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A kind of multi-component coating starch and its production process

A technology of coating starch and production process, which is applied in coating, paper coating, papermaking, etc. It can solve the problems of high energy consumption for paper drying, affecting the concentration of coating, and high price, so as to achieve sustainable development and improve water retention performance , Improve the effect of dry matter yield

Active Publication Date: 2019-03-26
山东米能生物科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Yet coated starch and its production process have the following disadvantages in the prior art: (1) coated starch is generally unit or binary, and the technological process of coated starch is comparatively simple (adopts single process or double process), and reaction makes The quality of coated starch is deviated, the type and quantity of functional groups introduced are small, the starch paste solution ages quickly, and the rheology is poor, resulting in poor water retention of the coating and uneven coating layer of the paper; (2) The cooking concentration of starch is low ( Generally 30-35%), which affects the concentration of the coating, resulting in high energy consumption for paper drying; (3) starch uses deep viscosity reduction, and the yield is low (generally 93-96%)
The above reasons cause the high cost and high price of coating starch; high energy consumption for coating and drying
In turn, the production cost of downstream customers is high, and the enterprise lacks competitiveness.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] A kind of multi-component coating starch, production technology comprises the following steps:

[0044] (1) Oxidation: Slurry 10 tons of raw starch with tap water to a starch milk with a concentration of 35%, and put it into a tank with a volume of 30m 3 In the container, at first with concentration be that 5% sodium hydroxide solution is adjusted pH value to be 8.0, and the temperature of described starch milk is adjusted to 35 ℃, then adds the sodium hypochlorite (sodium hypochlorite is prepared as concentration is 13 % solution), the flow velocity of sodium hypochlorite solution was controlled at 300kg / h, and reacted for 3 hours;

[0045] (2) Esterification: adjust the pH value to 9.0 with a 5% sodium hydroxide solution, adjust the temperature to 30°C, add 4.0% acetic anhydride on a dry basis of the original starch, and react for 1 hour;

[0046] (3) Etherification stage: washing and dehydration into wet starch containing about 16% of moisture; adding the starch sta...

Embodiment 2

[0050] (1) Oxidation: Slurry 10 tons of raw starch with tap water to a starch milk with a concentration of 40%, and put it into a tank with a volume of 30m 3 In the container, at first be that 5% sodium hydroxide solution is adjusted pH value to be 10.0 with concentration, and the temperature of described starch milk is adjusted to 25 ℃, then add the sodium hypochlorite that is 4.0% of original starch dry basis weight (sodium hypochlorite is prepared as concentration is 13 % solution), the flow velocity of sodium hypochlorite solution was controlled at 400kg / h, and reacted for 2 hours;

[0051] (2) Esterification: adjust the pH value to 11.0 with a concentration of 5% sodium hydroxide solution, adjust the temperature to 35°C, add 6.0% acetic anhydride on a dry basis of the original starch, and react for 2 hours;

[0052] (3) Etherification stage: washing and dehydrating into wet starch containing about 18% of moisture; adding starch starch powder with a dry weight of 6.0% of t...

Embodiment 3

[0056] (1) Oxidation: Slurry 10 tons of raw starch with tap water to a starch milk with a concentration of 38%, and put it into a tank with a volume of 30m 3 In the container, at first with concentration be that 5% sodium hydroxide solution is adjusted pH value to be 9.0, and the temperature of described starch milk is adjusted to 35 ℃, then adds the sodium hypochlorite (sodium hypochlorite is prepared as concentration is 13 % solution), the flow velocity of sodium hypochlorite solution was controlled at 500kg / h, and reacted for 3 hours;

[0057] (2) Esterification: adjust the pH value to 10.0 with a 5% sodium hydroxide solution, adjust the temperature to 40°C, add 5.0% acetic anhydride on a dry basis of the original starch, and react for 1 hour;

[0058] (3) Etherification stage: washing and dehydrating into wet starch containing about 20% moisture; adding 4.5% starch starch on a dry basis of the original starch, and then spraying 6.5% of the starch dry basis with a content o...

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PUM

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Abstract

The invention discloses a multielement coating starch. In the multielement coating starch, the dry-basis content is 50%, the viscosity is 200-500cp, the water content in a finished product is less than or equal to 14.0%, the pH value is 6.0-8.0, the substitution degree is 0.035-0.060, the carboxyl accounts for 1.0-2.0% and the acetyl accounts for 1.0-2.0%. The multielement coating starch comprises the following components of: native starch, sodium hypochlorite, a cationic etherifying agent, anhydrous sodium sulphate, acetic anhydride, hydrochloric acid, enzymes, tap water and a proper amount of sodium hydroxide, wherein the sodium hypochlorite accounts for 3.0-4.0% of the mass of the dry basis in the native starch; the cationic etherifying agent accounts for 5.0-8.0% of the mass of the dry basis in the native starch; the acetic anhydride accounts for 4.0-6.0% of the mass of the dry basis in the native starch; the anhydrous sodium sulphate accounts for 3.0-6.0% of the mass of the dry basis in the native starch; and the hydrochloric acid accounts for 1.0-3.0% of the mass of the dry basis in the native starch. The multielement coating starch disclosed by the invention has the advantages that many types of functional groups are adopted, the content of the functional groups is high, the environment-friendly effect is achieved, and petroleum base can be substituted to synthesize latex. Simultaneously, the invention also discloses a production process of the multielement coating starch. The production process is characterized by comprising the five steps of oxidation, esterification, etherification, enzymatic degradation and finished-product preparation.

Description

technical field [0001] The invention belongs to the technical field of new materials, and in particular relates to a multi-component coated starch and a production process thereof. Background technique [0002] The synthetic latex components used in coated paper coatings come from petrochemicals, and petroleum is a non-renewable resource. In order to get rid of this resource limitation and reduce costs even more, many coated paper manufacturers and scientific researchers have started to develop new starch-based products. Coating starch was developed under this background. As a coating adhesive, it is different from petroleum-based synthetic latex. It is derived from renewable resources and does not contain volatile organic compounds. It is an environmentally friendly product. Yet coated starch and its production process have the following disadvantages in the prior art: (1) coated starch is generally unit or binary, and the technological process of coated starch is comparat...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08B31/18C08B31/16D21H19/14
CPCC08B31/16C08B31/18D21H19/14
Inventor 吕志红
Owner 山东米能生物科技有限公司
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