Antibacterial and antifouling oil-water separation material and preparation method thereof
A technology of oil-water separation and anti-fouling, applied in the field of water treatment, to achieve good application prospects, simple method, and high-efficiency anti-fouling effect
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Embodiment 1
[0023] (1) Immerse a 5cm×5cm cellulose filter membrane in distilled water, boil and activate it for 30min, then wash it for later use.
[0024] (2) Immerse the activated cellulose filter membrane in step (1) in 30 mL of copper sulfate solution with a concentration of 0.5 mol / L, stir at room temperature at 120 rpm for 30 min, and slowly adjust the pH of the solution to 11 with NaOH solution of 1.0 mol / L .
[0025] (3) Add 30 mL of glucose solution with a concentration of 0.5 mol / L to the mixed system obtained in step (2), and reduce in situ at 25° C. for 6 h. Then it was taken out, washed and dried to obtain a film material with in-situ deposition of copper oxide inorganic nanoparticles on the surface, which is an antibacterial and antifouling oil-water separation material, named S1.
Embodiment 2
[0027] (1) Immerse a 5cm×5cm cellulose filter membrane in distilled water, boil and activate it for 30min, then wash it for later use.
[0028] (2) Immerse the activated cellulose filter membrane in step (1) in 30 mL of copper acetate solution with a concentration of 1.0 mol / L, stir at room temperature at 120 rpm for 30 min, and slowly adjust the pH of the solution to 10 with 1.0 mol / L of NaOH solution. .
[0029] (3) Add 30 mL of glucose solution with a concentration of 1.0 mol / L to the mixed system obtained in step (2), and reduce in situ at 70° C. for 4 h. Then it was taken out, washed and dried to obtain a film material with in-situ deposition of cuprous oxide inorganic nanoparticles on the surface, which is an antibacterial and antifouling oil-water separation material, named S2.
Embodiment 3
[0031] (1) Immerse a 5cm×5cm polyester filter membrane in 0.1mol / L NaOH solution, boil it for 30min and then wash it for later use.
[0032] (2) Immerse the polyester filter membrane activated in step (1) in 30 mL of copper acetate solution with a concentration of 1.0 mol / L, stir at 120 rpm for 30 min at room temperature, and then slowly adjust the pH of the solution to 12 with 1.0 mol / L NaOH solution.
[0033] (3) Add 30 mL of glucose solution with a concentration of 1.5 mol / L to the mixed system obtained in step (2), and perform in-situ reduction at 120° C. for 3 h. Then it was taken out, washed and dried to obtain a film material with in-situ deposition of cuprous oxide inorganic nanoparticles on the surface, which is an antibacterial and antifouling oil-water separation material, named S3.
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