Ultralow-linear expansion coefficient polypropylene composite material and preparation method thereof

A linear expansion coefficient, composite material technology, applied in the field of polypropylene, can solve the problems of shrinkage rate change, material performance loss, density increase, etc., to achieve the effect of simple operation and easy guarantee of material performance

Inactive Publication Date: 2017-01-11
HEFEI GENIUS NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, this method can reduce the linear expansion coefficient to a limited extent, usually the linear expansion coefficient of pure polypropylene raw materials is about 12*10 -5 / °C, when the filling amount of talcum powder reaches 20%, the linear expansion coefficient of the material can be reduced to 8*10 -5 / °C, but the filling amount is large, there will be disadvantages such as shrinkage change, loss of material properties, increase in density, etc.

Method used

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  • Ultralow-linear expansion coefficient polypropylene composite material and preparation method thereof

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Effect test

Embodiment 1

[0032] Mix 95 kg polypropylene, 0.5 kg phenolic heat stabilizer 1010, 0.5 kg lubricant EBS, 5 kg Sc 2 W 3 o 12 , 0.2 kg of titanate coupling agent NDZ109, 0.2 kg of white oil 36# are melted, mixed and dispersed in a twin-screw extruder with a length-to-diameter ratio of 40:1. After all raw materials are blended and extruded to granulate, the implementation Examples of polypropylene composites. The processing temperature during preparation was 200°C.

Embodiment 2

[0034] 97 kg of polypropylene, 0.5 kg of phenolic heat stabilizer 1010, 0.5 kg of lubricant zinc stearate, 0.3 kg of lubricant calcium stearate, 3 kg of Sc 2 W 3 o 12 , 0.4 kilograms of silane coupling agent KH-550, and 0.3 kilograms of white oil 32# are melted and mixed and dispersed in a twin-screw extruder with a length-to-diameter ratio of 56:1. After all raw materials are blended and extruded to granulate, the implementation Examples of polypropylene composites. The processing temperature during preparation was 220°C.

Embodiment 3

[0036] With 93 kilograms of polypropylene, 0.1 kilogram of phenolic heat stabilizer 1010 and 0.1 kilogram of heat stabilizer 168, 0.2 kilogram of silane coupling agent KH-570, 0.2 kilogram of white oil 15#, 7 kilograms of Sc 2 W 3 o 12 Melt, mix and disperse in a twin-screw extruder with an aspect ratio of 35:1. After all raw materials are blended, extruded and granulated, the polypropylene compound of this example is obtained. The processing temperature during preparation was 170°C.

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Abstract

The invention relates to an ultralow-linear expansion coefficient polypropylene material and a preparation method thereof. The material is prepared from 90-98 parts of polypropylene, 2-10 parts of Sc2W3O12, 0.1-0.5 parts of a coupling agent, 0.1-1 part of a heat stabilizer, 0-1 part of a lubricant and 0-0.5 parts of white oil, wherein the weight part sum of the polypropylene and Sc2W3O12 is 100. One-dimensional Sc2W3O12 is added to the polypropylene material in order to reduce the linear expansion coefficient of the composite material, so the prepared polypropylene composite material has a low linear thermal expansion coefficient, and can be applied to the aerospace field, the optical field, the communication field and other fields with high material dimension change requirements.

Description

technical field [0001] The invention relates to the technical field of polypropylene, in particular to an ultra-low linear expansion coefficient polypropylene composite material and a preparation method thereof. Background technique [0002] Polypropylene material is widely used in automobiles, electronic products and other fields due to its advantages of low price and light weight. However, the polypropylene material itself has a large linear expansion coefficient, which makes it difficult to meet the dimensional requirements of precision parts and the dimensional stability requirements in the use environment with large temperature changes. [0003] In order to solve this problem, traditional inorganic fillers such as talcum powder with aspect ratio are usually added to polypropylene materials to reduce the linear expansion coefficient of the material. However, this method can reduce the linear expansion coefficient to a limited extent, usually the linear expansion coeffic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L91/06C08K13/02C08K3/22C08K5/134C08K5/526C08K5/098C08K5/20
CPCC08L23/12C08K2201/014C08L91/06C08K13/02C08K3/22C08K5/1345C08K5/20C08K5/098C08K5/526C08K5/103
Inventor 杨桂生计娉婷
Owner HEFEI GENIUS NEW MATERIALS
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