Drilling fluid additive composition application thereof and water-based drilling fluid suitable for high-bearing-pressure plugging while drilling and application thereof
A composition and additive technology, applied in the field of water-based drilling fluid, can solve problems such as poor plugging effect, achieve high pressure bearing capacity, excellent plugging effect, and save drilling time
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[0052] According to the present invention, the above-mentioned weakly crosslinked copolymer can be prepared by various conventional methods in the art, but preferably, the preparation method of the weakly crosslinked copolymer includes: in an aqueous solvent, in an oxidation-reduction initiation system In the presence of a crosslinking agent and an emulsifier, the compound shown in formula (1'), the compound shown in formula (2') and the compound shown in formula (3') are emulsion polymerized, wherein the crosslinking The dosage of the agent makes the content of the crosslinked substructure in the weakly crosslinked copolymer obtained be 0.1-1% by weight,
[0053]
[0054] Wherein, the substituents involved in the monomers in the above method are as described above, and will not be repeated here. The compound represented by formula (1'), the compound represented by formula (2') and the compound represented by formula (3') can also be appropriately selected according to the ...
Embodiment approach
[0142] According to a preferred embodiment of the present invention, the biomimetic wall-fixing agent contains a structural unit shown in formula (I):
[0143]
[0144] In formula (I), R 1 for hydrogen, -CH 2 COOR 3 ’, or -CH 2 COOR 3 , R 2 for hydrogen, or and R 1 and R 2 at least one of n is an integer greater than 1, n R 5 Each independently is H or a group derived from dopamine and n R 5 At least one of them is a group derived from dopamine, R 4 for H or C 1 -C 10 The alkyl group, R"' is H, -CH 2 COOR 3 ’ or -CH 2 COOR 3 , and R 1 and R"' are not H, R at the same time 3 ’ is hydrogen or an alkali metal, R 3 is a group derived from dopamine.
[0145] The weight average molecular weight of the biomimetic wall-fixing agent may be 20000g / mol-150000g / mol, preferably 50000g / mol-100000g / mol.
[0146] According to the present invention, preferably, in formula (I), R 4 for C 2 -C 10 Alkyl, more preferably C 2 -C 6 of alkyl. R 4 Specific exampl...
specific Embodiment approach
[0161] According to a specific embodiment of the present invention, the preparation method of the biomimetic shale inhibitor comprises: in the presence of an inorganic acid catalyst, carrying out condensation reaction of arginine and lysine, the amount of arginine and lysine The molar ratio of the amount of amino acid is 0.2-6:1, and the condensation reaction conditions make the weight average molecular weight of the obtained biomimetic shale inhibitor 800-4000g / mol.
[0162] According to the present invention, in the preparation method of the bionic shale inhibitor, the arginine can be L-type, D-type or a mixture of the two, and the lysine can be L-type, D-type or a mixture of both. Preferably L-arginine and L-lysine are used.
[0163] According to the present invention, in the preparation method of the biomimetic shale inhibitor, the amount of the arginine and lysine is not particularly limited, as long as the weight average molecular weight of the product of the condensati...
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