Antistatic, wear-resistant and high-performance PS composite material and preparation method thereof

A composite material and high-performance technology, which is applied in the field of antistatic and wear-resistant high-performance PS composite materials and its preparation, can solve problems that have not been reported and limit the application of PS composite materials, and achieve improved mechanical properties, strong three-dimensional protection, The effect of preventing reunion

Inactive Publication Date: 2017-03-08
ANHUI JIANGHUAI AUTOMOBILE GRP CORP LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, with the development of science and technology, in some specific fields, people have higher and higher performance requirements for PS materials, especially wear resistance, antistatic performance and mechanical properties, which greatly limits the application of PS composite mater...

Method used

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  • Antistatic, wear-resistant and high-performance PS composite material and preparation method thereof
  • Antistatic, wear-resistant and high-performance PS composite material and preparation method thereof
  • Antistatic, wear-resistant and high-performance PS composite material and preparation method thereof

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preparation example Construction

[0038] The preparation method of the wear-resistant high-performance PS composite material of any one of the above, comprising the following steps:

[0039] (1) Weigh 60-80 parts of PS, 20-30 parts of modified nano-ZrO 2 , 0.1-0.5 parts of MAH-SEBS, 0.1-0.5 parts of antioxidant, 0.1-0.3 parts of lubricant are mixed and stirred evenly to obtain a mixture;

[0040] (2) Extruding and granulating the mixture obtained in step (1) to obtain a PS composite material.

[0041] Preferably, the step (2) specifically includes: putting the mixture obtained in the step (1) into the hopper of a twin-screw extruder to extrude and granulate to obtain a PS composite material, wherein the twin-screw extruder The output machine includes six temperature zones arranged in sequence, the temperature of the first zone is 140-180°C, the temperature of the second zone is 190-230°C, the temperature of the third zone is 190-230°C, the temperature of the fourth zone is 190-230°C, and the temperature of th...

preparation example 1

[0048] Modified Nano ZrO 2 , its preparation method is as follows:

[0049] (1) Weigh a certain amount of butyl acrylate (BA), nano ZrO 2, potassium persulfate (KPS), aluminum sulfate, sodium dodecylbenzenesulfonate; BA, nano ZrO 2 , Potassium persulfate (KPS), aluminum sulfate, and sodium dodecylbenzenesulfonate have a mass ratio of 10:30:0.3:1:0.1; nanometer ZrO 2 The diameter is 40-80nm.

[0050] (2) KPS, sodium dodecylbenzenesulfonate, BA, nano ZrO 2 Put it into a three-necked flask, react in an oil bath at 160-180°C for 6-12 hours, then add aluminum sulfate to break the emulsion for 6-10 hours, filter and wash to obtain modified nano-ZrO 2 .

preparation example 2

[0052] Modified Nano ZrO 2 , its preparation method is as follows:

[0053] (1) Weigh a certain amount of butyl acrylate (BA), nano ZrO 2 , potassium persulfate (KPS), aluminum sulfate, sodium dodecylbenzenesulfonate; BA, nano ZrO 2 , Potassium persulfate (KPS), aluminum sulfate, and sodium dodecylbenzenesulfonate have a mass ratio of 10:40:0.7:3:0.3; nanometer ZrO 2 The diameter is 40-80nm.

[0054] (2) KPS, sodium dodecylbenzenesulfonate, BA, nano ZrO 2 Put it into a three-necked flask, react in an oil bath at 160-180°C for 6-12 hours, then add aluminum sulfate to break the emulsion for 6-10 hours, filter and wash to obtain modified nano-ZrO 2 .

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Abstract

The invention relates to an antistatic, wear-resistant and high-performance PS composite material and a preparation method thereof. The antistatic, wear-resistant and high-performance PS composite material is prepared by, by weight, 60-80 parts of PS, 20-30 parts of modified nano ZrO2, 10-16 parts of antistatic agent, 0.1-0.5 part of compatibilizer, 0.1-0.5 part of antioxidant and 0.1-0.3 part of lubricating agent. The antistatic, wear-resistant and high-performance PS composite material has the advantages that due to the fact that the nano ZrO2 is grafted by poly-butyl acrylate (PBA), a PBA organic coating layer can be formed on the surface of the nano ZrO2, a strong three-dimensional protection effect is generated, ZrO2 agglomeration is prevented, the ZrO2 can be evenly dispersed in a PS matrix, and the mechanical performance of the PS composite material is increased.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, in particular to an antistatic and wear-resistant high-performance PS composite material and a preparation method thereof. Background technique [0002] Polystyrene (PS), as a common thermoplastic, is widely used. However, with the development of science and technology, in some specific fields, people have higher and higher performance requirements for PS materials, especially wear resistance, antistatic performance and mechanical properties, which greatly limits the application of PS composite materials in these special fields. on the application. [0003] Nano-zirconium dioxide (ZrO) grafted with polybutylacrylate (PBA) 2 ), and then modify the PS to improve the wear resistance, antistatic performance and physical properties of the PS composite material. This method has not been reported so far. Contents of the invention [0004] The purpose of the present invention is to provide...

Claims

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Application Information

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IPC IPC(8): C08L25/06C08L51/10C08L51/00C08K5/526C08K5/13C08K5/134C08K5/098C08K5/42C08K5/17C08F292/00C08F220/18
CPCC08F292/00C08L25/06C08L2201/04C08L2205/02C08L2205/03C08L51/10C08L51/003C08K5/526C08K5/098C08K5/17C08K5/13C08K5/1345C08K5/42C08F220/1804
Inventor 刘凯徐志海黄家奇王添琪
Owner ANHUI JIANGHUAI AUTOMOBILE GRP CORP LTD
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