Adhesive sheet and display
An adhesive sheet, display technology, applied in the direction of adhesives, adhesive types, ester copolymer adhesives, etc. Excellent foaming effect
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[0074] (5) Preparation of adhesive composition
[0075] The adhesive composition P can be prepared by preparing the (meth)acrylate polymer (A), and then combining the obtained (meth)acrylate polymer (A), thermal crosslinking agent (B) and UV absorber (C), and add additives as required.
[0076] The (meth)acrylate polymer (A) can be prepared by polymerizing a mixture of monomers constituting a polymer by a normal radical polymerization method. The polymerization of the (meth)acrylate polymer (A) is preferably performed by a solution polymerization method using a polymerization initiator as needed. Examples of the polymerization solvent include ethyl acetate, n-butyl acetate, isobutyl acetate, toluene, acetone, hexane, methyl ethyl ketone, and the like, and two or more of them may be used in combination.
[0077] As a polymerization initiator, an azo compound, an organic peroxide, etc. are mentioned, and 2 or more types may be used together. Examples of azo compounds include ...
Embodiment 1
[0134] 1. Preparation of (meth)acrylate polymer
[0135] The (meth)acrylate polymer (A) was prepared by copolymerizing 60 mass parts of n-butyl acrylate, 20 mass parts of methyl acrylate, and 20 mass parts of 2-hydroxyethyl acrylate. When the molecular weight of this (meth)acrylate polymer (A) was measured by the method mentioned later, it was 600,000 in weight average molecular weight (Mw).
[0136] 2. Preparation of Adhesive Composition
[0137] 100 parts by mass (solid content conversion value; the same below) of the (meth)acrylate polymer (A) obtained in the above step 1, 0.23 parts by mass of trimethylol as a thermal crosslinking agent (B) Propane-modified toluene diisocyanate (manufactured by Toyokemu Co., Ltd., product name "BHS8515"), 1.7 parts by mass (1.7 mass %) of 2,2- Dihydroxy-4-methoxybenzophenone (manufactured by Cytec Industries Inc., Japan, product name "Cyasorb UV24") was mixed, and fully stirred, and diluted with methyl ethyl ketone to obtain a solid cont...
Embodiment 2
[0142] 60 parts by mass of 2-ethylhexyl acrylate, 20 parts by mass of methyl methacrylate, and 20 parts by mass of 2-hydroxyethyl acrylate were copolymerized to prepare a (meth)acrylate polymer (A). When the molecular weight of this (meth)acrylate polymer (A) was measured by the method mentioned later, it was 700,000 in weight average molecular weight (Mw).
[0143] Coating of an adhesive composition (thermal crosslinking type) was prepared in the same manner as in Example 1, except that the (meth)acrylate polymer (A) obtained above was used and the solid content concentration was 40% by mass. solution. An adhesive sheet was prepared in the same manner as in Example 1 using the obtained coating solution of the adhesive composition.
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