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A kind of rubber composition and preparation method thereof

A rubber composition and a technology for mixing rubber, applied in the field of rubber processing, can solve the problems of unmentioned multi-stage vulcanization, poor performance, large difference in vulcanization performance, etc., and achieve uniform distribution of cross-linking bonds, low production cost, and vulcanization temperature. Moderate effect

Active Publication Date: 2018-03-09
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The vulcanization of rubber products, especially the composite products of various rubbers, often uses a variety of vulcanization systems, especially the blends of nitrile rubber and chlorinated polyethylene, which are commonly used in rubber hoses. Because the vulcanization properties of the two rubbers are quite different, so The properties of products obtained by a single vulcanization system are often worse than those prepared by a compound vulcanization system
[0003] In "Research and Application of Rubber Chlorinated Polyethylene and Nitrile Rubber Blending System", Gao Xinwen mentioned the use of rubber-type chlorinated polyethylene and nitrile rubber for blending, and mentioned the use of the two blends Vulcanization systems with sulfur vulcanization, vulcanization systems with peroxide vulcanization are also mentioned, but multi-stage vulcanization is not mentioned

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] Take 100 parts of Lanzhou Petrochemical nitrile rubber 3305, 10 parts of chlorinated polyethylene, put it into the open mixer and start mixing, and add 50 parts of N550 carbon black, 1 part of accelerator CZ, 3 parts of zinc oxide, 1 part of Stearic acid, after making it mix evenly, add 3 parts of phenolic resin, 2 parts of sulfur, 3 parts of tert-butyl peroxyneodecanoate successively, mix evenly in the mill with cold water cooling to obtain the rubber compound, the Put the mixed rubber into a mold and vulcanize at room temperature for 10 hours, then place it in a flat vulcanizing machine at 135°C for 20 minutes, and then place it in a flat vulcanizing machine at 155°C for 10 minutes to get the sample , the performance test results are shown in Table 1.

Embodiment 2

[0053] Take 100 parts of Lanzhou Petrochemical nitrile rubber 3305, 20 parts of chlorinated polyethylene, put them into an open mixer and start mixing, and add 100 parts of N550 carbon black, 0.5 parts of accelerator CZ, 3 parts of zinc oxide, 1 part Stearic acid, make it mix evenly, then add 5 parts of phenolic resin, 0.5 part of sulfur, 0.5 part of pivalate pivalate in turn, and mix evenly in an open mill with cold water cooling to obtain a rubber compound. Put the mixed rubber into a mold for molding, park it at room temperature for 15 hours, then place it in a flat vulcanizing machine at 140°C for 35 minutes, and then place it in a flat vulcanizing machine at 160°C for 5 minutes, that is, The samples were obtained, and the performance test results are shown in Table 1.

Embodiment 3

[0061] Take 100 parts of LG nitrile rubber 6250, 15 parts of chlorinated polyethylene, put them into an open mill and start mixing, and add 150 parts of N330 carbon black, 2 parts of accelerator CZ, 3 parts of zinc oxide, 1 part of hard Fatty acid, make it mix evenly, then add 8 parts of phenolic resin, 1 part of sulfur, and 2 parts of pivalate pivalate in turn, and mix evenly in an open mill with cold water cooling to obtain a rubber compound. Put the mixed rubber into a mold for molding, park it at room temperature for 20 hours, then place it in a flat vulcanizing machine at 145°C for 35 minutes, and then place it in a flat vulcanizing machine at 160°C for 20 minutes, namely The samples were obtained, and the performance test results are shown in Table 1.

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PUM

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Abstract

The invention provides a rubber composition and a preparation method thereof. By using a compound vulcanization system and using a staged vulcanization method, each vulcanization system can be vulcanized within its own suitable vulcanization temperature range independently of each other. One section is room temperature vulcanization. The compositions obtained according to the invention have high strength and high elongation.

Description

technical field [0001] The invention relates to a composition of nitrile rubber and chlorinated polyethylene rubber suitable for rubber hoses, oil-resistant rubber hoses, etc. and a preparation method thereof, belonging to the field of rubber processing. Background technique [0002] The vulcanization of rubber products, especially the composite products of various rubbers, often uses a variety of vulcanization systems, especially the blends of nitrile rubber and chlorinated polyethylene, which are commonly used in rubber hoses. Because the vulcanization properties of the two rubbers are quite different, so The properties of products obtained by a single vulcanization system are often worse than those prepared by a composite vulcanization system. [0003] In "Research and Application of Rubber Chlorinated Polyethylene and Nitrile Rubber Blending System", Gao Xinwen mentioned the use of rubber-type chlorinated polyethylene and nitrile rubber for blending, and mentioned the us...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L9/02C08L23/28C08L61/06C08K13/02C08K3/04C08K5/14C08K3/36C08K3/26C08K3/34C08J3/24B29C35/02
Inventor 吴宇赵洪国樊洁孟令坤伏研何连成胡海华宋中勤张群郑红兵
Owner PETROCHINA CO LTD