AIN-doped modified visible-light activity photocatalyst preparation method

A photocatalyst and visible light technology, applied in the field of air purification, can solve the problems of insignificant photocatalyst modification effect, narrowing the use range of photocatalyst, and low utilization rate of sunlight, and achieve excellent effect, narrow energy level gap, and good photocatalytic activity. Effect

Inactive Publication Date: 2017-03-01
THE GREEN ENVIRONMENTAL PROTECTION TECH CO LTD
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  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It can be known from the mechanism of photocatalyst that only under the irradiation of ultraviolet light with a wavelength lower than 387.5nm, the photocatalyst can be excited to generate photogenerated electron-hole pairs, degrade the organic pollutants in the indoor and car air, and achieve the effect of purifying the air. Ultraviolet light of this wavelength only accounts for 3-5% of sunlight, and the utilization rate of sunlight is very low, thus greatly reducing the scope of use of photocatalysts
In order to make better use of sunlight to stimulate photocatalysts to degrade organic pollutants and expand the photocatalyst’s photoresponse absorption wavelength range, it is necessary to modify photocatalysts. In the existing photocatalyst doping modification methods, there are mainly metal ion doping, Non-metal ion doping, noble metal deposition, surface photosensitization, etc., are basically modified by a single doping method, the effect of photocatalyst modification is not significant, and some methods still have problems such as unstable performance and expensive modification.

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  • AIN-doped modified visible-light activity photocatalyst preparation method
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Embodiment 1

[0024] The preparation method of AlN-doped modified visible light active photocatalyst, the specific steps are first taking 10ml of nano-TiO with a solid content of 10%. 2 Colloidal solution, diluted 1:9 with deionized water to form nano-TiO 2 Colloid dilute solution, this is the photocatalyst solution; then, add nano-aluminum nitride of 0.01wt% of photocatalyst solution weight to the photocatalyst solution to carry out doping modification, stir 0.5h under the condition of 250rpm, finally, obtain the photocatalyst solution of modification .

[0025] Spray the prepared modified photocatalyst evenly on a 200*250mm glass sheet, then place it in a closed transparent glass reaction vessel to investigate the visible light activity of the modified photocatalyst, select a 20W incandescent lamp to simulate sunlight, and inject it into the reaction vessel 5ppm of formaldehyde gas, the degradation product of formaldehyde CO 2 Generate speed and concentration to characterize the visible...

Embodiment 2

[0027] The preparation method of AlN-doped modified visible light active photocatalyst, the specific steps are first taking 10ml of nano-TiO with a solid content of 10%. 2 Colloidal solution, diluted 1:9 with pure water to form nano-TiO 2 The dilute colloidal solution, which is the photocatalyst solution; then, doping and modifying the photocatalyst solution with 0.1% nano-AlN by weight of the photocatalyst solution, stirring at 250rpm for 0.5h, and finally obtaining the modified photocatalyst solution.

[0028] Spray the prepared modified photocatalyst evenly on a 200*250mm glass sheet, then place it in a closed transparent glass reaction vessel to investigate the visible light activity of the modified photocatalyst, select a 20W incandescent lamp to simulate sunlight, and inject it into the reaction vessel 5ppm of ethanol gas, the degradation product of ethanol CO 2 Generate speed and concentration to characterize the visible light activity of the modified photocatalyst, th...

Embodiment 3

[0030] With above-mentioned embodiment 1, its difference is:

[0031] Nano TiO in step (1) 2 The solid content of the colloidal solution is 15wt%, and the surface potential is 37mV; Nano TiO 2 The solid content of the dilute solution is 0.5wt%.

[0032] In the step (2), the average particle size of the nano-aluminum nitride is 45nm, and the addition amount is 0.05wt% of the weight of the photocatalyst solution; the stirring speed is 300rpm, and the stirring time is 1h.

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Abstract

The invention discloses an AIN-doped modified visible-light activity photocatalyst preparation method. The method comprises the following steps: taking a nano TiO2 colloidal solution with a certain of solid content, using water for dilution to obtain a nano TiO2 dilute solution according to a certain proportion to obtain a photocatalyst solution; adding AIN in the photocatalyst solution according to a certain proportion, stirring the materials for a while to obtain the AIN-doped modified photocatalyst; wherein the solid content of the nano TiO2 colloidal solution is 10-30 wt%, the solid content of the nano TiO2 dilute solution is 0.1-1.0 wt%, AIN is nano aluminium nitride, the average particle size is 30-60 nm, and the AlN addition is 0.01-0.1wt%. The photocatalyst has the advantages of realization of visible light band response, good dispersibility, high photocatalysis efficiency, and more excellent modification effect.

Description

technical field [0001] The invention relates to the technical field of air purification, in particular to a preparation method of an AlN doped modified visible light active photocatalyst. Background technique [0002] Photocatalyst is a general term for a photo-semiconductor material with photocatalytic function represented by nano-scale titanium dioxide. It is coated on the surface of the substrate, and under the action of ultraviolet light, it produces a strong catalytic degradation function: it can effectively degrade toxic substances in the air. Harmful gas; can effectively kill a variety of bacteria, and can decompose and harmlessly treat the toxins released by bacteria or fungi; it also has functions such as deodorization, anti-pollution, and air purification. It can be known from the mechanism of photocatalyst that only under the irradiation of ultraviolet light with a wavelength lower than 387.5nm, the photocatalyst can be excited to generate photogenerated electron-...

Claims

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Application Information

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IPC IPC(8): B01J27/24B01D53/86B01D53/62
Inventor 杨姗姗
Owner THE GREEN ENVIRONMENTAL PROTECTION TECH CO LTD
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