Composition for purifying tail gas of grain dryer based on activated carbon modification and its preparation method and application
A technology of activated carbon and drying machine, which is applied in chemical instruments and methods, separation methods, gas treatment, etc. It can solve the problems of unsatisfactory tail gas treatment, difficulty in completely clearing dust particles, and unresolved exhaust gas, etc., and achieves excellent results. Purification ability, excellent absorption ability, easy to promote the effect
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[0015] The invention provides a method for preparing a composition based on activated carbon modification for purifying the tail gas of a grain dryer, the preparation method comprising:
[0016] 1) In the presence of protective gas, the bentonite is calcined to obtain bentonite powder;
[0017] 2) placing activated carbon powder, wheat bran powder, fly ash and bentonite powder in an acid solution for activation treatment to obtain an activation mixture;
[0018] 3) MDI (4,4,-diphenylmethane diisocyanate), TDI (toluene diisocyanate), polyether polyol, activated carbon, potassium fluotitanate and the activated mixture are contacted in the presence of ultrasonic waves to obtain foaming resin;
[0019] 4) Pulverizing the foaming resin to obtain foaming resin powder, and then mixing anionic surfactant, water and foaming resin powder to prepare a composition for purifying grain dryer tail gas based on activated carbon modification.
[0020] In step 1) of the above-mentioned prepar...
Embodiment 1
[0036] 1) In the presence of protective gas (nitrogen), the bentonite was calcined at 430° C. for 5 hours to obtain bentonite powder (particle size below 10 μm);
[0037] 2) Mix activated carbon powder (below 10 μm in particle size), wheat bran powder (below 10 μm in particle size), fly ash (below 10 μm in particle size), bentonite powder and acid solution (pH 4) according to 100:22:15:45 : mixed at a weight ratio of 400, and activated at 48°C for 1.2h to obtain an activated mixture;
[0038] 3) MDI, TDI, polyether polyol (brand L61), activated carbon, potassium fluorotitanate and the activation mixture are mixed according to the weight ratio of 100:19:120:39:1.1:28 in the presence of ultrasonic waves with a frequency of 25MHz and Carry out a contact reaction at 75°C for 8 hours to obtain a foamed resin;
[0039] 4) Pulverize the foaming resin to obtain foaming resin powder (below 10 microns), then mix anionic surfactant (sodium lauryl sulfate), water and foaming resin powder...
Embodiment 2
[0041]1) In the presence of protective gas (neon gas), calcining bentonite at 420°C for 4 hours to obtain bentonite powder (particle size below 10 μm);
[0042] 2) Mix activated carbon powder (below 10 μm in particle size), wheat bran powder (below 10 μm in particle size), fly ash (below 10 μm in particle size), bentonite powder and acid solution (pH 3.5) according to 100:20:12:35 : mixed at a weight ratio of 300, and activated at 45°C for 1 hour to obtain an activated mixture;
[0043] 3) MDI, TDI, polyether polyol (brand L64), activated carbon, potassium fluorotitanate and activation mixture according to the weight ratio of 100:15:110:34:0.8:22 in the presence of ultrasonic waves with a frequency of 20MHz and Carry out a contact reaction at 60°C for 6 hours to obtain a foamed resin;
[0044] 4) Pulverize the foaming resin to obtain foaming resin powder (below 10 microns), then mix anionic surfactant (sodium lauryl sulfate), water and foaming resin powder in a weight ratio o...
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