Method for constructing high-adhesion super-hydrophobic surfaces

A super-hydrophobic surface and high-adhesion technology, applied in the field of surface treatment of functional materials, can solve the problems of time-consuming and labor-consuming, cumbersome steps, expensive chemical raw materials, etc., and achieve high contact angle, cheap, simple and easy-to-operate effects

Active Publication Date: 2016-12-14
SUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the disadvantage of layer-by-layer self-assembly technology is that the steps are cumbersome, time-consuming and labor-intensive.
[0016] The preparation of the above-mentioned super-hydrophobic surfaces with high adhesion currently has problems such as the petal effect is not obvious, the preparation process is complicated, the chemical raw materials are expensive, or relatively fine templates are required or the super-hydrophobic performance is poor.

Method used

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  • Method for constructing high-adhesion super-hydrophobic surfaces
  • Method for constructing high-adhesion super-hydrophobic surfaces
  • Method for constructing high-adhesion super-hydrophobic surfaces

Examples

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Embodiment 1

[0051] figure 1 Prepare the experimental flow chart of highly adhesive superhydrophobic surface for the present invention, concrete steps are as follows:

[0052] (1) Preparation of TiO 2 Sol-gel:

[0053] Take 50ml of absolute ethanol and place it in a beaker, and add 0.27ml of acetylacetone dropwise into it, and stir for 10min with a magnetic stirrer at a speed of 200rpm. Then, 0.85ml of TEOT was added dropwise to the mixture of absolute ethanol / acetylacetone, stirred with a magnetic stirrer for 1 hour, and left to stand to obtain a titanium dioxide sol-gel, which was aged for 4 days and then used for later use.

[0054] (2) Preparation of carbon black / titanium sol-gel composite film:

[0055] Wash the glass with glass water and deionized water, and treat it with a plasma cleaner for 2 minutes, and bake kerosene carbon black on the glass. Then dip the glass piece of baked carbon black into the prepared TiO 2 in sol-gel. Repeat the dip coating three times, immerse in th...

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Abstract

The invention relates to a method for constructing high-adhesion super-hydrophobic surfaces. The method includes steps of adding inhibitors into organic solvents, uniformly stirring the inhibitors, then adding precursors into the organic solvents and stirring the precursors to obtain inorganic nano-particle sol-gel; thoroughly cleaning base materials, then modifying the base materials by the aid of amorphous carbon to obtain modified base materials, carrying out dip-coating on the modified base materials in the inorganic nano-particle sol-gel and then heating the modified base materials to obtain base materials with modified composite membranes; annealing the base materials with the modified composite membranes to remove the amorphous carbon and then modifying the base materials with the modified composite membranes by the aid of substances with low surface energy to obtain the high-adhesion super-hydrophobic surfaces. The method has the advantages that the method is easy to implement and low in cost and is environmentally friendly and safe, environments can be protected, and obvious petal effects can be realized by the high-adhesion super-hydrophobic surfaces constructed by the aid of the method.

Description

technical field [0001] The invention relates to the field of surface treatment of functional materials, in particular to a method for constructing a highly adhesive superhydrophobic surface. Background technique [0002] Surface wettability is one of the important characteristics of solid surface, which is closely related to the roughness of solid surface and its surface energy. Wettability is generally measured by the contact angle of a droplet on a solid surface. A solid surface with a contact angle of less than 90° is called a hydrophilic surface, and a surface with a contact angle of less than 10° is a superhydrophilic surface; a solid surface with a contact angle greater than 90° It is called a hydrophobic surface, and the surface with a contact angle greater than 150° is called a superhydrophobic surface. [0003] As a special wetting surface, superhydrophobic surface has attracted much attention since its discovery in 2004. In nature, many plants, insects and animal...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C17/34
CPCC03C17/3441
Inventor 石震武吴竹慧张锋徐成云彭长四
Owner SUZHOU UNIV
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