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Glass fiber reinforced polypropylene composition and preparation method thereof

A polypropylene composition and polypropylene technology, applied in the field of polymer composite materials, can solve the problems of affecting the appearance of PA parts, affecting the performance of pressure-resistant parts, and large color differences, so as to reduce the phenomenon of floating fibers and improve The effect of bonding state and improving surface floating fiber

Inactive Publication Date: 2017-06-09
HEFEI GENIUS NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, after adding glass fiber, the phenomenon of floating fiber is easy to appear. The phenomenon of floating fiber is generally caused by the exposure of glass fiber. The white glass fiber floats on the surface during the filling and flow process of the plastic melt. After condensation molding, it will be on the surface of the plastic part. Form radial white traces, which will be more obvious when the plastic part is black due to the increased color difference
Therefore, the floating fiber phenomenon not only affects the appearance of PA parts, but also affects its performance as a pressure-resistant part.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] (1) Dry polypropylene at 50°C for 4 hours; polyethylene at 50°C for 4 hours;

[0040] (2) Weigh 60 parts of dry polypropylene, 1 part of polyethylene, 25 parts of glass fiber, 5 parts of nucleating agent sodium benzoate, and 10 parts of surface improving agent;

[0041] (3) Stir the material weighed in the above step (2) in a high-speed mixer for 3 minutes;

[0042] (4) Then, the above-mentioned homogeneously mixed material is fed into the feeding port of the twin-screw extruder, melted and extruded through the twin-screw extruder, and granulated to obtain a polypropylene composition;

[0043] The processing technology of the twin-screw extruder is as follows: the temperature of the first zone of the twin-screw extruder is 160°C, the temperature of the second zone is 170°C, the temperature of the third zone is 185°C, the temperature of the fourth zone is 185°C, the temperature of the fifth zone is 200°C, and the temperature of the sixth zone The temperature is 200°C, t...

Embodiment 2

[0045] (1) Dry polypropylene at 80°C for 5 hours; polyethylene at 80°C for 5 hours;

[0046] (2) Weigh dry 40 parts of polypropylene, 10 parts of polyethylene, 30 parts of glass fiber, 5 parts of toughening agent (maleic anhydride grafted ethylene-octene copolymer, ethylene-methyl acrylate copolymer thing), 10 parts of nucleating agent sodium benzoate, 5 parts of surface improving agent;

[0047] (3) Stir the material weighed in the above step (2) in a high-speed mixer for 5 minutes;

[0048] (4) Then, the above-mentioned homogeneously mixed material is fed into the feeding port of the twin-screw extruder, melted and extruded through the twin-screw extruder, and granulated to obtain a polypropylene composition;

[0049] The processing technology of the twin-screw extruder is as follows: the temperature of the first zone of the twin-screw extruder is 170°C, the temperature of the second zone is 180°C, the temperature of the third zone is 195°C, the temperature of the fourth zo...

Embodiment 3

[0051] (1) Dry polypropylene at 60°C for 4 hours; polyethylene at 70°C for 5 hours;

[0052] (2) Weigh dry 40 parts of polypropylene, 5 parts of polyethylene, 35 parts of glass fiber, 3 parts of toughening agent (ethylene-methyl acrylate-glycidyl methacrylate), 8 parts of ingredients Nucleating agent sodium benzoate, 8 parts of surface improving agent;

[0053] (3) Stir the material weighed in the above step (2) in a high-speed mixer for 4 minutes;

[0054] (4) Then, the above-mentioned homogeneously mixed material is fed into the feeding port of the twin-screw extruder, melted and extruded through the twin-screw extruder, and granulated to obtain a polypropylene composition;

[0055] The processing technology of the twin-screw extruder is as follows: the temperature of the first zone of the twin-screw extruder is 180°C, the temperature of the second zone is 190°C, the temperature of the third zone is 200°C, the temperature of the fourth zone is 205°C, the temperature of the ...

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PUM

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Abstract

The invention provides a glass fiber reinforced polypropylene composition and a preparation method thereof. The glass fiber reinforced polypropylene composition is prepared from 30-60 parts of polypropylene, 1-10 parts of polyethylene, 25-45 parts of glass fibers, 0-5 parts of a flexibilizer, 5-10 parts of a nucleating agent and 5-10 parts of a surface improver through mixing and extrusion granulation. By mixing TAF in the surface improver with silicone, the compatibleness between polypropylene and the glass fibers is improved; and by forming an anchor-like knot, namely a cross-linking point between the glass fibers and polypropylene, the bonding state between the glass fibers and polypropylene is improved, and the separation between the glass fibers and resin is reduced, so that the exposure of the glass fibers is reduced. Besides, by utilizing short-cut glass fibers with a rectangular cross section, a fiber floating phenomenon can be reduced; besides, the short-cut glass fibers can be further mutually matched with the surface improver to jointly ameliorate the surface fiber floating caused after the injection molding of the glass fiber reinforced polypropylene composition and improve the compressive property of the glass fiber reinforced polypropylene composition.

Description

technical field [0001] The invention belongs to the field of polymer composite materials, and in particular relates to a glass fiber reinforced polypropylene composition and a preparation method thereof. Background technique [0002] Polypropylene is a non-toxic, odorless, tasteless milky white highly crystalline polymer with a molecular weight of about 80,000-150,000 and a density of only 0.90-0.91g / cm 3 , is currently one of the lightest varieties of all plastics. In addition, polypropylene is particularly stable to water, and its water absorption rate in water is only 0.01%. Polypropylene has good formability, but because of its large shrinkage rate, about 1% to 2.5%, thick-walled products are prone to dents, so it is difficult to meet the requirements for some parts with high dimensional accuracy. [0003] At present, polypropylene is mainly reinforced by adding glass fibers, which can improve the strength, heat distortion temperature and dimensional stability of pol...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08L23/06C08L83/04C08K7/14C08K5/20C08K5/098B29C47/92B29C48/92
CPCC08L23/12B29C48/92B29C2948/9259B29C2948/92704C08K2201/004C08L2205/03C08L2205/035C08L23/06C08L83/04C08K7/14C08K5/20C08K5/098
Inventor 杨桂生吴安琪
Owner HEFEI GENIUS NEW MATERIALS
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