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Fluorgypsum-based high-water and super high-water filling material and preparation method thereof

A filling material, fluorogypsum technology, which is applied in the field of fluorogypsum-based high-water/ultra-high-water filling materials, can solve the problems of poor material performance, a large amount of manpower, material resources, slow condensation, etc., achieve good incompressibility, and save filling costs , the effect of adjustable initial setting time

Inactive Publication Date: 2017-05-24
HENAN POLYTECHNIC UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, fly ash-based filling materials and concrete materials are mainly used for mine gobside entry retention and gob filling. Although the price of fly ash-based filling materials is low, the material performance is poor, the setting time is slow, and the strength is low; concrete materials Although the strength is high, more materials are required per unit volume, and the production system is more complicated. At the same time, the use of this material requires a lot of manpower and material resources.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Prepare the components of the filling material with the raw materials in the following percentages by weight:

[0017] Component A is composed of the following raw materials in weight percentage: 83% of ferric aluminate clinker, 8% of calcium-based bentonite, 2.5% of sodium sulfate, 1.5% of magnesium aluminum silicate, and 2% of sodium polyacrylate; component B is composed of the following Raw material composition in weight percentage: 68.5% of fluorogypsum, 10.5% of calcium oxide, 5% of metakaolin, 1% of composite early strength agent, 2% of magnesium aluminum silicate, and 2% of calcium carbonate.

[0018] Add water to component A and stir, the mass ratio of water to component A is 5:1; add water to component B and stir, the mass ratio of water to component A is 5:1; add water and stir component A Mix well with component B at a mass ratio of 1:1, and stir well to obtain the ultra-high water filling material.

[0019] The ultra-high water filling material 1d prepared ...

Embodiment 2

[0021] Prepare the components of the filling material with the raw materials in the following percentages by weight:

[0022] Component A is composed of the following raw materials in weight percentage: 84% of iron-aluminate clinker, 9% of calcium-based bentonite, 2.8% of calcium nitrite, 1.8% of magnesium aluminum silicate, and 2% of sodium polyacrylate; Component B is composed of the following Raw material composition in weight percent: 70.0% of fluorogypsum, 11.5% of calcium oxide, 5.5% of metakaolin, 1.5% of composite early strength agent, 2.5% of magnesium aluminum silicate, and 2% of calcium carbonate.

[0023] Add water to component A and stir, the mass ratio of water to component A is 6:1; add water to component B and stir, the mass ratio of water to component A is 6:1; add water and stir component A Mix evenly with component B at a mass ratio of 1:1 to obtain ultra-high water materials.

Embodiment 3

[0025] Prepare the components of the filling material with the raw materials in the following percentages by weight:

[0026] Component A is composed of the following raw materials in weight percentage: 86% of ferric aluminate clinker, 10% of calcium-based bentonite, 3% of sodium sulfate, 2% of magnesium aluminum silicate, and 2% of sodium polyacrylate; component B is composed of the following Raw material composition in weight percentage: 79.5% of fluorine gypsum, 16% of calcium oxide, 6% of metakaolin, 3.5% of composite early strength agent, 3% of magnesium aluminum silicate, and 2% of calcium carbonate.

[0027] Add water to component A and stir, the mass ratio of water to component A is 1.5:1; add water to component B and stir, the mass ratio of water to component A is 1.5:1; add water and stir component A Mix evenly with component B at a mass ratio of 1:1 to obtain a high water filling material.

[0028] The strength of the high-water filling material prepared in this ex...

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Abstract

The invention provides a fluorgypsum-based high-water and super high-water filling material and a preparation method thereof. The material is prepared from a component A and a component B, wherein the component A is prepared from, by weight percentage, aluminoferic cement clinker, calcium bentonite, an accelerator, a suspending agent and a thickening agent; the component B is prepared from, by weight percentage, fluorgypsum, calcium oxide, metakaolin, a compound early strength agent, the suspending agent and calcium carbonate. The material has the advantages of achieving early strength and rapid hardening and being high in water-cement ratio, adjustable in initial setting time and less in material consumption, after the component A and the component B are mixed, no bleeding happens, and the initial setting time is 3-25 minutes and can be adjusted according to field needs.

Description

technical field [0001] The invention relates to a fluorine gypsum-based high-water / ultra-high-water filling material, which is mainly used for retaining entry along the goaf of mines, filling of gobs, filling and mining, backfilling and support of the walls of wells, and the like. Background technique [0002] At present, fly ash-based filling materials and concrete materials are mainly used for mine gobside entry retention and gob filling. Although the price of fly ash-based filling materials is low, the material performance is poor, the setting time is slow, and the strength is low; concrete materials Although the strength is high, more materials are required per unit volume, and the production system is more complicated. At the same time, the use of this material requires a lot of manpower and material resources. Therefore, it is particularly important to develop a high-water material suitable for gobside retaining and goblin filling in mines. [0003] Fluorogypsum is a ...

Claims

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Application Information

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IPC IPC(8): C04B28/14
CPCC04B28/142C04B2111/00724C04B2201/50C04B22/08C04B14/104C04B22/147C04B14/042C04B24/2641C04B22/064C04B14/106C04B2103/0068C04B14/28C04B22/085
Inventor 熊祖强王雨利张耀辉胡黎明孙亚鹏
Owner HENAN POLYTECHNIC UNIV
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