Waterborne polyurethane decorative leather and manufacturing method thereof

A water-based polyurethane, manufacturing method and technology, applied in the field of decorative leather, to achieve the effect of simple operation, not easy to crack and wear, and flexible hand feeling

Active Publication Date: 2017-05-10
HEFEI KETIAN WATERBORNE TECH CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In recent years, the research on the preparation of waterborne polyurethane synthetic leather has made great progress, but the research on decorative leather is still in the traditional manufacturing process, especially in order to achieve the leather feel, wear resistance and ecological environmental protection, further development is needed

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A kind of manufacture method of waterborne polyurethane decorative leather, comprises the following steps:

[0031] 1. Ingredients:

[0032] (1) Preparation of impregnation solution

[0033] Add 10 kg of water-based polyurethane KT705 (Hefei Ketian Chemical Industry) with a solid content of 40% into 90 kg of tap water, stir evenly at high speed, and the pH value is 7.

[0034] (2) Preparation of coagulation solution

[0035] Mix and stir 8kg of phosphoric acid and 92kg of tap water to completely dissolve the phosphoric acid in the water.

[0036] (3) Preparation of foaming slurry

[0037] Add 2.8kg powder wetting agent A168 (Clariant), 29kg lignocellulose (Yixing Shengdeli), and 4.8kg foaming agent to 300kg waterborne polyurethane resin KT705 (solid content is 40%, Hefei Ketian Chemical Industry Co., Ltd.) K12 (Jinan Shuochang Chemical Industry), 4.8kg foam stabilizer 207 (Qingdao Zhongbao Chemical Industry), 1.7kg water-based crosslinking agent HD-105 (Shanghai Hao...

Embodiment 2

[0047] A kind of manufacture method of waterborne polyurethane decorative leather, comprises the following steps:

[0048] 1. Ingredients:

[0049] (1) Preparation of impregnation solution

[0050] 12 kg of water-based polyurethane KT705 (Hefei Ketian Chemical Industry Co., Ltd.) with a solid content of 40% was added to 88 kg of tap water, stirred evenly at high speed, and the pH value was 7.

[0051](2) Preparation of coagulation solution

[0052] Mix and stir 10kg of calcium chloride and 90kg of tap water to completely dissolve the calcium chloride in the water.

[0053] (3) Preparation of foaming slurry

[0054] Add 3.2kg powder wetting agent 5040 (Shenzhen Haichuan Chemical Industry), 32kg lignocellulose (Yixing Shengdeli) and 5.5kg foaming agent to 290kg waterborne polyurethane resin KT705 (40% solid content, Hefei Ketian Chemical Industry Co., Ltd.) Zinc stearate (Henan Huier Nano), 5kg foam stabilizer 207 (Qingdao Zhongbao Chemical), 1.5kg water-based crosslinking a...

Embodiment 3

[0064] A kind of manufacture method of waterborne polyurethane decorative leather, comprises the following steps:

[0065] 1. Ingredients:

[0066] (1) Preparation of impregnation solution

[0067] Add 14 kg of water-based polyurethane KT705 (Hefei Ketian Chemical) with a solid content of 40% into 86 kg of tap water, stir evenly at high speed, and the pH value is 7.

[0068] (2) Preparation of coagulation solution

[0069] Mix and stir 4kg calcium chloride, 6kg sodium chloride and 90kg tap water to completely dissolve calcium chloride in the water.

[0070] (3) Preparation of foaming slurry

[0071] Add 2.4kg powder wetting agent 5040 (Shenzhen Haichuan Chemical Industry), 24kg lignocellulose (Yixing Shengdeli), and 3.8kg foaming agent to 250kg water-based polyurethane resin KT705 (40% solid content, Hefei Ketian Chemical Industry Co., Ltd.) Zinc stearate (Henan Huier Nano), 3.9kg foam stabilizer 207 (Qingdao Zhongbao Chemical), 1.2kg water-based crosslinking agent HD-110 ...

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PUM

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Abstract

The invention provides waterborne polyurethane decorative leather and a manufacturing method thereof. The manufacturing method includes the steps of 1), performing base cloth treatment; 2), coating; 3), agglomerating; 4), conducting washing and drying, namely removing residual solidification liquid on the base cloth through a washing trough, drying and setting so as to obtain waterborne polyurethane decorative leather base; 5), conducting dry-process direct coating, namely applying the waterborne polyurethane decorative leather base with waterborne direct coating topcoat slurry and drying; 6), subjecting the waterborne polyurethane decorative leather base obtained after dry-process direct coating to high-temperature embossing to shape surface effect grain so as to obtain the waterborne polyurethane decorative leather. The manufacturing method has the advantage that the waterborne polyurethane resin slurry and a waterborne environment-friendly auxiliary are used for enabling the decorative leather to be free of organic solvents during preparation and use, so that the problems of contamination and residues of solvent-type decorative leather are solved. The waterborne polyurethane decorative leather has the advantages of compact structure, less proneness to cracking and wear and flexibility in hand feel and can meet the demands of existing market on the decorative leather completely.

Description

technical field [0001] The invention relates to the technical field of decorative leather, and specifically discloses a water-based polyurethane decorative leather and a manufacturing method thereof. Background technique [0002] At present, synthetic leather has been applied in various fields in people's life, and there are various varieties. Decorative leather is a product developed in the synthetic leather industry in recent years. It has the advantages of light weight, wear resistance, heat resistance, toughness, good cold resistance, and high tensile strength. At present, the decorative leather is still made of solvent-based polyurethane, and the DMF (dimethylformamide) in the solvent-based polyurethane is replaced with water by a wet process, so that the coating has continuous pores, so as to achieve a certain thickness to increase the three-dimensional effect. However, a large amount of DMF is used in the coating slurry, and the solvent is washed and replaced, but it...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06N3/14D06N3/00
Inventor 王刚罗文远戴家兵李维虎
Owner HEFEI KETIAN WATERBORNE TECH CO LTD
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