borate, 0.02-0.3 part of imarcaptoacetate dioctyltin and 0.02-0.04 part of yttria. The invention also provides a preparation method of the refractory glass.

Description

technical field [0001] The invention belongs to the field of glass materials, in particular to a high-temperature-resistant glass and a preparation method thereof. Background technique [0002] Glass can be divided into oxide glass and non-oxide glass according to its main composition. Plastic, rubber, abrasive and other industries. [0003] With the gradual increase in the application of glass, the research on glasses with different properties has gradually become the focus of people's research, especially by changing the composition of the glass to make the glass have different properties. Zirconium dioxide has excellent thermal and chemical stability, high melting point, high boiling point, small thermal conductivity, high hardness, good wear resistance, insulator at room temperature, and high refractive index. Very high melting point, so limit its application in the field of glass. Contents of the invention [0004] In view of the above requirements, the present inv...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C4/02C03C3/118
CPCC03C4/02C03C3/118
Inventor 戴晓宸
Owner SUZHOU YUNSHU NEW MATERIAL TECH