Ethyl ester and furfuryl carboxylate based flame-retardant storage battery sealant and preparation method

A technology of tetrahydrofurfuryl methacrylate and dimethylaminoethyl methacrylate is applied in the directions of adhesives, non-polymer adhesive additives, adhesive additives, etc. Affecting material properties, poor flame retardant effect, etc., to achieve the effect of reducing the discharge of harmful substances, reducing the gap in the glue, increasing the fire resistance and heat insulation performance

Inactive Publication Date: 2016-11-16
哈尔滨永淇化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, a large amount of halogen flame retardants added to flame retardant sealants will generate a large amount of toxic gases such as hydrogen halide during the combustion process, while halogen-free flame retardant materials, such as magnesium hydroxide and aluminum hydroxide, have poor flame r...

Method used

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  • Ethyl ester and furfuryl carboxylate based flame-retardant storage battery sealant and preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] A flame retardant battery sealant based on ethyl ester and furfuryl alcohol ester, characterized in that: it comprises A component and B component; the A component is composed of dimethylaminoethyl methacrylate, solvent, o-phenylene Dinonyl diformate, antimony trioxide, reinforcing filler, antioxidant, chlorosulfonated polyethylene; component B consists of methacrylate tetrahydrofurfuryl alcohol ester, acrylate rubber, benzyl dimethylamine, Phosphonate flame retardant plasticizer, fumed silica, solvent, BYK-066N, r-aminopropyltriethoxysilane composition; wherein the A component includes: 40-60 parts of methacrylic acid Dimethylaminoethyl ester, 20-30 parts solvent, 4-8 parts dinonyl phthalate, 10-25 parts antimony trioxide, 5-10 parts reinforcing filler, 5- 10 parts of antioxidant, 20-35 parts of chlorosulfonated polyethylene; in the B component, including: 60-80 parts of methacrylate tetrahydrofurfuryl alcohol ester, 20-30 parts of acrylate rubber , 5-15 parts of benz...

Embodiment 2

[0023] A flame retardant battery sealant based on ethyl ester and furfuryl alcohol ester, characterized in that: it comprises A component and B component; the A component is composed of dimethylaminoethyl methacrylate, solvent, o-phenylene Dinonyl diformate, antimony trioxide, reinforcing filler, antioxidant, chlorosulfonated polyethylene; component B consists of methacrylate tetrahydrofurfuryl alcohol ester, acrylate rubber, benzyl dimethylamine, Phosphonate flame retardant plasticizer, fumed silica, solvent, BYK-066N, r-aminopropyltriethoxysilane composition; wherein the A component includes: 40-60 parts of methacrylic acid Dimethylaminoethyl ester, 20-30 parts solvent, 4-8 parts dinonyl phthalate, 10-25 parts antimony trioxide, 5-10 parts reinforcing filler, 5- 10 parts of antioxidant, 20-35 parts of chlorosulfonated polyethylene; in the B component, including: 60-80 parts of methacrylate tetrahydrofurfuryl alcohol ester, 20-30 parts of acrylate rubber , 5-15 parts of benz...

Embodiment 3

[0032] The A component includes: 40-55 parts of dimethylaminoethyl methacrylate, 20-28 parts of solvent, 4-7 parts of dinonyl phthalate, 10-22 parts of It consists of antimony trioxide, 5-8 parts of reinforcing filler, 5-9 parts of antioxidant, 20-33 parts of chlorosulfonated polyethylene; the B component includes: 60-78 parts of Methacrylate tetrahydrofurfuryl alcohol ester, 20-25 parts of acrylate rubber, 5-12 parts of benzyl dimethylamine, 5-13 parts of phosphonate flame retardant plasticizer, 5-8 parts of gas phase dimethicone Silica, 25-35 parts solvent, 10-14 parts BYK-066N, 4-8 parts r-aminopropyltriethoxysilane.

[0033] The proportioning in the above-mentioned components is made by the following preparation method:

[0034] 1. In component A, dimethylaminoethyl methacrylate, solvent, dinonyl phthalate, and chlorosulfonated polyethylene are added to the vacuum kneader according to the above-mentioned proportioning method of parts by weight, at a temperature of 100 ℃,...

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Abstract

The invention discloses an ethyl ester and furfuryl carboxylate based flame-retardant storage battery sealant and a preparation method. The sealant contains a component A and a component B. The component A is prepared from 2-aminoethyl methacrylate, a solvent, dinonyl phthalate, antimony trioxide, a reinforcing filler, an antioxidant and chlorosulfonated polyethylene. The component B is prepared from tetrahydrofurfuryl methacrylate, acrylate rubber, benzyl dimethylamine, a phosphonate flame-retardant plasticizer, gas-phase silicon dioxide, a solvent, BYK-066N and r-amino propyl triethoxysilane. The adhesive containing two different components is prepared by conducting vacuum kneading on adhesives of the two components A and B and mixing in a reaction kettle. The raw materials in the components A and B are reasonably prepared to make the two components well bonded in the using process, internally produced air bubbles are decreased, adhesive gaps are decreased, meanwhile good fireproof and heat-insulation properties are added, the original liquidity of the adhesive is guaranteed, and the discharge of harmful substances is decreased.

Description

technical field [0001] The invention relates to the technical field of chemical industry, in particular to a flame retardant battery sealant based on ethyl ester and furfuryl alcohol ester and a preparation method thereof, which has a sealing effect on a battery. Background technique [0002] Polymer materials are widely used in the building materials industry. However, the polymer materials themselves are very easy to burn. When a fire occurs, the combustion releases a large amount of toxic gases, such as carbon monoxide and nitric oxide, which can poison people in a very short time. die. A large number of data show that poisonous smoke is the number one killer of people dying in fires. Therefore, the flame retardant properties of building materials are directly related to the safety of people's lives and property. However, the halogen flame retardants added in a large amount of flame retardant sealants will generate a large amount of toxic gases such as hydrogen halide d...

Claims

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Application Information

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IPC IPC(8): C09J4/02C09J4/06C09J11/04C09J11/06
CPCC09J4/06C09J11/04C09J11/06
Inventor 刘振亭
Owner 哈尔滨永淇化工有限公司
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