Method for wet removal of sulfur and mercury components in flue gas containing mercury and sulfur by urea phosphate

A technology of urea phosphate and wet method, which is applied in the field of wet removal of mercury, mercury components, urea phosphate, and sulfur in flue gas containing sulfur, which can solve the problems of secondary pollution, high investment and operation costs, and unsatisfactory technology , to achieve the effect of improving catalytic oxidation and reducing content

Inactive Publication Date: 2017-05-31
YINYU MINERALS WUCHUAN AUTONOMOUS COUNTY
View PDF1 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, my country's sulfur dioxide emissions have ranked among the top in the world, becoming the third largest acid rain area in the world, and the damage caused by acid rain has gradually increased every year, reaching more than 100 billion yuan. The source of sulfur dioxide is mainly sintering flue gas, and Most of the sintering flue gas also contains mercury components, so that when sulfur dioxide enters the air and forms acid rain, mercury components also enter the environment, and mercury is a toxic heavy metal component, which enters the environment with rainwater Afterwards, it is easy to enter the organism and convert into methylmercury in the organism, and methylmercury can greatly affect the metabolism of the organism, leading to threats to the health of the organism
[0003] Therefore, it is necessary to desulfurize and demercurize sintering flue gas; for desulfurization, most of the desulfurization at home and abroad is still dominated by wet desulfurization, and wet desulfurization accounts for more than 85%. Limestone-gypsum method and sodium desulfurization are generally used Alkali method, etc. These methods not only have high inv...

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] A kind of method that urea phosphate is used for wet removal sulfur, mercury component in mercury-containing, sulfur-containing flue gas, comprises the following steps:

[0038] (1) Put urea phosphate in phosphoric acid, mix according to the mass ratio of 1:0.1, and adjust the temperature to 80°C for 20 minutes, then add water to cool to room temperature, and the amount of water added is 3 times the mass of urea phosphate to obtain phosphourea solution ;

[0039] (2) pulverizing pyrolusite, crossing 40 mesh sieves to obtain pyrolusite powder;

[0040] (3) adding the phosphourea solution to the pyrolusite powder, stirring evenly, so that the liquid-solid ratio is 3:1, to obtain a desulfurization and demercuration agent;

[0041] (4) The mercury-containing and sulfur-containing flue gas is first subjected to activated carbon adsorption treatment, and then passed into the spray absorption tower at a rate of 10L / min, and the desulfurization and mercury removal agent is spr...

Embodiment 2

[0044] A kind of method that urea phosphate is used for wet removal sulfur, mercury component in mercury-containing, sulfur-containing flue gas, comprises the following steps:

[0045] (1) Put urea phosphate in phosphoric acid, mix according to the mass ratio of 1:0.7, and adjust the temperature to 180°C for 30 minutes, then add water to cool to room temperature, and the amount of water added is 8 times the mass of urea phosphate to obtain a phosphourea solution ;

[0046] (2) pulverizing pyrolusite, crossing 100 mesh sieves to obtain pyrolusite powder, adopting microwave radiation, the radiation power is 100W, and the radiation time is 10min;

[0047] (3) adding the phosphourea solution to the pyrolusite powder, stirring evenly so that the liquid-solid ratio is 7:1, and obtaining the desulfurization and demercuration agent;

[0048] (4) The mercury-containing and sulfur-containing flue gas is first subjected to activated carbon adsorption treatment, and then passed into the sp...

Embodiment 3

[0051] A kind of method that urea phosphate is used for wet removal sulfur, mercury component in mercury-containing, sulfur-containing flue gas, comprises the following steps:

[0052] (1) Put urea phosphate into phosphoric acid, mix according to the mass ratio of 1:0.5, and adjust the temperature to 100°C for 25 minutes, then add water to cool to room temperature, and the amount of water added is 5 times the mass of urea phosphate to obtain phosphourea solution ;

[0053] (2) pulverizing pyrolusite, crossing a 40-100 mesh sieve to obtain pyrolusite powder, adopting microwave radiation, the radiation power is 300W, and the radiation time is 20min;

[0054] (3) adding the phosphourea solution to the pyrolusite powder, stirring evenly, so that the liquid-solid ratio is 5:1, and obtaining the desulfurization and demercuration agent;

[0055] (4) The mercury-containing and sulfur-containing flue gas is first subjected to activated carbon adsorption treatment, and then passed into...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Graininessaaaaaaaaaa
Login to view more

Abstract

The invention relates to the technical field of purification treatment of flue gases, in particular to a method for wet removal of sulfur and mercury components in flue gas containing mercury and sulfur by urea phosphate. The method comprises the following steps: researching removal of the sulfur and mercury components in the flue gas containing the mercury and the sulfur; adding the urea phosphate for removing, adsorbing with activated carbon and then carrying out spraying treatment by adopting a sulfur and mercury removing agent prepared from the urea phosphate and pyrolusite. Therefore, liquid subjected to sulfur removal and mercury removal can be used for producing fertilizer, further the efficiency of the sulfur removal and the mercury removal for the flue gas containing the sulfur and the mercury is improved, added values of the sulfur removal and the mercury removal are also increased, and the cost of the sulfur removal and the mercury removal for the flue gas is reduced.

Description

technical field [0001] The invention relates to the technical field of flue gas purification treatment, in particular to a method for wet removal of sulfur and mercury components in flue gas containing mercury and sulfur by using urea phosphate. Background technique [0002] At present, my country's sulfur dioxide emissions have ranked among the top in the world, becoming the third largest acid rain area in the world, and the damage caused by acid rain has gradually increased every year, reaching more than 100 billion yuan. The source of sulfur dioxide is mainly sintering flue gas, and Most of the sintering flue gas also contains mercury components, so that when sulfur dioxide enters the air and forms acid rain, mercury components also enter the environment, and mercury is a toxic heavy metal component, which enters the environment with rainwater Afterwards, it is easy to enter the organism and convert into methylmercury in the organism, and methylmercury can greatly affect th...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): B01D53/86B01D53/80B01D53/75B01D53/64B01D53/50
CPCB01D53/75B01D53/80B01D53/8609B01D53/8665B01D2255/2073B01D2257/302B01D2257/602B01D2258/0283
Inventor 李军旗刘利黄碧芳金会心陈庆唐道文赵平原王丽远鲁圣军黎志英陈肖虎
Owner YINYU MINERALS WUCHUAN AUTONOMOUS COUNTY
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products